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The details of Di-Air, a new NOx reduction system using continuous short pulse injections of hydrocarbons (HC) in front of a NOx storage and reduction (NSR) catalyst, have already been reported. This paper describes further studies into the deNOx mechanism, mainly from the standpoint of the contribution of HC and intermediates. In the process of a preliminary survey regarding HC oxidation behavior at the moment of injection, it was found that HC have unique advantages as a reductant. The addition of HC lead to the reduction or metallization of platinum group metals (PGM) while keeping the overall gas atmosphere in a lean state due to adsorbed HC. This causes local O₂ inhibition and generates reductive intermediate species such as R-NCO. Therefore, the specific benefits of HC were analyzed from the viewpoints of 1) the impact on the PGM state, 2) the characterization of intermediate species, and 3) Di-Air performance compared to other reductants.

High-pressure metal hydride (MH) tank has been designed based on a 35 MPa cylinder vessel. The heat exchanger module is integrated into the tank. Its advantage over high-pressure cylinder vessels is its large hydrogen storage capacity, for example 9.5 kg with a tank volume of 180 L by Ti25Cr50V20Mo5 alloy. Cruising range is about 900 km, over 3 times longer than that of a 35 MPa cylinder vessel system with the same volume. The hydrogen-charging rate of this system is equal to the 35 MPa cylinders without any external cooling facility. And release of hydrogen at 243 K is enabled due to the use of hydrogen-absorbing alloy with high-dissociation pressure, for example Ti35Cr34Mn31 alloy.

In order to enhance the catalytic performance of the NOx Storage-Reduction Catalyst (NSR Catalyst), the sulfur tolerance of the NSR catalyst was improved by developing new support and NOx storage materials. The support material was developed by nano-particle mixing of ZrO2-TiO2 and Al2O3 in order to increase the Al2O3-TiO2 interface and to prevent the ZrO2-TiO2 phase from sintering. A Ba-Ti oxide composite material was also developed as a new NOx storage material containing highly dispersed Ba. It was confirmed that the sulfur tolerance and activity of the developed NSR catalyst are superior to that of the conventional one.

There is ever increasing interest in the issues of fossil fuel depletion, global warming, due to increased atmospheric CO2, and air pollution, all of which are due in some extent to transportation, including automobiles. Hybrid Vehicles (HVs), whose performance and usage are equivalent to existing conventional vehicles, attract lots of attention and have started to come into wider use. Meanwhile, EVs have been considered by many as the best solution for the issues mentioned above. But the technical difficulty of battery energy density is an obstruction to successful implementation. Currently the Plug-in HV (PHEV), which combines the advantages of HV and EV, is being considered as one promising solution. PHEVs can be categorized into two types, according to operating modes. The first uses battery stored energy initially, only stating the internal combustion engine when the battery is depleted. This we call the All Electric Range (AER) system.

Stringent emission regulations call for advanced catalyst substrates with thinner walls and higher cell density. However, substrates with higher cell density increase backpressure, thinner cell wall substrates have lower mechanical characteristics. Therefore we will focus on cell configurations that will show a positive effect on backpressure and emission performance. We found that hexagonal cells have a greater effect on emission and backpressure performance versus square or round cell configurations. This paper will describe in detail the advantage of hexagonal cell configuration versus round or square configurations with respect to the following features: 1 High Oxygen Storage Capacity (OSC) performance due to uniformity of the catalyst coating layer 2 Low backpressure due to the large hydraulic diameter of the catalyst cell 3 Quick light off characteristics due to efficient heat transfer and low thermal mass

Three-way catalyst shows high performance under stoichiometric atmosphere. The CeO2-ZrO2 based materials (CZ) are added as a buffer of O2 concentration. To improve the catalyst performance the larger O2 storage capacity (OSC) are needed. Theoretically, the sulfur oxidation-reduction reaction moves oxygen 8 times larger than cerium. We focused on this phenomenon and synthesized Ln2O2SO4 as a new OSC material. The experimental result under model gas shows that the OSC of Ln2O2SO4 is 5 times lager than CZ.

Previous studies have investigated the impacts of biofuel usage on the performance, drivability and durability of modern diesel engines and exhaust after-treatment systems including test work with different types, concentrations and mixtures of bio fuel components. During this earlier work vehicle fuel filter blocking issues were encountered during a field trial using various types of EN 14214 compliant Fatty Acid Methyl Ester (FAME) blended into EN 590 diesel. This paper summarises a subsequent literature review that was carried out looking into potential causes of this filter blocking and further work that was then carried out to expand on the findings. From this, a laboratory study was carried out to assess the increase in fuel filter blocking tendency (FBT) when various FAMEs from mixed sources were blended into EN 590 diesel at different concentrations, including levels above those currently allowed in the European market.

We developed a high performance automotive lithium-ion battery and applied it to our new Toyota Intelligent Idling Stop System. This hybrid power management system has been introduced in the “intelligent package” of Toyota Vitz vehicles sold in Japan. The lithium-ion battery is installed under the seat on the passenger-side. The battery supplies electric power to the auxiliary electrical systems during the “idling stop” mode, and when restarting the engine. The main requirements of this battery are to supply high electric power output even at low temperatures and at the same time, maintain continuous power during charge and discharge cycling, and have long storage life. This performance has been accomplished successfully through a series of improvements in battery materials and structures.

Toyota Motor Corporation began leasing a new generation fuel cell vehicle the FCHV (Fuel Cell Hybrid Vehicle) in December 2002. That vehicle includes a new variable voltage power electronics system and uses the Nickel Metal Hydride (Ni-MH) battery system from the Prius hybrid gasoline electric vehicle. This paper describes on-going efforts to model optimum secondary storage systems for future vehicles. Efficiency modeling is presented for the base Ni-MH storage system, an ultra capacitor system and a Lithium ion (Li-ion) battery system. The Li-ion system in combination with a new high efficiency converter shows a 4% improvement in fuel economy relative to the base system. The ultra capacitor system is not as efficient as the base system.

By using analytical techniques (FT-IR, TG-MS, ICP) and DFT calculations, the potassium (K) used as a storage component in NOx Catalysts can be analyzed. The results from this study show that the, K exists as K2CO3, and that the amount, molecular structure, and thermal stability of K2CO3 are different, depending on the support material (ZrO2, Al2O3, or TiO2). If the amount of K that interacts with the support to form an inactive complex oxide is decreased, the amount of K2CO3 and NOx storage is increased. The amount of the inactive K varies with the basicity of the supports. K2CO3 that exists in unstable structures on the supports can be easy to react with NOx to form the nitrate. So, the higher the quantity of unstable K2CO3, the higher the NOx storage capacity. Based on these results, a development guideline was proposed to improve the NOx storage performance.

In order to further improve the performance of NOx storage-reduction catalysts (NSR catalysts), focus was placed on their high temperature performance deterioration via sulfur poisoning and heat deterioration. The reactions between the basicity or acidity of supports and the storage element, potassium, were analyzed. It was determined that the high temperature performance of NSR catalysts is enhanced by the interaction between potassium and zirconia, which is a basic metal oxide. Also, a new zirconia-titania complex metal oxides was developed to improve high temperature performance and to promote the desorption of sulfur from the supports after aging.

A new after-treatment system called DPNR (Diesel Particulate-NOx Reduction System) has been developed for simultaneous and continuous reduction of particulate matter (PM) and nitrogen oxides (NOx) in diesel exhaust gas. This system consists of both a new catalytic technology and a new diesel combustion technology which enables rich operating conditions in diesel engines. The catalytic converter for the DPNR has a newly developed porous ceramic structure coated with a NOx storage reduction catalyst. A fresh DPNR catalyst reduced more than 80 % of both PM and NOx. This paper describes the concept and performance of the system in detail. Especially, the details of the PM oxidation mechanism in DPNR are described.

We studied the adoption of plastics derived from plants (bioplastics) such as poly(lactic acid) (PLA) for automotive parts in order to contribute to suppressing the increase in CO, emissions. For this application. major improvements of heat and impact resistance are needed. As a method to improve heat resistance, we developed PLA combined with clay of high heat resistance. As a result. we succeeded in synthesizing a PLA-clay nanocomposite using 18(OH)2-Mont. In-mold crystallization of PLA-clay nanocomposite lead to the great suppression of storage modulus decrease at high temperature. which in turn improved the heat resistance of PLA.

Introducing effective technologies to reduce carbon emissions in the transport sector is a critical issue for automotive manufacturers to contribute to sustainable development. Unlike the plug-in electric vehicles (PEVs), whose effectiveness is dependent on the carbon intensity of grid electricity, the solar hybrid vehicle (SHV) can be an alternative electric vehicle because of its off-grid, zero-emission electric technology. Its usability is also advantageous because it does not require manual charging by the users. This study aims at evaluating the economic, environmental, and usability benefits of SHV by comparing it with other types of vehicles including PEVs. By setting cost and energy efficiency on the basis of the assumed technology level in 2030, annual cost and annual CO2 emissions of each vehicle are calculated using the daily mileage pattern obtained from a user survey of 5,000 people in Japan and the daily radiation data for each corresponding user.

In recent years, automakers have been developing various types of environmentally friendly vehicles such as hybrid (HV), plug-in hybrid (PHV), electric (EV), and fuel cell (FCV) vehicles to help reduce greenhouse gas (GHG) emissions. However, there are few commercial solar vehicles on the market. One of the reasons why automakers have not focused attention on this area is because the benefits of installing solar modules on vehicles under real conditions are unclear. There are two difficulties in measuring the benefits of installing solar modules on vehicles: (1) vehicles travel under various conditions of sunlight exposure and (2) sunlight exposure conditions differ in each region. To address these problems, an analysis was performed based on an internet survey of 5,000 people and publically available meteorological data from 48 observation stations in Japan.

This paper presents a new application of a vehicle on-board battery charger utilizing high frequency Silicon Carbide (SiC) power devices. SiC is one of the most promising alternatives to Silicon (Si) for power semiconductor devices due to its superior material characteristics such as lower on-state resistance, higher junction temperature, and higher switching frequency. An on-board charger prototype is developed demonstrating these advantages and a peak system efficiency of 95% is measured while operating with a switching frequency of 250 kHz. A maximum output power of 6.06 kW results in a gravimetric power density of 3.8 W/kg and a volumetric power density of 5.0 kW/L, which are about 10 times the densities compared with the current Prius Plug-In Si charger. SiC technology is indispensable to eco-friendly PHV/EV development.

Toyota introduced the first generation Prius in 1997. The vehicle was conceived, designed and launched as a dedicated, mass-produced global hybrid vehicle platform, the first of its kind. The introduction of the 2nd and 3rd generation Prius (2003, 2009) saw vehicles with significantly improved performance, including fuel efficiency. The Prius Alpha (Japan/EU), launched in 2011, represented Toyota first foray with Li-ion battery in a strong hybrid configuration. For the Prius Alpha, the adoption of a compact Li-ion battery resulted in sufficient cabin space to allow a 3rd row of seats while maintaining high fuel efficiency. Before and after the launch of the Prius Alpha, an extensive list of tests was performed on the Li-ion battery pack, including electrical, electrochemical, mechanical, and safety. The evaluations were performed in the lab, in the field (demonstration fleets) and by acquiring vehicles used by customers.

Toyota has been introducing several hybrid vehicles (HV) as a countermeasure to concerns related to the automotive mobility like CO2 reduction, energy security, and emission reduction in urban areas. A next step towards an even more effective solution for these concerns is a plug-in hybrid vehicle (PHV). This vehicle combines the advantages of electric vehicles (EV), which can use clean electric energy, and HV with it's high environmental potential and user-friendliness comparable to conventional vehicles such as a long cruising range. This paper describes a newly developed plug-in hybrid system and its vehicle performance. This system uses a Li-ion battery with high energy density and has an EV-range within usual trip length without sacrificing cabin space. The vehicle achieves a CO2 emission of 59g/km and meets the most stringent emission regulations in the world. The new PHV is a forerunner of the large-scale mass production PHV which will be introduced in two years.

Toyota has been introducing several hybrid vehicles (HV) since 1997 as a countermeasure to the concerns raised by automobile, like CO2 reduction, energy security, and pollutant emission reduction in urban areas. Plug in hybrid Vehicle (PHV) uses electric energy from grid rather than fuel for most short trips and therefore presents a next step forward towards an even more effective solution for these concerns. For longer trips, the PHV works as a conventional hybrid vehicle, providing all the benefits of Toyota full hybrid technology, such as low fuel consumption, user-friendliness and long cruising range. This paper describes a newly developed plug-in hybrid system and its vehicle performance. This system uses a Li-ion battery with high energy density and has an EV-range within usual trip length without sacrificing cabin space.

In recent years, many various energy sources have been investigated as replacements for traditional automotive fossil fuels to help reduce CO₂ emissions, respond to instabilities in the supply of fossil fuels, and reduce emissions of air pollutants in urban areas. Toyota Motor Corporation considers the plug-in hybrid vehicle, which can use electricity efficiently, to be the most practical current solution to these issues. For this reason, Toyota began sales of the Prius plug-in hybrid in early 2012 in both the U.S. and Japan. This is the first plug-in hybrid vehicle to be mass-produced by Toyota Motor Corporation. Prior to this, in December 2009, Toyota sold 650 plug-in hybrid vehicles through lease programs for verification testing in the U.S., Europe, and Japan. The system of the recently launched mass-produced vehicle underwent major improvements in response to the results of this verification testing. As a result, EV range was increased with a smaller battery.