Search Results

A newly-developed time resolved exhaust gas analysis system was utilized in this study. The hydrocarbon compositions upstream and downstream of the catalytic converter were investigated during cold start and warm up of the Federal Test Procedure(FTP), with three fuels of different aromatic contents. Although engine-out hydrocarbon emissions had high concentrations right after cold start, the specific reactivity was low. This can be explained by the selective adsorption of the high boiling point components which had a high Maximum Incremental Reactivity (MIR) in the intake manifold and engine-oil films. Thereafter, the high boiling point components were desorbed rapidly and consequently specific reactivity increased. Hydrocarbon adsorption of high boiling point components and hydrocarbon conversion of low boiling point components occurred simultaneously on the catalyst during warm up.

A new proportional collection system for extremely low tailpipe emission measurement in transient conditions has been developed. The new system can continuously sample a minute flow of exhaust gas, at a rate that is proportional to the engine exhaust rate. A zero grade gas dilution technique is utilized to prevent the influence of pollutants in atmospheric air that are the same concentration level as those in the exhaust gas. The system has accuracy within ±5%. For the direct exhaust gas flow meter, a pitot tube type flow meter is utilized as it is simple, heat resistant, sufficiently accurate and has low flow-resistance characteristic. For the collection and dilution controllers, two mass flow controllers (MFC) were adopted. The MFCs' output can be adversely influenced by variation of the specific heat of the sample gas, resulting in flow reporting error.