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Exhaust and evaporative emissions systems have been developed to match the characteristics and usage of the Toyota THS II plug-in hybrid electric vehicle (PHEV). Based on the commercially available Prius, the Toyota PHEV features an additional external charging function, which allows it to be driven as an electric vehicle (EV) in urban areas, and as an hybrid electric vehicle (HEV) in high-speed/high-load and long-distance driving situations. To reduce exhaust emissions, the conventional catalyst warm up control has been enhanced to achieve emissions performance that satisfies California's Super Ultra Low Emissions Vehicle (SULEV) standards in every state of battery charge. In addition, a heat insulating fuel vapor containment system (FVS) has been developed using a plastic fuel tank based on the assumption that such a system can reduce the diffusion of vapor inside the fuel tank and the release of fuel vapor in to the atmosphere to the maximum possible extent.

In order to investigate the effect of sulfur and distillation properties on exhaust emissions, emission tests were carried out using a California Low Emission Vehicle (LEV) in accordance with the 1975 Federal Test Procedure ('75 FTP). To study the fuel effect on the exhaust emissions from different systems, these test results were compared with the results obtained from our previous studies using a 92MY vehicle for California Tier 1 standards and a 94MY vehicle for California TLEV standards. (1)(2) First, the sulfur effect on three regulated exhaust emissions (HC, CO and NOx) was studied. As fuel sulfur was changed from 30 to 300 ppm, the exhaust emissions from the LEV increased about 20% in NMHC, 17% in CO and 46% in NOx. To investigate the recovery of the sulfur effect, the test fuel was changed to 30 ppm sulfur after the 300 ppm sulfur tests. The emission level did not recover to that of the initial 30 ppm sulfur during three repeats of the FTP.

The original Toyota Hybrid System (THS) was installed in the Prius and was introduced in 1997 as the world's first mass-produced hybrid passenger car. Since then, THS has been continuously improved. In 2003 THS-II (marketed as Hybrid Synergy Drive [HSD]), was installed in a new larger Prius. In 2006 HSD was installed in a Rear Wheel Drive Vehicle: the LEXUS GS450h. This system achieved both 4.5-liter class power performance and compact class fuel economy with outstanding emissions performance. In 2007, this system is expanded to a mechanical all-wheel-drive(AWD) in the LEXUS LS600hL(with new V8 engine). This paper will explain this hybrid system which achieved both V12 class power performance and mid-size class fuel economy, while meeting the most stringent emission standard SULEV as a full-size vehicle.

The design of the newly developed Toyota AZ series 4 cylinder engine has been optimized through both simulations and experiments to improve heat transfer, cooling water flow, vibration noise and other characteristics. The AZ engine was developed to achieve good power performance and significantly reduced vibration noise. The new engine meets the LEV regulations due to the improved combustion and optimized exhaust gas flow. A major reduction in friction has resulted in a significant improvement in fuel economy compared with conventional models. It also pioneered a newly developed resin gear drive balance shaft.

Toyota Hybrid System (THS), the powertrain that combines a gasoline engine and an electric motor was first introduced in December 1997. It became the first mass-produced hybrid passenger vehicle in the world, gaining a reputation as a highly innovative vehicle, and its cumulative worldwide sales have exceeded 120,000 units. In 2003, THS had a further evolution. The “new-generation Toyota Hybrid System (THS II)” would be introduced on the new Prius. This report shall explain “THS II”, which achieved drastic improvements in power performance and fuel economy, while securing the most stringent emission standard Advanced Technology Partial Zero Emission Vehicle (ATPZEV).

CARB (California Air Resources Board) has required the evaporative emissions to be restricted to 1/4th of the parameter stated in the 1995 regulations. Furthermore, hydrocarbons (hereafter, HC) from the fuel system must be reduced to near 0.0 grams, according to the PZEV (Partial Zero Emission Vehicle) regulations enforced from 2003. The wet film in intake ports and fuel leaking from the injector nozzles evaporate and diffuse while the car is parked, and consequently may cause HC to leak the air cleaner inlet. The air cleaner which prevents HC leakage from the air intake system is already in mass production. In the course of designing this product to be installed in a vehicle, the authors developed a method to estimate the amount of HC that reaches the air cleaner. Based on detailed investigation on HC distribution and the changes that occur during parking, the HC amount reaching the air cleaner was calculated by both the equation of diffusion and the equation of state.

In preparation for compliance with California's SULEV standard and Euro STAGE 4 standard, which will take effect in 2002 and 2005, respectively, we have developed a laminated planar oxygen sensor. The developed sensor has the following characteristics: high thermal conductivity and superior dielectric characteristic, due to direct joining of the heater element alumina substrate and the sensor element zirconia electrolyte; low heat stress at temperature rise, due to optimized heater design; superior sensor protection from water droplets, and improved sensor response, due to optimized arrangement of intake holes in the sensor cover. With these characteristics, the developed oxygen sensor can be activated in 10 seconds after cold start. This report describes the technologies we used to develop the early-activation oxygen sensor.

To realize the high performance of the three-way catalyst, this development focused on the heat resistance of the CeO2-ZrO2 solid solution (CZ) that possesses the oxygen storage capacity (OSC). A new concept of the OSC compound with high durability is proposed. We devised a new method of inhibiting the coagulation of the primary CZ particles by placing diffusion barrier layers made of alumina among the primary CZ particles. This material is called “ACZ”. The specific surface area of ACZ was larger than that of the conventional CZ after durability test. The sintering of Pt on the ACZ-added catalyst is inhibited and the crystal size of CZ in the ACZ-added catalyst is smaller than that in the CZ-added catalyst. The OSC and the light off temperature of the ACZ-added catalyst are improved.

The effects of the phosphorus and sulfated ash contents of engine oils on the deactivation of monolithic three-way catalysts and oxygen sensors were studied. The effect of temperature was evaluated as well. The catalysts and oxygen sensors were poisoned in a 100-hour engine bench test. As a result, it was learned that engine oils with higher phosphorus contents showed a higher concentration of phosphorus on the catalyst surfaces, and the ability of the catalysts to convert carbon monoxide and oxides of nitrogen decreased. However, the phosphorus content was not observed to have any effect on hydrocarbons. The sulfated ash reduced the phosphorus concentration on the catalyst surface, but it also had a negative effect on the catalytic activity. The deactivation of the catalysts was much more noticeable at 800°C than at 720°C. In the tests at 720°C and 800°C, no deactivation of the oxygen sensors was observed, regardless of the composition of the engine oil.

New 2A/F systems different from usual A/F-O2 systems are being developed to cope with strict regulation of exhaust gas. In the 2A/F systems, 2A/F sensors are equipped in front and rear of a three-way catalyst. The A/F-O2 systems are ideas which use a rear O2 to detect exhaust gas leaked from three-way catalyst early and feed back. On the other hand, the 2A/F systems are ideas which use a rear A/F sensor to detect nearly stoichiometric gas discharged from the three-way catalyst accurately, and to prevent leakage of exhaust gas from the three-way catalyst. Therefore, accurate detection of nearly stoichiometric gas by the rear A/F sensor is the most importrant for the 2A/F systems. In general, the A/F sensors can be classified into two types, so called, one-cell type and two-cell type. Because the one-cell type A/F sensors don’t have hysteresis, they have potential for higher accuracy.

The original Toyota Hybrid System (THS) was installed in the Prius and was introduced in 1997 as the world's first mass-produced hybrid passenger car. THS has been continuously improved. In 2003 THS-II (marketed as Hybrid Synergy Drive [HSD]), was installed in a new larger Prius. In 2005 HSD was installed in two SUVs: the RX400h and Highlander Hybrid. This system achieved both V8 engine power performance and compact class fuel economy with outstanding emissions performance. In 2006, the HSD line-up is expanded to front-engine rear-wheel (FR) drive in the Lexus GS450h. This paper will explain this hybrid system which achieves both 4.5-liter class power performance and compact class fuel economy, while meeting the most stringent emission standard SULEV.

In conventional gasoline engine vehicles, three-way catalysts are used to simultaneously remove HC, CO and NOx from the exhaust gas. The effectiveness of the catalyst to remove these harmful species depends strongly on the oxygen concentration in the exhaust gas. Deterioration of three-way catalyst results in a reduction in its purification activity and OSC (oxygen storage capacity). In this investigation, additive elements were used to enhance the durability and OSC of the catalyst support material. An optimized formulation of a CeO2-ZrO2 and a ZrO2 material was developed to have excellent durability, improved OSC, enhanced interaction between precious metals and support materials, and increase thermal stability. Using these newly developed support materials, catalysts with increased performance was designed.

In response to various reformulated gasoline regulations, several studies have been conducted to evaluate the relationship between fuel properties and vehicle exhaust emissions. These studies, however, have focused on the fuel effect and have not examined the most promising advanced technology emission control systems on low emission vehicles. Toyota's reformulated gasoline research first set out to study the effect fuel compositions has on 2 different emission control systems. On both systems, non-methane hydrocarbon (NMHC) emissions were significantly affected by the 50% and 90% distillation temperature (T50 and T90). A correlation was also found exhaust olefine content and the amount of MTBE contained in the fuel. Research was also conducted on the specific ozone reactivity (SOR) of exhaust hydrocarbons. Various fuels with similar specifications but blended from different feedstocks were evaluated.

It is widely known that pellet-typed catalysts are deactivated by phosphorus (ZnDTP) that comes from engine oils. In this paper, the poisoning of monolithic three-way catalysts and oxygen sensors by engine oils is studied. First, catalysts and oxygen sensors were poisoned on the engine bench by test oils in which the quantity of phosphorus and ash was varied. Next, performance of the catalysts and sensors alone was examined and the vehicle exhaust emission at FTP mode was measured on a chassis dynamometer. The results indicate that phosphorus in engine oils poisons the monolithic catalyst and the oxygen sensor resulting in deterioration of the vehicle NOx exhaust emission. However, Ca sulfonate and Mg sulfonate detergents act by restraining phosphorus poisoning of the catalyst and the oxygen sensor. Through analysis of the catalyst and sensor surfaces, it is concluded that phosphorus poisons the catalyst and sensor forming a dense coating.

The Pd only three-way catalyst with Rh as an activator completely removed has been developed. The catalyst has been improved with regards to its thermal stability and its NOx reduction capability in the fuel rich region. These two factors have been known as the weak points of Pd catalyst. The thermal stability of the Pd catalyst was improved by modifying the washcoat alumina to yield a higher thermal stability. On the other hand, the NOx reduction capability was controlled by adding a combination of La and Ba. The developed Pd only three-way catalyst demonstrated the equivalent performance to a current production Pt/Rh catalyst after engine dynamometer aging up to 800°C.

A new 3-way catalyst with NOx conversion performance for lean-burn engines has been developed. The catalyst oxidizes NOx and stores the resulting nitrate, which is then reduced by HC and CO during engine operation around the stoichiometric air/fuel ratio. Both the composition of the storage component and the particle sizes of the noble metal were optimized. In addition, a special air fuel mixture control has been developed to make the best of the NOx storage-reduction function. The present catalyst showed 90% conversion efficiency and improved fuel economy by 4% in the Japanese 10-15 mode test cycle. The efficiency remained at 60% or more after durability test.

In order to satisfy future demands of low exhaust emission vehicles (LEV), a new fuel injection control system has been developed for SI engines with three-way catalytic converters. An universal exhaust gas oxygen sensor (UEGO) is mounted on the exhaust manifold upstream of the catalytic converter to rapidly feedback the UEGO output signal and a heated exhaust gas oxygen sensor (HEGO) is mounted on the outlet of the converter to achieve an exact air fuel ratio control at stoichiometry. The control law is derived from mathematical models of dynamic air flow, fuel flow and exhaust oxygen sensors (HEGO and UEGO). Experimental results on FTP (Federal Test Procedure) exhaust emissions show a dramatic reduction of HC, CO and NOx emissions and a possibility of practical low emission vehicles at low cost.

A new combustion concept for DISI gasoline engine was developed to achieve superior performances of high power and low environmental load. It realizes a high specific power and a good lean combustion performance simultaneously by utilizing a DI spray jet effectively to accelerate the in-cylinder tumble flow. Injection direction and configuration of the DI spray was optimized for intensification of the in-cylinder flow and high mixture homogeneity, a thin fan-shaped spray generated by a slit nozzle was adopted. As a result, combustion was accelerated by increase of in-cylinder turbulence intensity, and homogeneity of air-fuel mixture was improved. In addition, in-cylinder fuel wall wetting, which causes emission of particulate matter (PM) and oil dilution, was drastically reduced by improvement of the fan-shaped spray.

Toyota Hybrid System (THS), that combines a gasoline engine and an electric motor was installed in the Prius, which was introduced in 1997 as the world's first mass-produced hybrid passenger car, and was vastly improved in 2003. The new Prius gained a status of highly innovative and practical vehicle. In 2005, combined with a V6 engine, THS had a further evolution as a Hybrid System for SUV, which was installed in the RX400h and Highlander Hybrid to be introduced into the world. This report will explain “new THS” which achieved both V8 engine power performance and compact class fuel economy, while securing the most stringent emission standard, SULEV.

Automotive catalysts with a good thermal durability have been developed by modifying the composition of additives. The stability of alumina supports against the loss of the surface area depends on the ionic radius and amount of additives. Some lanthanides and alkaline earthes with large ionic radii of 0.11-0. 15nm are most effective. Among these elements, lanthanum improves not only the alumina stability but the catalytic activities of rhodium and cerium oxide. Infrared spectroscopic studies show that lanthanum oxide affects NO adsorbed on Rh to improve the activity for NO reduction. Moreover, lanthanum forms the complex oxide with cerium to improve the activity of cerium oxide. CO pulse reactions on the complex oxide (Ce, La)O2 -x have proved that the oxygen defect in the lattice promotes the diffusion of oxygen atoms to improve the oxide activity.