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The Hybrid Electric Vehicle Team of Virginia Tech participated in the three-year EcoCAR Advanced Vehicle Technology Competition organized by Argonne National Laboratory, and sponsored by General Motors and the U.S. Department of Energy. The team established goals for the design of a plug-in, range-extended hybrid electric vehicle that meets or exceeds the competition requirements for EcoCAR. The challenge involved designing a crossover SUV powertrain to reduce fuel consumption, petroleum energy use, regulated tailpipe emissions, and well-to-wheel greenhouse gas emissions. To interface with and control the hybrid powertrain, the team added a Hybrid Vehicle Supervisory Controller, which enacts a torque split control strategy. This paper builds on an earlier paper [1] that evaluated the petroleum energy use, criteria tailpipe emissions, and greenhouse gas emissions of the Virginia Tech EcoCAR vehicle and control strategy from the 2nd year of the competition.

Low temperature combustion through in-cylinder blending of fuels with different reactivity offers the potential to improve engine efficiency while yielding low engine-out NOx and soot emissions. A Navistar MaxxForce 13 heavy-duty compression ignition engine was modified to run with two separate fuel systems, aiming to utilize fuel reactivity to demonstrate a technical path towards high engine efficiency. The dual-fuel engine has a geometric compression ratio of 14 and uses sequential, multi-port-injection of a low reactivity fuel in combination with in-cylinder direct injection of diesel. Through control of in-cylinder charge reactivity and reactivity stratification, the engine combustion process can be tailored towards high efficiency and low engine-out emissions. Engine testing was conducted at 1200 rpm over a load sweep.

Controlled Auto-Ignition (CAI) combustion can effectively improve the thermal efficiency of conventional spark ignition (SI) gasoline engines, due to shortened combustion processes caused by multi-point auto-ignition. However, its commercial application is limited by the difficulties in controlling ignition timing and violent heat release process at high loads. Stratified flame ignited (SFI) hybrid combustion, a concept in which rich mixture around spark plug is consumed by flame propagation after spark ignition and the unburned lean mixture closing to cylinder wall auto-ignites in the increasing in-cylinder temperature during flame propagation, was proposed to overcome these challenges.

The study of spray-wall interaction is of great importance to understand the dynamics that occur during fuel impingement onto the chamber wall or piston surfaces in internal combustion engines. It is found that the maximum spreading length of an impinged droplet can provide a quantitative estimation of heat transfer and energy transformation for spray-wall interaction. Furthermore, it influences the air-fuel mixing and hydrocarbon and particle emissions at combusting conditions. In this paper, an analytical model of a single diesel droplet impinging on the wall with different inclined angles (α) is developed in terms of βm (dimensionless maximum spreading length, the ratio of maximum spreading length to initial droplet diameter) to understand the detailed impinging dynamic process.

Lean-burn combustion is an effective method for increasing the thermal efficiency of gasoline engines fueled with stoichiometric fuel-air mixture, but leads to an unacceptable level of high cyclic variability before reaching ultra-low nitrogen oxide (NOx) emissions emitted from conventional gasoline engines. Multi-point micro-flame ignited (MFI) hybrid combustion was proposed to overcome this problem, and can be can be grouped into double-peak type, ramp type and trapezoid type with very low frequency of appearance. This research investigates the micro-flame ignition stages of double-peak type and ramp type MFI combustion captured by high speed photography. The results show that large flame is formed by the fast propagation of multi-point flame occurring in the central zone of the cylinder in the double-peak type. However, the multiple flame sites occur around the cylinder, and then gradually propagate and form a large flame accelerated by the independent small flame in the ramp type.

The dual-fuel Reactivity Controlled Compression Ignition (RCCI) combustion could achieve high efficiency and low emissions over a wide range of operating conditions. However, further high load extension is limited by the excessive pressure rise rate and soot emission. Polyoxymethylene dimethyl ethers (PODE), a novel diesel alternative fuel, has the capability to achieve stoichiometric smoke-free RCCI combustion due to its high oxygen content and unique molecule structure. In this study, experimental investigations on high load extension of gasoline/PODE RCCI operation were conducted using late intake valve closing (LIVC) strategy and intake boosting in a single-cylinder, heavy-duty diesel engine. The experimental results show that the upper load can be effectively extended through boosting and LIVC with gasoline/PODE stoichiometric operation.

Lean NOx trap (LNT) is a great potential NOx abatement method for lean-burn gasoline engines in consideration of exhaust aftertreatment cost and installation space. NOx firstly is adsorbed on storage sites during the lean-burn period, then reduced to N2 under catalysis of the catalyst sites in the rich-burn phase. There must be a spillover of NOx species between both types of sites. For a better understanding of this spillover process of NOx species between Pt (as the catalytic center) and BaO sites (as storage components in commercial catalyst), this work focused on the vital first step of spillover, the adsorption of NOx on clean substrate surface (γ-Al2O3 (110) surface) and Ba\Pt cluster supported by the surface. Based on first principles software VASP (Vienna Ab-initio Simulation Package), the most stable adsorption structures of NO with Pt3 clusters and (BaO)3 clusters on carrier γ- Al2O3 (110) surface were confirmed and the adsorption energy of these structures were compared.

Striving for sustainable transportation solutions, hydrogen is often identified as a promising energy carrier and internal combustion engines are seen as a cost effective consumer of hydrogen to facilitate the development of a large-scale hydrogen infrastructure. Driven by efficiency and emissions targets defined by the U.S. Department of Energy, a research team at Argonne National Laboratory has worked on optimizing a spark-ignited direct injection engine for hydrogen. Using direct injection improves volumetric efficiency and provides the opportunity to properly stratify the fuel-air mixture in-cylinder. Collaborative 3D-CFD and experimental efforts have focused on optimizing the mixture stratification and have demonstrated the potential for high engine efficiency with low NOx emissions. Performance of the hydrogen engine is evaluated in this paper over a speed range from 1000 to 3000 RPM and a load range from 1.7 to 14.3 bar BMEP.

The combustion and emission characteristics of a diesel engine running on butanol-diesel blends were investigated in this study. The blending ratio of n-butanol to diesel was varied from 0 to 40 vol% using an increment of 10 vol%, and each blend was tested on a 2.7 L V6 common rail direction injection diesel engine equipped with an EGR system. The test was carried out under two engine loads at a constant engine speed, using various combinations of EGR ratios and injection timings. Test results indicate that n-butanol addition to engine fuel is able to substantially decrease soot emission from raw exhaust gas, while the change in NOx emissions varies depending on the n-butanol content and engine operating conditions. Increasing EGR ratio and retarding injection timing are effective approaches to reduce NOx emissions from combustion of n-butanol-diesel blends.

Detailed diesel particulates morphology, nanostructures, fractal geometry, and nitrogen oxides (NOx) emissions were analyzed for five different test fuels in a 1.7-L, common-rail direct-injection diesel engine. The accurately formulated fuels permit the effects of sulfur, paraffins, aromatics, and naphthene concentrations to be determined. A novel thermophoretic sampling technique was used to collect particulates immediately after the exhaust valves. The morphology and nanostructures of particulate samples were examined, imaged with a high-resolution transmission electron microscope (HRTEM), and quantitatively analyzed with customized digital image processing/data acquisition systems. The results show that the particle sizes and the total mass of particulate matter (PM) emissions correlate most strongly with the fuels' aromatics and sulfur content.

In order to achieve the targets for hydrogen engines set by the U.S. Department of Energy (DOE) - a brake thermal efficiency of 45% and nitrogen oxide (NOx) emissions below 0.07 g/mi - while maintaining the same power density as comparable gasoline engines, researchers need to investigate advanced mixture formation and combustion strategies for hydrogen internal combustion engines. Hydrogen direct injection is a very promising approach to meeting DOE targets; however, there are several challenges to be overcome in order to establish this technology as a viable pathway toward a sustainable hydrogen infrastructure. This paper describes the use of endoscopic imaging as a diagnostic tool that allows further insight into the processes that occur during hydrogen combustion. It also addresses recent progress in the development of advanced direct-injected hydrogen internal combustion engine concepts.

This paper evaluates the total lifecycle impacts for hauling freight long distances over land in the United States. The dominant modes of surface freight transport in the United States are large motor trucks (tractor-semitrailer combinations) and trains. These vehicles account for a significant portion of the transportation sector's petroleum usage and atmospheric emissions (among which nitrogen oxides and particulate matter are especially important). The objective of this paper is to evaluate the potential for reductions in energy use (in particular, petroleum use) and atmospheric emissions that result from freight transport, possibly as the result of research and development on improved technology or alternative fuels, such as Fischer-Tropsch diesel and natural gas, or from mode shifts in competitive markets. The impacts examined include energy use, both in toto and the petroleum fraction, and emissions of greenhouse gases and nitrogen oxides and particulate matter.

The potential exists to displace a portion of the petroleum diesel demand with butanol and positively impact engine-out particulate matter. As a preliminary investigation, 20% and 40% by volume blends of butanol with ultra low sulfur diesel fuel were operated in a 1999 Mercedes Benz C220 turbo diesel vehicle (Euro III compliant). Cold and hot start urban as well as highway drive cycle tests were performed for the two blends of butanol and compared to diesel fuel. In addition, 35 MPH and 55 MPH steady-state tests were conducted under varying road loads for the two fuel blends. Exhaust gas emissions, fuel consumption, and intake and exhaust temperatures were acquired for each test condition. Filter smoke numbers were also acquired during the steady-state tests. The results showed that for the urban drive cycle, both total hydrocarbon (THC) and carbon monoxide (CO) emissions increased as larger quantities of butanol were added to the diesel fuel.

This paper reports on research activities aiming to improve the efficiency of direct injected, hydrogen powered internal combustion engines. In a recent major change in the experimental setup the hydrogen single cylinder research engine at Argonne National Laboratory was upgraded to a new engine geometry providing increased compression ratio and a longer piston stroke compared to its predecessor. The higher compression ratio and the more advantageous volume to surface ratio of the combustion chamber are both intended to improve the overall efficiency of the experimental setup. Additionally, a new series of faster acting, piezo-activated injectors is used with the new engine providing increased flexibility for the optimization of DI injection strategies. This study focuses on the comparison of experimental data of the baseline versus the improved single cylinder research engine for similar engine operating conditions.

Different blends of gasoline range hydrocarbons were investigated to determine the effect of aromatic, naphthenic, and paraffinic content on performance in an autothermal reformer. In addition, we investigated the effects of detergent, antioxidant, and oxygenate additives. These tests indicate that composition effects are minimal at temperatures of 800°C and above, but at lower temperatures or at high gas hourly space velocities (GHSV approaching 100,000 h-1) composition can have a large effect on catalyst performance. Fuels high in aromatic and naphthenic components were more difficult to reform. In addition, additives, such as detergents and oxygenates were shown to decrease reformer performance at lower temperatures.

Piston wetting can be isolated from the other sources of HC emissions from DISI engines by operating the engine predominantly on a gaseous fuel and using an injector probe to impact a small amount of liquid fuel on the piston top. This results in a marked increase in HC emissions. All of our prior tests with the injector probe used California Phase 2 reformulated gasoline as the liquid fuel. In the present study, a variety of pure liquid hydrocarbon fuels are used to examine the influence of fuel volatility and structure. Additionally, the exhaust hydrocarbons are speciated to differentiate between the emissions resulting from the gaseous fuel and those resulting from the liquid fuel. It is shown that the HC emissions correspond to the Leidenfrost effect: fuels with very low boiling points yield high HCs and those with a boiling point near or above the piston temperature produce much lower HCs.

Piston wetting can be isolated from the other sources of HC emissions from DISI engines by operating the engine predominantly on a gaseous fuel and using an injector probe to impact a small amount of liquid fuel on the piston top. This results in a marked increase in HC emissions. In a previous study, we used a variety of pure liquid hydrocarbon fuels to examine the influence of fuel volatility and structure on the HC emissions due to piston wetting. It was shown that the HC emissions correspond to the Leidenfrost effect: fuels with very low boiling points yield high HCs and those with a boiling point near or above the piston temperature produce much lower HCs. All of these prior tests of fuel effects were performed at a single operating condition: the Ford World Wide Mapping Point (WWMP). In the present study, the effects of load and engine speed are examined.

Particulate and nitrogen oxide emissions from a 1.9-liter Volkswagen diesel engine were measured for three different fuels: neat diesel fuel, a blend of diesel fuel with 10% ethanol, and a blend of diesel fuel with 15% ethanol. Engine-out emissions were measured on an engine dynamometer for five different speeds and five different torques using the standard engine-control unit. Results show that particulate emissions can be significantly reduced over approximately two-thirds of the engine map by using a diesel-ethanol blend. Nitrogen oxide emissions can also be significantly reduced over a smaller portion of the engine map by using a diesel-ethanol blend. Moreover, there is an overlap between the regions where particulate emissions can be reduced by up to 75% and nitrogen oxide emissions are reduced by up to 84% compared with neat diesel fuel.

Hybrid electric vehicles (HEVs) may have key fuel economy and emissions advantages over current conventional vehicles, but they have drawbacks such as frequent engine starts that can slow down market penetration of HEVs. First, the hydrocarbon emissions due to the numerous engine starts would make newly developed HEV powertrains even more demanding on the emission control system. Second, frequent starts may make the engine deteriorate quickly. This study is an attempt to gain a better understanding of the engine start characteristics of two limited-production HEVs (Toyota Prius and Honda Insight). Using fast-response (5 ms) hydrocarbon and NO (nitric oxide) analyzers, the transient emissions were measured in the engine exhaust ports during cold and hot engine starts. On the basis of the experimental findings, several recommendations were made to improve performance and emissions of future HEVs.

The combustion in low-speed two-stroke marine diesel engines can be characterized as large spatial and temporal scales combustion. One of the most effective measures to reduce NOx emissions is to reduce the local maximum combustion temperature. In the current study, multi-dimensional numerical simulations have been conducted to explore the potential of Miller cycle, high compression ratio coupled with EGR (Exhaust Gas Recirculation) and WEF (water emulsified fuel) to improve the trade-off relationship of NOx-ISFC (indicated specific fuel consumption) in a low-speed two-stroke marine engine. The results show that the EGR ratio could be reduced combined with WEF to meet the Tier III emission regulation. The penalty on fuel consumption with EGR and WEF could be offset by Miller cycle and high geometric compression ratio.