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Recent toxicological and epidemiologic studies have shown that diesel emissions have been a significant toxic air contaminant. Catalyzed DPF (CDPF) not only significantly reduces the PM mass emissions (>90%), but also further promotes carrier self-regeneration and oxidize more harmful gaseous pollutants by the catalyst coated on the carrier. However, some ultrafine particles and potentially harmful gaseous pollutants, such as VOCs species, originally emitted in the vapor-phase at high plume temperature, may penetrate through the CDPF filter. Furthermore, the components and content of catalyst coated on the CDPF could influence the physicochemical properties and toxicity intensity of those escaping ultrafine particles and gaseous pollutants. In this work, (1) we investigated the influence of precious metal content as a variable parameter on the physicochemical properties and catalytic activities of the small CDPF samples.

In this study, effects of altitude on free diesel spray morphology, macroscopic spray characteristics and air-fuel mixing process were investigated. The diesel spray visualization experiment using high-speed photography was performed in a constant volume chamber which reproduced the injection diesel-like thermodynamic conditions of a heavy-duty turbocharged diesel engine operating at sea level and 1000 m, 2000 m, 3000 m and 4500 m above sea level. The results showed that the spray morphology became narrower and longer at higher altitude, and small vortex-like structures were observed on the downstream spray periphery. Spray penetration increased and spray angle decreased with increasing altitude. At altitudes of 0 m, 1000 m, 2000 m, 3000 m and 4500 m, the spray penetration at 1.45 ms after start of injection (ASOI) were 79.54 mm, 80.51 mm, 81.49 mm, 83.29 mm and 88.92 mm respectively, and the spray angle were 10.9°, 10.8°, 10.7°, 10.4°and 9.8° respectively.

The diesel particulate filter (DPF) is an effective device for reducing particulate emissions from diesel engines, while its durability and reliability after long-term use are causes for concern. Usually, particulates are considered to be uniformly deposited in DPF channels to form a cake or end plug, however, recent studies have found that a “middle channel deposit” phenomenon of particulates can form a bridge near the middle of the DPF channel. This phenomenon has serious adverse effects on the durability and reliability of the DPF, including abnormally increased pressure drop and frequent regeneration. Since the width of the DPF channel is only about 1-2 millimeters, conventional methods cannot observe the particulate deposition process inside the DPF.