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Exhaust and evaporative emissions systems have been developed to match the characteristics and usage of the Toyota THS II plug-in hybrid electric vehicle (PHEV). Based on the commercially available Prius, the Toyota PHEV features an additional external charging function, which allows it to be driven as an electric vehicle (EV) in urban areas, and as an hybrid electric vehicle (HEV) in high-speed/high-load and long-distance driving situations. To reduce exhaust emissions, the conventional catalyst warm up control has been enhanced to achieve emissions performance that satisfies California's Super Ultra Low Emissions Vehicle (SULEV) standards in every state of battery charge. In addition, a heat insulating fuel vapor containment system (FVS) has been developed using a plastic fuel tank based on the assumption that such a system can reduce the diffusion of vapor inside the fuel tank and the release of fuel vapor in to the atmosphere to the maximum possible extent.

Diesel engines with relatively good fuel economy are known as an effective means of reducing CO₂ emissions. It is expected that diesel engines will continue to expand as efforts to slow global warming are intensified. Diesel particulate and NOx reduction system (DPNR), which was first developed in 2003 for introduction in the Japanese and European markets, shows high purification performance which can meet more stringent regulations in the future. However, it is poisoned by sulfur components in exhaust gas derived from fuel and lubricant. We then developed the sulfur trap DPNR with a sulfur trap catalyst that traps sulfur components in the exhaust gas. High purification performance could be achieved with a small amount of platinum group metal (PGM) due to prevention of sulfur poisoning and thermal deterioration.

The emission regulations for diesel engines are continually becoming stricter to reduce pollution and conserve energy. To meet these increasingly stringent regulations, a new exhaust after-treatment device is needed. Recently, the authors proposed the simultaneous electrochemical reduction (ECR) system for diesel particulate matter (PM) and NOx. In this method, a gas-permeable electrochemical cell with a porous solid oxide electrolyte is used for PM filtering on the anode. Alkaline earth metal is coated on the cathode for NOx storage. Application of voltage to both electrodes enables the simultaneous reduction of PM and NOx by the forced flow of oxygen ions from the cathode to the anode (oxygen pumping). In this study, the basic characteristics of the ECR system were investigated, and a disk-shaped electrochemical cell was evaluated.

The effects of an increasing boost pressure, a high EGR rate and a high injection pressure on exhaust emissions from an HSDI (High Speed Direct Injection) diesel engine were examined. The mechanisms were then investigated with both in-cylinder observations and 3DCFD coupled with ϕT-map analysis. Under a high-load condition, increasing the charging efficiency combined with a high injection pressure and a high EGR rate is an effective way to reduce NOx and soot simultaneously, which realized an ultra low NOx of 16ppm at 1.7MPa of IMEP (Indicated Mean Effective Pressure). The flame temperature with low NOx and low soot emissions is decreased by 260K from that with conventional emissions. Also, the distribution of the fuel-air mixture plot on a ϕT-map is moved away from the NOx and soot formation peninsula, compared to the conventional emissions case.

In this study, we combined a diesel engine with the Toyota Hybrid System (THS). Utilizing the functions of the THS, reducing engine friction, lowering the compression ratio, and adopting a low pressure loop exhaust gas recirculation system (LPL-EGR) were examined to achieve both low fuel consumption and low nitrogen oxides (NOx) emissions over a wide operating range. After applying this system to a test vehicle it was verified that the fuel economy greatly surpassed that of a conventional diesel engine vehicle and that NOx emissions could be reduced below the value specified in the Euro 6 regulations without DeNOx catalysts.

A study of the effects of changes in gasoline composition is one area to explore in our effort to reduce tailpipe emissions from vehicles. However, affects on vehicle performances should also be considered from the perspective of practical useage. In this paper, the influence of gasoline composition (aromatics),volatility, and MTBE blending on engine outlet and tailpipe emissions are discussed,in particular,forcusing on distillation properties which have a close relationship to driveability. Under stable driving conditios and without a catalitic converter, the effects of gasoline volatility is small, while aromatics in gasoline affect exhaust HC and NOx emissions. MTBE has a leaning effect on the engine intake air/fuel mixture. During a transient driving cycle, a high gasoline 50% distillation temperature causes poor driveability, as a result, HC emissions increase.

The impact of fatty acid methyl ester (FAME) blended diesel fuel on engine/vehicle systems was comprehensively investigated by vehicle, laboratory and engine tests. In this study, 20% FAME blended fuel (B20) was mainly used and soy bean oil methyl ester (SME) was primarily selected as the FAME. Vehicle testing with long-term fuel storage in vehicle fuel tanks was conducted, considering the most severe conditions in market use. Laboratory and engine tests were also conducted to better understand the vehicle test results. In the vehicle test, engine startability, idle roughness and fuel injection control were evaluated using nine vehicles with plastic or metal fuel tanks. All vehicles showed no problems up to 7 months. While five vehicles with plastic fuel tank did not show any problems throughout the test period up to 18 months, four vehicles with metal fuel tanks experienced malfunctions in engine start or fuel injection control following 8, 13, 13 and 18 months respectively.

An unprecedented phenomenon that achieves high NOx conversion was found over an NSR catalyst. This phenomenon occurs when continuous short cycle injections of hydrocarbons (HCs) are supplied at a predetermined concentration in lean conditions. Furthermore, this phenomenon has a wider range of applicability for different catalyst temperatures (up to 800 degrees Celsius) and SVs, and for extending thermal and sulfur durability than a conventional NOx storage and reduction system. This paper analyzes the reaction mechanism and concludes it to be highly active HC-deNOx by intermediates generated from adsorbed NOx over the base catalysts and HCs partially oxidized by oscillated HC injection. Subsequently, a high performance deNOx system named Di-Air (diesel NOx aftertreatment by adsorbed intermediate reductants) was demonstrated that applies this concept to high speed driving cycles.

In order to investigate the effect of sulfur and distillation properties on exhaust emissions, emission tests were carried out using a California Low Emission Vehicle (LEV) in accordance with the 1975 Federal Test Procedure ('75 FTP). To study the fuel effect on the exhaust emissions from different systems, these test results were compared with the results obtained from our previous studies using a 92MY vehicle for California Tier 1 standards and a 94MY vehicle for California TLEV standards. (1)(2) First, the sulfur effect on three regulated exhaust emissions (HC, CO and NOx) was studied. As fuel sulfur was changed from 30 to 300 ppm, the exhaust emissions from the LEV increased about 20% in NMHC, 17% in CO and 46% in NOx. To investigate the recovery of the sulfur effect, the test fuel was changed to 30 ppm sulfur after the 300 ppm sulfur tests. The emission level did not recover to that of the initial 30 ppm sulfur during three repeats of the FTP.

In order to clarify the diesel fuel spray characteristics inside the cylinder, we developed two novel techniques, which are preparation of same level of temperature and pressure ambient as inside cylinder and quantitative measurement of vapor concentration. The first one utilizes combustion-type constant-volume chamber (inner volume 110cc), which allows 5 MPa and 873K by igniting the pre-mixture (n-pentane and air) with two spark plugs. In the second technique, TMPD vapor concentration is measured by using Laser Induced Exciplex Fluorescence method (LIEF). The concentration is compensated by investigation of the influence of ambient pressure (from 3 to 5 MPa) and temperature (from 550 to 900 K) on TMPD fluorescence intensity. By using two techniques, we investigated the influence of nozzle hole diameter, injection pressure and ambient condition on spray characteristics.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. In the impact on exhaust emissions, the impact of high biodiesel blends into diesel fuel on diesel emissions was evaluated. The wide variety of biodiesel blendstock, which included not only some kinds of fatty acid methyl esters(FAME) but also hydrofined biodiesel(HBD) and Fischer-Tropsch diesel fuel(FTD), were selected to evaluate. The main blend level evaluated was 5, 10 and 20% and the higher blend level over 20% was also evaluated in some tests. The main advanced technologies for exhaust aftertreatment systems were diesel particulate filter(DPF), Urea selective catalytic reduction (Urea-SCR) and the combination of DPF and NOx storage reduction catalyst(NSR).

Premixed diesel combustion modes including low temperature combustion and MK combustion are expected to realize smokeless and low NOx emissions. As ignition must be delayed until after the end of fuel injection to establish these combustion modes, methods for active ignition control are being actively pursued. It is reported that alcohols including methanol and ethanol strongly inhibit low temperature oxidation in HCCI combustion offering the possibility to control ignition with alcohol induction. In this research improvement of diesel combustion and emissions by ethanol intake port injection for the promotion of premixing of the in-cylinder injected diesel fuel, and by increased EGR for the reduction of combustion temperature.

In order to correspond to the exhaust emissions regulations that become severe every year, more advanced engine control becomes necessary. Engine engineers are concerned about the Hydrocarbons (HCs) that flow through the air-intake ports and that are difficult to precisely control. The main sources of the HCs are, the canister purge, PCV, back-flow gas through the intake valves, and Air / Fuel ratio (A/F) may be aggravated when they flow into the combustion chambers. The influences HCs give on the A/F may also grow even greater, which is due to the increasingly stringent EVAP emission regulations, by more effective ventilation in the crankcase, and also by the growth of the VVT-operated angle and timing, respectively. In order to control the A/F more correctly, it is important to estimate the amount of HCs that are difficult to manage, and seek for suitable controls over fuel injection and so on.

CARB (California Air Resources Board) has required the evaporative emissions to be restricted to 1/4th of the parameter stated in the 1995 regulations. Furthermore, hydrocarbons (hereafter, HC) from the fuel system must be reduced to near 0.0 grams, according to the PZEV (Partial Zero Emission Vehicle) regulations enforced from 2003. The wet film in intake ports and fuel leaking from the injector nozzles evaporate and diffuse while the car is parked, and consequently may cause HC to leak the air cleaner inlet. The air cleaner which prevents HC leakage from the air intake system is already in mass production. In the course of designing this product to be installed in a vehicle, the authors developed a method to estimate the amount of HC that reaches the air cleaner. Based on detailed investigation on HC distribution and the changes that occur during parking, the HC amount reaching the air cleaner was calculated by both the equation of diffusion and the equation of state.

A new stratified charge system has been developed for direct injection gasoline engines. The special feature of this system is employment of a thin fan-shaped fuel spray formed by a slit nozzle and a shell-shaped piston cavity. This system, basically classified into the wall-guided mixture preparation concept that leads air/fuel mixture to the spark plug periphery by means of spray penetration and piston cavity configuration without an extra intake air flow controlling system, obtained wide engine operating area with stratified combustion and high output performance. This report presents the characteristics of stratified mixture formation and combustion, especially the important factor for achieving stable stratified combustion in the high-speed region, which have been clarified through analytical studies.

An experimental study was carried out in order to reduce engine-out HC emissions from a direct injection spark ignition (DISI) engine during the cold start period. The objectives of this study were to investigate the fuel behavior quantified with an analytic method and to propose some practical techniques to reduce the cylinder-wetting fuel volume and engine-out HC emissions. Compared to the MPI (Multi Port Fuel Injection) engine, required fuel volume for DISI engine was reduced during the cold start because intake port wall-wetting was not generated. On the other hand, a large volume of cylinder wetting fuel resulted in engine-out HC emissions. Injection timing, atomization and vaporization of injected fuel affected the cylinder-wetting fuel volume. Above all, Injection of the heated fuel provided good results. In summary, engine-out HC emissions from DISI engine was reduced compared to that of MPI engine during the cold-start period.

The Vapor Reducing Fuel Tank System (Bladder Tank System) using a flexible plastic membrane (Bladder Membrane) was newly developed in order to reduce the amount of vaporized gasoline in a steel fuel tank. This Bladder Membrane is flexible to expand in proportion to a fuel volume and prevents the permeation of the vaporized gasoline. As a result of our initial study for various materials, we decided to apply a multi-layer plastic material which could achieve both low fuel permeability and good flexibility. This multi-layer material consists of polyethylene(PE) for structural material and polyamide(PA) for low permeability. The modulus of the PE needs to achieve a sufficient flexibility in order to keep the movement of the membrane. While PA material must have not only low fuel permeability but also strong adhesion with the structural material of PE. We also clarify the membrane design to keep a good flexibility and to reduce a strain.

Two effects of rich-spike duration on NOx-storing have been analyzed. The first one, that NOx-storing speed decreases as rich-spike duration increases, is explained as the influence of NOx diffusion in wash-coat layer, which is quantified by a simple mathematical expression for NOx-storing rate. The second one, a peculiar behavior of NOx-storing in appearance of the outlet NOx concentration, is clarified: Heat produced directly or indirectly (via oxygen storage in ceria) by rich-spike warms up the downstream part, which releases excess NOx at the raised temperature. Contributions of the oxygen storage and the carbonate of NOx-storage material are also discussed.

Methanol steam reforming, which is an endothermic reaction, needs some heating. Both methanol conversion ratio and carbon monoxide (CO) concentration increase when temperature is elevated. As CO poisons a typical polymer electrolyte of a fuel cell, the relationship between methanol conversion ratio and CO concentration is a trade-off one. It was found from preliminary researches that the reforming reaction speed is controlled by heat transfer rate at large methanol flow rate, where methanol conversion ratio becomes lower and CO concentration becomes higher. Therefore it is necessary to develop a new methanol reforming concept that provides stable combustion for heating and enhanced heat transfer for improving the trade-off relationship and making a compact reformer. Reforming catalyst using metal honeycomb support and a new catalytic combustion were applied to a new concept plate type methanol steam reformer, which is used in a fuel cell of 3 kW-class electric generation.

In order to further improve the performance of NOx storage-reduction catalysts (NSR catalysts), focus was placed on their high temperature performance deterioration via sulfur poisoning and heat deterioration. The reactions between the basicity or acidity of supports and the storage element, potassium, were analyzed. It was determined that the high temperature performance of NSR catalysts is enhanced by the interaction between potassium and zirconia, which is a basic metal oxide. Also, a new zirconia-titania complex metal oxides was developed to improve high temperature performance and to promote the desorption of sulfur from the supports after aging.