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Based on the temperature and pressure in the cylinder of GDI (Gasoline Direct Injection) engines under the common operating conditions, jets´ characteristics of gasoline and iso-octane at different fuel temperatures under the high ambient temperature were studied by means of high-speed photography and striation method. It is found that the supercritical gasoline jet shows the morphological collapse of jet center and the protrusion of the front surface, but the iso-octane jet doesn´t. Meanwhile, as the fuel temperature rises, the flash boiling and the interference between adjacent plumes affect the gasoline jet, and cause the center of the jet to form a high-speed and low-pressure zone, hence the air entrainment in this region contributes to the collapse of jets. The collapse and convergence of jets´ morphology are the main reasons for the change of penetration and cone angle.