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With regulatory standards for diesel engine emissions becoming stricter worldwide, integrated catalytic systems are becoming increasingly necessary. One of the better approaches is to use an after-treatment system consisting of a diesel oxidation catalyst (DOC), a catalyzed diesel particulate filter (CDPF), and a selective catalytic reduction (SCR), but many factors can affect how well this system works. This study investigates the effects of DOC and CDPF catalyst composition on emissions characteristics for DOC + CDPF + SCR systems by collecting reactor and engine data. The reactor results show that the light-off temperatures (T50) of CO and C3H6 increase with the growth of Pt:Pd ratio while the T50 of NO degrades. An engine dynamometer test was conducted on a light-duty diesel engine equipped with DOC + CDPF + SCR. The results show light-off curves of CO and THC that are smoother than the reactor data.

The diesel particulate filter (DPF) is an effective device for reducing particulate emissions from diesel engines, while its durability and reliability after long-term use are causes for concern. Usually, particulates are considered to be uniformly deposited in DPF channels to form a cake or end plug, however, recent studies have found that a “middle channel deposit” phenomenon of particulates can form a bridge near the middle of the DPF channel. This phenomenon has serious adverse effects on the durability and reliability of the DPF, including abnormally increased pressure drop and frequent regeneration. Since the width of the DPF channel is only about 1-2 millimeters, conventional methods cannot observe the particulate deposition process inside the DPF.

The catalyzed diesel particulate filter with Pt and Pd noble metals as the main loaded active components are widely used in the field of automobile engines, but the high cost makes it face huge challenges. Rare earth element doping can improve the soot oxidation performance of the catalyzed diesel particulate filter and provide a new way to reduce its cost. In this paper, thermogravimetric tests and chemical reaction kinetic calculations were used to explore the effect of Pt-Pd catalysts doped Ce, and La rare earth elements on the oxidation properties of soot. The results shown that, among Pt-Pd-5%Ce, Pt-Pd-5%La, and Pt-Pd-5%Ce-5%La catalysts, Pt-Pd-5%La catalyst has the highest soot conversion, the highest low-temperature oxidation speed, and the activation energy is the smallest. Compared with soot, this catalyst reduced T10 and T20 by 82% and 26%, respectively, meaning the catalytic activity of Pt-Pd-5%La catalyst was the best.