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Battery models are often applied to describe the dynamic characteristics of batteries and can be used to predict the state of the battery. Due to the process of charging and discharging, the battery heat generation will cause the inhomogeneity between inner battery temperature and surface temperature. In this paper, a novel battery impedance model, which takes the impact of the battery internal temperature gradient on battery impedance into account, is proposed to improve the battery model performance. Several experiments are designed and conducted for pouch typed battery to investigate the electrochemical impedance spectroscopy (EIS) characteristics with the artificial temperature gradient (using a heating plate). Experimental results indicate that the battery internal temperature gradient will influence battery EIS regularly.

With the continuous popularization of electric vehicles (EVs), ensuring the best performance of EVs has become a significant concern, and lithium-ion power batteries are considered as the essential storage and conversion equipment for EVs. Therefore, it is of great significance to quickly evaluate the state of power batteries. This paper investigates a fast state estimation method of power batteries oriented to after-sales and maintenance. Based on the battery equivalent circuit model and heuristics optimization algorithm, the battery model parameters, including the internal ohmic and polarization resistance, can be identified using only 30 minutes of charging or discharging process data without full charge or discharge. At the same time, the proposed method can directly estimate the state of charge (SOC) and maximum available capacity of the battery without knowing initial SOC information.