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Exhaust particle number concentrations and size distributions were measured from the exhaust of a 1995 direct injection, Diesel engine. Number concentrations ranged from 1 to 7.5×107 particles/cm3. The number size distributions were bimodal and log-normal in form with a nuclei mode in the 7-15 nm diameter range and an accumulation mode in the 30-40 nm range. For nearly all operating conditions, more than 50% of the particle number, but less than 1% of the particle mass were found in the nuclei mode. Preliminary indications are that the nuclei mode particles are solid and formed from volatilization and subsequent nucleation of metallic ash from lubricating oil additives. Modern low emission engines produce low concentrations of soot agglomerates. The absence of these agglomerates to act as sites for adsorption or condensation of volatile materials makes nucleation and high number emissions more likely.

As part of an ongoing program to control the emissions of diesel-powered equipment used in underground mines, the U. S. Bureau of Mines evaluated exhaust emissions from a compression ignition engine using oxygenated diesel fuels and a diesel oxidation catalyst (DOC). The fuels include neat (100%) soy methyl ester (SME), and a blend of 30% SME (by volume) with 70% petroleum diesel fuel. A Caterpillar 3304 PCNA engine was tested for approximately 50 hours on each fuel. Compared with commercial low-sulfur diesel fuel (D2), neat SME increased volatile organic diesel particulate matter (DPM) but greatly decreased non-volatile DPM, for a net decrease in total DPM. The DOC further reduced volatile and total DPM NOx emissions were slightly reduced for the case of neat SME, but otherwise were not significantly affected. Peak brake power decreased 9% and brake specific fuel consumption increased 13 to 14% for the neat methyl soyate because of its lower energy content compared with D2.

Alcohols are examined as supplemental carbureted fuels for highspeed turbocharged diesels as typified by the White Motor/Waukesha F310 DBLT (6 cylinder, 310 cu. in.). Most of the work was with methanol; ethanol and isopropanol were compared at a few points. Fumigation (dual-fueling) with alcohol significantly reduced smoke and intake manifold temperature. These effects were largest at high load. Efficiency and HC emissions were essentially unchanged. Cylinder pressures and rise rates were examined for possible adverse effects on engine structure. The range of speed and load favorable to alcohol dual-fueling are such that, should alcohols become economically competitive as fuels, a practical duel-fuel system could be applied to existing diesel engines.