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This paper describes an exhaust system using a new air-fuel ratio (hereinafter, A/F) sensor that contributes to low emissions and low fuel consumption of gasoline engines. As the first technical feature, the water splash resistance of the A/F sensor has been substantially improved which allows A/F control to be enabled without delay during engine cold start. To realize this capability, it is important that the sensor characteristics are not affected by the condensed water generated in the exhaust pipe. Therefore, a technique that has the effectiveness of a water splash resistance layer with water repellent function is demonstrated. As the second technical feature, the power consumption of the sensor has been substantially reduced. This is achieved by improving thermal efficiency of the sensor that the element can be activated at a low temperature.

To meet future stringent emission regulations such as Euro6, the design and control of diesel exhaust after-treatment systems will become more complex in order to ensure their optimum operation over time. Moreover, because of the strong pressure for CO₂ emissions reduction, the average exhaust temperature is expected to decrease, posing significant challenges on exhaust after-treatment. Diesel Oxidation Catalysts (DOCs) are already widely used to reduce CO and hydrocarbons (HC) from diesel engine emissions. In addition, DOC is also used to control the NO₂/NOx ratio and to generate the exothermic reactions necessary for the thermal regeneration of Diesel Particulate Filter (DPF) and NOx Storage and Reduction catalysts (NSR). The expected temperature decrease of diesel exhaust will adversely affect the CO and unburned hydrocarbons (UHC) conversion efficiency of the catalysts. Therefore, the development cost for the design and control of new DOCs is increasing.

A new clean diesel combustion concept has been proposed and its excellent performance with respect to gas emissions and fuel economy were demonstrated using a single cylinder diesel engine. It features the following three items: (1) low-penetrating and highly dispersed spray using a specially designed injector with very small and numerous orifices, (2) a lower compression ratio, and (3) drastically restricted in-cylinder flow by means of very low swirl ports and a lip-less shallow dish type piston cavity. Item (1) creates a more homogeneous air-fuel mixture with early fuel injection timings, while preventing wall wetting, i.e., impingement of the spray onto the wall. In other words, this spray is suitable for premixed charge compression ignition (PCCI) operation, and can decrease both nitrogen oxides (NOx) and soot considerably when the utilization range of PCCI is maximized.

The details of Di-Air, a new NOx reduction system using continuous short pulse injections of hydrocarbons (HC) in front of a NOx storage and reduction (NSR) catalyst, have already been reported. This paper describes further studies into the deNOx mechanism, mainly from the standpoint of the contribution of HC and intermediates. In the process of a preliminary survey regarding HC oxidation behavior at the moment of injection, it was found that HC have unique advantages as a reductant. The addition of HC lead to the reduction or metallization of platinum group metals (PGM) while keeping the overall gas atmosphere in a lean state due to adsorbed HC. This causes local O₂ inhibition and generates reductive intermediate species such as R-NCO. Therefore, the specific benefits of HC were analyzed from the viewpoints of 1) the impact on the PGM state, 2) the characterization of intermediate species, and 3) Di-Air performance compared to other reductants.

Newly designed laboratory measurement system, which reproduces particle number size distributions of both nuclei and accumulation mode particles in exhaust emissions, was developed. It enables continuous measurement of nano particle emissions in the size range between 5 and 1000 nm. Evaluations of particle number size distributions were conducted for diesel vehicles with a variety of emission aftertreatment devices and for gasoline vehicles with different combustion systems. For diesel vehicles, Diesel Oxidation Catalyst (DOC), urea-Selective Catalytic Reduction (urea-SCR) system and catalyzed Diesel Particulate Filter (DPF) were evaluated. For gasoline vehicles, Lean-burn Direct Injection Spark Ignition (DISI), Stoichiometric DISI and Multi Point Injection (MPI) were evaluated. Japanese latest transient test cycles were used for the evaluation: JE05 mode driving cycle for heavy duty vehicles and JC08 mode driving cycle for light duty vehicles.

In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.

Comparison of net thermal efficiency and emission in two and four stroke gasoline HCCI engine has been carried out for various valve-timings as negative valve overlap and exhaust valve double opening. The valve timings could easily be converted from a mode to another by configuring schedule of electromagnetic valve-train. Extension of operable torque with high thermal efficiency had been expected in two-stroke HCCI operation, however friction and supercharger loss curtailed about half of the gain in indicated thermal efficiency. In four-stroke operation modes, exhaust valve double opening (‘reinduction’ or ‘rebreathing’) showed the best net thermal efficiency and emission, however the extension of high load limit could not be achieved considerably.

Recently, global warming and energy security have received significant attention. Thus an improvement of the vehicle fuel economy is strongly required. For engines, one effective way is to improve the engine thermal efficiency. Raising compression ratio [1] or turbo charging technologies have potential to achieve high thermal efficiency. However knock does not allow the high thermal efficiency. Knock depends on the fuel composition and the pressure and temperature history of unburnt end-gas [2-3]. For fuels, RON is well known for describing the anti knock quality. High RON fuels have high anti knock quality and result in higher thermal efficiency. This paper investigates the impact of high RON fuels on the thermal efficiency by using high compression ratio engine, turbo charged engine, and lean boosted engine [4]. Finally, it is shown that the high thermal efficiency can be approached with high RON gasoline and ethanol.

Feasibility studies concerning ethanol utilization in direct injection gasoline engines were conducted in order to clarify the effects of ethanol on engine performance, exhaust emissions and injector deposit formation. The investigation results indicate that E100 (100% ethanol fuel) can improve full load engine performance around whole engine speed range in a high compression ratio engine (ε=13:1), compared to that of a base compression ratio engine (ε=11.5:1) operated on a premium gasoline. This was caused by the volumetric efficiency (ηv) improvement and engine knock suppression in the high compression ratio engine. On the other hand, HC emissions remarkably increased under lower engine speeds at a full load condition. This phenomenon suggests that poor combustion occurred due to insufficient mixing of air and E100 fuel under these conditions, in which the amount of ethanol injected was too large and fluidity in the cylinder was weak.

From the viewpoint of primary energy diversification and CO2 reduction, interests of using Biomass Fuel are rising. Some kinds of FAME (Fatty Acid Methyl Ester), which are obtained from oil fats like vegetable oil using transesterification reaction with methanol, are getting Palm Oilpular for bio-diesel recently. In this study, we have conducted many experiments of palm oil hydrogenations using our pilot plants, and checked the reactivity and the pattern of product yields. As a result, we figured out that the hydrocarbon oil equivalent to the conventional diesel fuel can be obtained from vegetable oils in good yield under mild hydrogenation conditions. Moreover, as a result of various evaluations for the hydrogenated palm oil (oxidation stability, lowtemperature flow property, LCA, etc.), we found that the hydrogenated palm oil by our technology has performances almost equivalent to conventional diesel fuel.

From the energy security and CO2 discharge reduction point of view, much attention has been paid to the usage of biofuel, ethanol, as an alternative source of energy in the transportation industry. Yet, the major drawback in applying highly concentrated ethanol in the spark ignited internal combustion engines is cold start instability. This is due to the characteristics of ethanol, large latent heat required to vaporize. This paper investigates necessary conditions for the engine cold start, using highly concentrated ethanol. Tests performed with varieties of ethanol fuel, a relationship between cold startability lower temperature limit and reid vapor pressure was observed. A method to boost the vaporization, intake valve timing control is introduced to obtain high compression peak temperature.

An investigation was conducted into pressure pulsation in the exhaust port, which greatly affects volumetric efficiency and engine performance. From experiments using a single blow-down generator, it was established that the amplitude of the pressure pulsation increases as the manifold branch is lengthened and that large negative pressure synchronized with the timing of valve overlap can be obtained if a proper branch length is used. The performance of a 2ℓ test engine was optimized by varying the length of both the manifold branches and front pipe forks. It was found that whereas front pipe fork length affects engine performance over only a narrow range of engine speed, optimizing manifold branch length results in a considerable improvement over a wide engine speed range. In the course of optimizing the exhaust pipe manifold length of this two-degree-of-freedom exhaust system, abnormal exhaust noises were emitted at specific engine speeds during deceleration.

In order to determine the main factors causing the mileage-related increase in formaldehyde emission from methanol-fueled vehicles, mileage was accumulated on three types of vehicle, each of which had a different air-fuel calibration system. From exhaust emission data obtained during and after the mileage accumulation, it was found that lean burn operation resulted in by far the highest formaldehyde emission increase. An investigation into the reason for the rise in engine-out formaldehyde emission revealed that deposits in the combustion chamber emanating from the lubricating oil promotes formaldehyde formation. Furthermore it was learnt that an increase in engine-out NOx emissions promotes partial oxidation of unburned methanol in the catalyst, leading to a significant increase in catalyst-out formaldehyde emission.

Non-equilibrium all-atom MD simulations are used to study the traction properties of hydrocarbon fluids. A fluid layer is confined between two solid Fe plates under the constant normal force of 1.0 GPa. Traction simulations are performed by applying a relative sliding motion to the Fe plates. Shear behaviors of nine hydrocarbon fluids are simulated on a sufficiently large film thickness of 6.7 nm, and succeeded in reproducing the order of the experimental traction coefficients. The dynamic mechanism of the momentum transfer on layers of fluid molecules are analyzed focusing on the intermolecular interactions (density profile, orientation factor, pair-correlation function) and intramolecular interactions (intramolecular interaction energy, conformation change of alicyclic ring). In contrast to the case of n-hexane, which shows low traction due to a fragile chain-like interaction, other mechanisms are obtained in the high traction molecules of cyclohexane, dicyclohexyl and santotrac 50.

One primary result of the reduction of platinum group metals (PGM) within a catalytic converter is the decline in NOx conversion efficiency. This paper hypothesizes that the primary factor of this decline to be hydrocarbon (HC) poisoning. To maintain high NOx conversion efficiency as the PGM reduces, Rh activation improvement becomes significant to overcome the HC poisoning. Analysis of the Rh deterioration mechanism found that it is effective to separately arrange Rh and CeO2 on the converter, avoiding the Rh deactivation. By this improvement, we improved the catalyst activity at less than 25% of the original Rh loading.

Diesel particulate and NOx reduction system (DPNR) is an effective technology for the diesel after-treatment system, which can reduce particulate matter (PM) and nitrogen oxides (NOx) simultaneously. Further improvement of the DPNR is expected for cleaner air in the future. The catalyst for the DPNR (called DPNR catalyst) consists of a NOx Storage Reduction (NSR) catalyst coated onto a Diesel Particulate Filter (DPF). The development of the DPNR catalyst for the decrease of exhaust weight has been considered before now with respect to the PM combustion. But it will be necessary to focus on PM particle number emissions in the future. In this study, the relationship between the pore structure of the DPNR catalyst and the trapping of PM to lower particle number was clarified by evaluating a high-porosity, large-pore cordierite DPF with an average pore size of 20 μm or greater. Furthermore, the optimal pore structure to trap PM particles in a highly effective manner was discussed.

Biodiesel Fuel (BDF) Research Work Group works on identifying technological issues on the use of high biodiesel blends (over 5 mass%) in conventional diesel vehicles under the Japan Auto-Oil Program started in 2007. The Work Group conducts an analytical study on the issues to develop measures to be taken by fuel products and vehicle manufacturers, and to produce new technological findings that could contribute to the study of its introduction in Japan, including establishment of a national fuel quality standard covering high biodiesel blends. For evaluation of the impacts of high biodiesel blends on performance of diesel particulate filter system, a wide variety of biodiesel blendstocks were prepared, ranging from some kinds of fatty acid methyl esters (FAME) to another type of BDF such as hydrotreated biodiesel (HBD). Evaluation was mainly conducted on blend levels of 20% and 50%, but also conducted on 10% blends and neat FAME in some tests.

Considering the popularity of biodiesel fuels for diesel vehicles, the impacts of rapeseed oil methyl ester (RME), which is the most utilized biodiesel fuel in Europe, on tailpipe emissions from a diesel passenger car was investigated. In this study, 30% RME blended diesel fuel (RME30) was used and the comparison of tailpipe emissions between RME30 and a reference diesel fuel was conducted using a test vehicle with the latest engine and aftertreatment system. The results of the investigation reveal that RME30 generates about the same amount of NOx in tailpipe emissions as diesel fuel, and less HC, CO, and PM. These phenomena occurred in spite of attaching catalysts to the test vehicle, and therefore suggesting that the NOx conversion efficiency of the catalysts for RME30 is equal to that for diesel fuel. The injection rate for RME30 was the same as that for diesel fuel.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. In the impact on exhaust emissions, the impact of high biodiesel blends into diesel fuel on diesel emissions was evaluated. The wide variety of biodiesel blendstock, which included not only some kinds of fatty acid methyl esters(FAME) but also hydrofined biodiesel(HBD) and Fischer-Tropsch diesel fuel(FTD), were selected to evaluate. The main blend level evaluated was 5, 10 and 20% and the higher blend level over 20% was also evaluated in some tests. The main advanced technologies for exhaust aftertreatment systems were diesel particulate filter(DPF), Urea selective catalytic reduction (Urea-SCR) and the combination of DPF and NOx storage reduction catalyst(NSR).

Previous studies have investigated the impacts of biofuel usage on the performance, drivability and durability of modern diesel engines and exhaust after-treatment systems including test work with different types, concentrations and mixtures of bio fuel components. During this earlier work vehicle fuel filter blocking issues were encountered during a field trial using various types of EN 14214 compliant Fatty Acid Methyl Ester (FAME) blended into EN 590 diesel. This paper summarises a subsequent literature review that was carried out looking into potential causes of this filter blocking and further work that was then carried out to expand on the findings. From this, a laboratory study was carried out to assess the increase in fuel filter blocking tendency (FBT) when various FAMEs from mixed sources were blended into EN 590 diesel at different concentrations, including levels above those currently allowed in the European market.