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The argon power cycle engine, which uses hydrogen as fuel, oxygen as oxidant, and argon other than nitrogen as the working fluid, is considered as a novel concept of zero-emission and high-efficiency system. Due to the extremely high in-cylinder temperature caused by the lower specific heat capacity of argon, the compression ratio of spark-ignition argon power cycle engine is limited by preignition or super-knock. Compression-ignition with direct-injection is one of the potential methods to overcome this challenge. Therefore, a detailed flammability limit of H2 under Ar-O2 atmosphere is essential for better understanding of stable autoignition in compression-ignition argon power cycle engines.

Argon power cycle hydrogen engine is an internal combustion engine that employs argon instead of nitrogen of air as the working fluid, oxygen as the oxidizer, and hydrogen as the fuel. Since argon has a higher specific heat ratio than air, argon power cycle hydrogen engines have theoretically higher indicated thermal efficiencies according to the Otto cycle efficiency formula. However, argon makes the end mixture more susceptible to spontaneous combustion and thus is accompanied by a stronger knock at a lower compression ratio, thus limiting the improvement of thermal efficiency in engine operation. In order to suppress the limitation of knock on the thermal efficiency, this paper adopts a combination of experimental and simulation methods to investigate the effects of port water injection on the knock suppression and combustion characteristics of an argon power cycle hydrogen engine.