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A push for more stringent emissions regulations has resulted in larger, increasingly complex aftertreatment solutions. In particular, oxides of nitrogen (NOX) and particulate matter (PM) have been controlled using two separate systems, selective catalytic reduction (SCR) and the catalyze diesel particulate filter (CDPF), or the functionality has been combined into a single device producing the SCR on filter (SCRoF). The SCRoF forgoes beneficial NO2 production present in the CDPF to avoid NH3 oxidation which occurs when using platinum group metals (PGM) for oxidation. In this study, mixed-metal oxides are shown to oxidize NO to NO2 without appreciable NH3 oxidation. This selectivity leads to enhanced performance when combined with a typical Cu-zeolite catalyst.

Advanced combustion strategies used to improve efficiency, emissions, and performance in internal combustion engines (IC) alter the chemical composition of engine-out emissions. The characterization of exhaust chemistry from advanced IC engines requires an analytical system capable of measuring a wide range of compounds. For many years, the widely accepted Coordinating Research Council (CRC) Auto/Oil procedure[1,2] has been used to quantify hydrocarbon compounds between C1 and C12 from dilute engine exhaust in Tedlar polyvinyl fluoride (PVF) bags. Hydrocarbons greater than C12+ present the greatest challenge for identification in diesel exhaust. Above C12, PVF bags risk losing the higher molecular weight compounds due to adsorption to the walls of the bag or by condensation of the heavier compounds. This paper describes two specialized exhaust gas sampling and analytical systems capable of analyzing the mid-range (C10 - C24) and the high range (C24+) hydrocarbon in exhaust.

This paper summarizes the Heavy-Duty In-Use Testing (HDUIT) measurement allowance program for Particulate Matter Portable Emissions Measurement Systems (PM-PEMS). The measurement allowance program was designed to determine the incremental error between PM measurements using the laboratory constant volume sampler (CVS) filter method and in-use testing with a PEMS. Two independent PM-PEMS that included the Sensors Portable Particulate Measuring Device (PPMD) and the Horiba Transient Particulate Matter (TRPM) were used in this program. An additional instrument that included the AVL Micro Soot Sensor (MSS) was used in conjunction with the Sensors PPMD to be considered a PM-PEMS. A series of steady state and transient tests were performed in a 40 CFR Part 1065 compliant engine dynamometer test cell using a 2007 on-highway heavy-duty diesel engine to quantify the accuracy and precision of the PEMS in comparison with the CVS filter-based method.

The use of fuel additives is one possible approach to reduce wear and corrosion in methanol fueled automobile engines. One hundred and six compounds added to M100 fuel in modest concentrations (1%) were tested in a Ball on Cylinder Machine (BOCM) for their ability to improve lubricity. The most promising candidates were then tested in an engine using a modified ASTM Sequence V-D wear screening test. Additive performance was measured by comparing the buildup of wear metals in the oil to that obtained from an engine fueled with neat M100. The BOCM method of evaluating the additive candidates proved inadequate in predicting abrasive engine wear under the test conditions utilized for this research program.

A zero-dimensional cycle simulation model coupled with a chemical equilibrium model and a two-zone combustion model has been extended to predict nitric oxide formation and emissions from spark-ignited, lean-burn natural gas engines. It is demonstrated that using the extended Zeldovich mechanism alone, the NOx emissions from an 8.1-liter, 6-cylinder, natural gas engine were significantly under predicted. However, by combining the predicted NOx formation from both the extended Zeldovich thermal NO and the Fenimore prompt NO mechanisms, the NOx emissions were predicted with fair accuracy over a range of engine powers and lean-burn equivalence ratios. The effect of injection timing on NOx emissions was under predicted. Humidity effects on NOx formation were slightly under predicted in another engine, a 6.8-liter, 6-cylinder, natural gas engine. Engine power was well predicted in both engines, which is a prerequisite to accurate NOx predictions.

Engine tests are widely used to measure the ability of lubricating oils to reduce fuel consumption through improved mechanical efficiency. Previous publications have correlated laboratory-scale tests with the well-established Sequence VI and VIA engine methods. The present paper uses a matrix of 66 oils to produce an empirical model for the recently developed Sequence VIB engine test. A smaller matrix of oils was available for correlation with Sequence VI and VIA results. The models combine a purposely-designed friction test with conventional measures of kinematic and high-temperature high-shear viscosity. Good correlation was obtained with the Sequence VI, VIA and VIB results, as well as each of the five stages in the Sequence VIB test. The effects of lubricant oxidation in the 96-hour FEI-2 portion of the Sequence VIB test were similar for each of the oils. As a result, good correlation was observed between FEI-1 and FEI-2 results from the VIB test.

Atmospheric corrosion of steels, aluminum alloys, and Al-clad aluminum alloys is a problem for many civil engineering structures, commercial and military vehicles, and aircraft. Paint is usually the primary means to prevent the corrosion of steel bridge components, automobiles, trucks, and aircraft. Under ideal conditions, the coating provides a continuous layer that is impervious to moisture. At present, maintenance cycles for commercial and military aircraft and ground vehicles, as well as engineered structures, is based on experience and appearance rather than a quantitative determination of coating integrity. To improve the maintenance process and reduce costs, sensors are often used to monitor corrosion. The present suite of sensors designed to detect corrosion and marketed to predict the lifetime of the engineered components, however, are not useful for determining the condition of the protective paint coatings.

This paper describes the findings of a laboratory effort to demonstrate improved automotive exhaust emission control with a cold-start hydrocarbon collection system. The emission control strategy developed in this study incorporated a zeolite molecular sieve in the exhaust system to collect cold-start hydrocarbons for subsequent release to an active catalytic converter. A prototype emission control system was designed and tested on a gasoline-fueled vehicle. Continuous raw exhaust emission measurements upstream and downstream of the zeolite molecular sieve revealed collection, storage, and release of cold-start hydrocarbons. Federal Test Procedure (FTP) emission results show a 35 percent reduction in hydrocarbons emitted during the cold-transient segment (Bag 1) due to adsorption by the zeolite.

The measurement of piston temperature in a reciprocating engine has historically been a very time-consuming and expensive process. Several conditions exist in an engine that measurement equipment must be protected against. Acceleration forces near 2000 G's occur at TDC in automotive engines at rated speed. Operating temperatures inside the crankcase can range to near 150°C. To allow complete mapping of piston temperature, several measuring locations are required in the piston and data must be obtained at various engine operating conditions. Southwest Research Institute (SwRI) has developed a telemetry-based system that withstands the harsh environments mentioned above. The device is attached to the underside of a piston and temperature data is transmitted to a receiving antenna in the engine crankcase. The key element of this device is a tiny power generator which utilizes the reciprocating motion of the piston to generate electricity thus allowing the transmitter to be self-powered.

Exhaust emissions of non-methane hydrocarbon (NMHC) and methane were measured from a Tier 3 dual-fuel demonstration locomotive running diesel-natural gas blend. Measurements were performed with the typical flame ionization detector (FID) method in accordance with EPA CFR Title 40 Part 1065 and with an alternative Fourier-Transform Infrared (FTIR) Spectroscopy method. Measurements were performed with and without oxidation catalyst exhaust aftertreatment. FTIR may have potential for improved accuracy over the FID when NMHC is dominated by light hydrocarbons. In the dual fuel tests, the FTIR measurement was 1-4% higher than the FID measurement of. NMHC results between the two methods differed considerably, in some cases reporting concentrations as much as four times those of the FID. However, in comparing these data it is important to note that the FTIR method has several advantages over the FID method, so the differences do not necessarily represent error in the FTIR.

Biodiesel produced from soybean oil, canola oil, yellow grease, and beef tallow was tested in two heavy-duty engines. The biodiesels were tested neat and as 20% by volume blends with a 15 ppm sulfur petroleum-derived diesel fuel. The test engines were a 2002 Cummins ISB and 2003 DDC Series 60. Both engines met the 2004 U.S. emission standard of 2.5 g/bhp-h NOx+HC (3.35 g/kW-h) and utilized exhaust gas recirculation (EGR). All emission tests employed the heavy-duty transient procedure as specified in the U.S. Code of Federal Regulations. Reduction in PM emissions and increase in NOx emissions were observed for all biodiesels in all engines, confirming observations made in older engines. On average PM was reduced by 25% and NOx increased by 3% for the two engines tested for a variety of B20 blends. These changes are slightly larger in magnitude, but in the same range as observed in older engines.

The dual-fuel combustion process of ethanol and n-heptane was characterized experimentally in an optically accessible engine and numerically through a chemical kinetic 3D-CFD investigation. Previously reported formaldehyde PLIF distributions were used as a tracer of low-temperature oxidation of straight-chained hydrocarbons and the numerical results were observed to be in agreement with the experimental data. The numerical and experimental evidence suggests that a change in the speed of flame propagation is responsible for the observed behavior of the dual-fuel combustion, where the energy release duration is increased and the maximum rate of pressure rise is decreased. Further, an explanation is provided for the asymmetrical energy release profile reported in literature which has been previously attributed to an increase in the diffusion-controlled combustion phase.

Natural gas vehicle (NGV) fuel energy storage density is a key issue, particularly in many heavy-duty applications where compressed natural gas may have unattractively low energy density. For these uses, benefits can be derived by using liquefied natural gas (LNG). From a market perspective, LNG can play a role for transportation because it is available in various areas of the United States and throughout the world. This paper provides a general overview of LNG use for vehicles and specifically an analysis of factors governing the behavior of this cryogenic fluid in a confined vessel. This is intended to provide an understanding of the cause/effect relation between LNG fuel composition, tank heat influx, and rate of fuel usage or storage time.

Due to the serious need of the U.S. Army for a simple and rapid mobile fuel filtration system, a Filtration/Additive Unit (FAU) has been designed and fabricated. The primary use of the FAU is to aid in the cleanup of fuel in Army ground vehicles and equipment fuel cells and storage tanks. The FAU provides a simple and rapid means to remove gross quantities of particulate and water. The unit consists of a trailer-mounted filtration and additive system capable of dispensing three separate additives into the fuel. The FAU was designed to rapidly clean and additive-treat diesel or aviation-type fuels in volumes between 400 and 4500 liters. However, the FAU is capable of processing larger quantities, such as in storage tanks. The designed pump rate is 225 liters per minute (minimum) using diesel fuel at its maximum viscosity (4.1 cSt at 40°C).

Electromagnetic emissions (EME) from vehicles and their effect on broadcast radio and television were studied as early as 1944. Their original effect was significantly reduced by the early 1960s. Today, ignition noise (broadband) and vehicular micro-processor-controlled system noise (narrowband) are interfering with Land Mobile (two-way) communication services and other devices such as computers. Two SAE test methods, J551 and J1816, are used to measure this EME. Under development are methods to measure conducted EME on vehicle signal wiring and power input leads. This paper discusses EME measurement methods, provides insight into the sources of EME problems, and gives information on the test instrumentation used to make these measurements. This paper is the third in a series of papers on electromagnetic compatibility (EMC) in the off-highway vehicle. The first paper was an overview of a complete EMC program with discussion of several important segments.

Particle size distribution and number concentration were measured in the dilute exhaust of a heavy-duty diesel engine for steady-state and transient engine operation using two different dilution systems that included a full flow CVS that was coupled to an ejector pump (CVS-EP), and a double-ejector micro-dilution tunnel (DEMDT) that was connected to engine exhaust close to turbocharger outlet. Measurements were performed using a scanning mobility particle sizer (SMPS), an electrical low pressure impactor (ELPI), and a parallel flow diffusion battery (PFDB). Fuels with sulfur content of about 385 ppm and 1 ppm were used for this work. The PFDB performed well in measuring nanoparticles in the size range below 56 nm when compared with the SMPS. This was especially valid when a distinct log-normal size distribution in the size range below 56 nm in diameter, the upper size limit of the PFDB, was present.

This paper describes the development and evaluation of an operative catalyst for the reduction of NOx in lean exhaust. A catalyst that incorporates iron (II)-complex impregnated modified mesoporous molecular sieves (MCM-41) has been synthesized and further treated with [pd(NH3)4]Cl2 [1]. Experimental results suggest a hydrocarbon-independent reduction of NOx takes place on the iron center, and oxidation of CO is assisted by the palladium ion. The catalytic activity toward HC CO, and NOx removal was studied with simulated and real engine exhaust in the laboratory and on an engine, respectively. Engine test results demonstrate a reduction of NOx of up to 10 percent at catalyst inlet temperatures in the range of 260°C to 280°C. In this paper, possible NOx reduction pathways are also discussed.

The effect of humidity on the lean misfire limit and emissions from a lean burn, natural gas engine is described in this paper, along with a description of a practical humidity compensation method for incorporation into an electronic control system. Experiments to determine the effects of humidity on the lean limit and emissions are described. Humidity increases were shown to decrease the rate of combustion, reduce NOx emissions, and increase the levels of unburned hydrocarbon (HC) and carbon monoxide (CO) emissions. Data and calculations are also presented which demonstrate that increases in humidity will cause enleanment in a typical closed loop control system utilizing a universal exhaust gas oxygen (UEGO) sensor. A prototype system for humidity sensing and subsequent compensation based on these findings was implemented, and the system was found, through additional testing, to compensate for humidity very effectively.

This paper summarizes an investigation of reductions in exhaust emission levels attainable using various techniques appropriate to gasoline engines used in vehicles over 14,000 lbs GVW. Of the eight gasoline engines investigated, two were evaluated parametrically resulting in an oxidation and reduction catalyst “best combination” configuration. Four of the engines were evaluated in an EGR plus oxidation catalyst configuration, and two involved only baseline tests. Test procedures used in evaluating the six “best combination” configurations include: three engine emission test procedures using an engine dynamometer, a determination of vehicle driveability, and two vehicle emission test procedures using a chassis dynamometer. Dramatic reductions in emissions were attained with the catalyst “best combination” configurations. Engine durability, however, was not investigated.

A technique for evaluating high temperature oxidation and corrosion tendencies of automotive crankcase lubricants is described. The technique utilizes a versatile bench apparatus which, with a minimum of modification, can be used for either evaluating thermal oxidation stability of gear lubricants or oxidation-corrosion tendencies of automotive crankcase lubricants. The apparatus is relatively compact and requires a minimal lubricant sample. Design of the apparatus permits close control of all operating parameters and provides satisfactory test data repeatability. Retainable copper-lead test bearings are used as the indicator in predicting a pass or fail of fully formulated crankcase lubricants as in the case of the CRC L-38-559 (Federal Test Method 3405) technique. Engine and bench test data are compared to illustrate the capabilities of this new bench technique.