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The increased severity and prevalence of insoluble deposits formed on fuel injectors in gasoline direct injection (GDI) engines precipitates negative environmental, economic and healthcare impacts. A necessary step in mitigating deposits is to unravel the molecular compositions of these complex layered materials. But very little molecular data has been acquired. Mass spectrometry shows promise but most techniques require the use of solvents, making them unsuited for analyzing insoluble deposits. Here, we apply the high mass-resolving power and in-situ analysis capabilities of 3D OrbitrapTM secondary ion mass spectrometry (3D OrbiSIMS) to characterize deposits formed on the external tip and internal needle from a GDI injector. This is the first application of the technique to study internal GDI deposits. Polycyclic aromatic hydrocarbons (PAHs) are present up to higher maximum masses in the external deposit.

An experimental investigation has been carried out to compare the indicated performance and heat release characteristics of a DI diesel engine at compression ratios of 18.4:1 and 15.4:1. The compression ratio was changed by modifying the piston bowl volume; the bore and stroke were unchanged, and the swept volume was nominally 500cc. The engine is a single cylinder variant of modern design which meets Euro 4 emissions requirements. Work output and heat release characteristics for the two compression ratios have been compared at an engine speed of 300 rev/min and test temperatures of 10, -10 and -20°C. A more limited comparison has also been made for higher speeds representative of cold idle at one test temperature (-20°C). The reduction in compression ratio generally produces an increase in peak specific indicated work output at low speeds; this is attributable to a reduction in blowby and heat transfer losses and lower peak rates of heat release increasing cumulative burn.

A Ford 2.4-liter 115PS light-duty diesel engine was modified to allow solenoid control of the oil feed to the piston cooling jets, enabling these to be switched on or off on demand. The influence of the jets on piston temperatures, engine thermal state, gaseous emissions and fuel economy has been investigated. With the jets switched off, piston temperatures were measured to be between 23 and 88°C higher. Across a range of speed-load points, switching off the jets increased engine-out emissions of NOx typically by 3%, and reduced emissions of CO by 5-10%. Changes in HC were of the same order and were reductions at most conditions. Fuel consumption increased at low-speed, high-load conditions and decreased at high-speed, low-load conditions. Applying the results to the NEDC drive cycle suggests active on/off control of the jets could reduce engine-out emissions of CO by 6%, at the expense of a 1% increase in NOx, compared to the case when the jets are on continuously.

Reducing friction in crankshaft bearings during cold engine operation by heating the oil supply to the main gallery has been investigated through experimental investigations and computational modelling. The experimental work was undertaken on a 2.4l DI diesel engine set up with an external heat source to supply hot oil to the gallery. The aim was to raise the film temperature in the main bearings early in the warm up, producing a reduction in oil viscosity and through this, a reduction in friction losses. The effectiveness of this approach depends on the management of heat losses from the oil. Heat transfer along the oil pathway to the bearings, and within the bearings to the journals and shells, reduces the benefit of the upstream heating.

The determination of size distribution of soot particles and agglomerates in oil samples using a Nanosight LM14 to perform Nanoparticle Tracking Analysis (NTA) is described. This is the first application of the technique to sizing soot-in-oil agglomerates and offers the advantages of relatively high rates of sample analysis and low cost compared to Transmission Electron Microscopy (TEM). Lubricating oil samples were drawn from the sump of automotive diesel engines run under a mix of light duty operating conditions. The oil samples were diluted with heptane before analysing. Results from NTA analysis were compared with the outputs of a more conventional analysis based on Dynamic Light Scattering (DLS). This work shows that soot-in-oil exists as agglomerates with average size of 115 nm. This is also in good agreement with TEM analysis carried out in a previous work. NTA can measure soot particles in polydisperse oil solutions and report the size distribution of soot-in-oil aggregates.

An experimental study has been carried out to explore what limits fuel injection and EGR strategies when trying to run a PCCI-type mode of combustion on an engine with current generation hardware. The engine is a turbocharged V6 DI diesel with (1600 bar) HPCR fuel injection equipment and a cooled external EGR system. The variables examined have been the split and timings of fuel injections and the level of EGR; the responses investigated have been ignition delay, heat release, combustion noise, engine-out emissions and brake specific fuel consumption. Although PCCI-type combustion strategies can be effective in reducing NOx and soot emissions, it proved difficult to achieve this without either a high noise or a fuel economy penalty.

DISI engine emissions and fuel economy are strongly dependent upon fuel injection and spark timings, particularly when the engine is operating in stratified charge mode. Experimental studies of the effects of injection and spark timings and the interaction between these are described. The sensitivity of HC and NOx emissions to timings during stratified charge operation, the comparison of performance under stratified and homogeneous charge modes of operation and the rationale for mode switch point settings are investigated. The high sensitivity of emissions to injection and spark timing settings gives rise to potential robustness issues. These are described.

An experimental study of the performance of a reverse tumble, DISI engine is reported. Specific fuel consumption and engine-out emissions have been investigated for both homogeneous and stratified modes of fuel injection. Trends in performance with varying AFR, EGR, spark and injection timings have been explored. It is shown that neural networks can be trained to describe these trends accurately for even the most complex case of stratified charge operation with exhaust gas recirculation.

Environmental authorities such as EPA, VCA have enforced stringent emissions legislation governing air pollutants released into the atmosphere. Of particular interest is the challenge introduced by the limit on particulate number (PN) counting (#/km) and real driving emissions (RDE) testing; with new emissions legislation being shortly introduced for the gasoline direct injection (GDI) engines, gasoline particulate filters (GPF) are considered the most immediate solution. While engine calibration and testing over the Worldwide harmonized Light vehicles Test Cycle (WLTC) allow for the limits to be met, real driving emission and cold start constitute a real challenge. The present work focuses on an experimental durability study on road under real world driving conditions. Two sets of experiments were carried out. The first study analyzed a gasoline particulate filter (GPF) (2.4 liter, diameter 5.2” round) installed in the underfloor (UF) position and driven up to 200k km.

Soot formation and distribution inside the cylinder of a light-duty direct injection diesel engine, have been predicted using Kiva-3v CFD software. Pathlines of soot particles traced from specific in-cylinder locations and crank angle instants have been explored using the results for cylinder charge motion predicted by the Kiva-3v code. Pathlines are determined assuming soot particles are massless and follow charge motion. Coagulation and agglomeration have not been taken into account. High rates of soot formation dominate during and just after the injection. Oxidation becomes dominant after the injection has terminated and throughout the power stroke. Computed soot pathlines show that soot particles formed just below the fuel spray axis during the early injection period are more likely to travel to the cylinder wall boundary layer. Soot particles above the fuel spray have lesser tendency to be conveyed to the cylinder wall.

The effect of compression ratio on sensitivity to changes in start of injection and air-fuel ratio has been investigated on a single-cylinder DI diesel engine at fixed low and medium speeds and loads. Compression ratio was set to 17.9:1 or 13.7:1 by using pistons with different bowl sizes. Injection timing and air-to-fuel ratio were swept around a nominal map point at which gross IMEP and NOx values were matched for the two compression ratios. It was found that CO, HC and ISFC were higher at low compression ratio, but the soot/NOx trade-off improved and this could be exploited to reduce the fuel economy penalty. Sensitivity to inputs is generally similar, but high compression ratio tended to have steeper response gradients. Reducing compression ratio to 13.7 gave rise to a marked degradation of performance at light load, producing high CO emissions and a fall in combustion efficiency. This could be eased by reducing rail pressure, but the advantage in smoke emission was lost.

The size and morphology of soot particles and agglomerates extracted from lubricating oil drawn from the sump of a diesel engine have been investigated and compared using Transmission Electron Microscopy (TEM) and Nanoparticle Tracking Analysis (NTA). Samples were prepared for electron microscopy imaging by both centrifugation and solvent extraction to investigate the impact of these procedures on the morphological characteristics, such as skeleton length and width and circularity, of the obtained soot. It was shown that centrifugation increases the extent of agglomeration within the sample, with 15% of the agglomerates above 200 nm compared to only 11% in the solvent extracted soot. It was also observed that the width of centrifugation extracted soot was typically 10 nm to 20 nm larger than that of solvent extracted soot, suggesting that centrifugation forces the individual agglomerate chains together.

A computational model has been developed to support investigations of temperature, heat flow and friction characteristics, particularly in connection with warm-up behaviour. A lumped capacity model of the engine block and head, empirically derived correlations for local heat transfer and friction losses, and oil and coolant circuit descriptions form the core of the model. Validation of the model and illustrative results are reported.

Two methods of determining the rate of heat transfer from the combustion chamber have been investigated. A First Law analysis is shown to be ill-conditioned because of sensitivity to heat release and gas property calculations. An alternative approach equates cycle-averaged chamber heat transfer to the difference between heat rejected to the coolant and gas heat transfer to the exhaust port. This has been examined as a basis for calibrating the Woschni correlation.

Optimising an engine specification to improve cold start performance has been investigated. Taguchi methods were used to define a test programme to assess the effect of seven build factors. Experiments were conducted to measure mixture ratio at the spark plug location after a short period of engine cranking at test conditions covering ± 15°C and three fuel-mass-supplied values. The analysis of the results identified build modifications which improved start quality and reduced HC and CO emissions substantially compared to a reference, base-line build. Injector design and location, and inlet valve timing were found to have most influence on robustness to uncontrolled variations in mixture preparation during starts.

The cycle-by-cycle variation of heat transferred per cycle (q) to the combustion chamber surfaces of spark ignition engines has been investigated for quasi-steady and transient conditions produced by throttle movements. The heat transfer calculation is by integration of the instantaneous value over the cycle, using the Woschni correlation for the heat transfer coefficient. By examination of the results obtained, a relatively simple correlation has been identified: This holds both for quasi-steady and transient conditions and is on a per cylinder basis. The analysis has been extended to define a heat flux distribution over the surface of the chamber. This is given by: where F(x/L) is a polynomial function, q″ is the heat transfer per cycle per unit area to head and piston crown surfaces and gives the distribution along the liner

Surface-mounted heat flux sensors have been used in the intake port of a fuel injected, spark ignition engine to investigate heat transfer between the surface, the gas flows through the port, and fuel deposited in surface films. The engine is of a four valve per cylinder design, with a bifurcated intake port. For dry-port conditions heat transfer per cycle varies between 0 and 300 J/m2 depending on location, towards the surface at low temperatures and away from the surface at fully-warm conditions. Particular attention has been given to the changes in heat transfer rate associated with fuel deposition. Typically this is of the order of 5 kW/m2 in regions of heavy fuel deposition and varies by a factor of 2 over the period of an engine cycle. During warm-up, as coolant temperature increases from 0 to 90°C, changes in heat transfer associated with fuel deposition typically increase from 300 J/m2 to 1000 J/m2.

The rate of heat rejection to the coolant system of an internal combustion engine depends upon coolant composition, among other factors, because this influences the coolant side heat transfer coefficient. The correlation developed by Taylor and Toong for heat transfer rate has been modified to account for this effect. The modification retains the gas-to-coolant passage thermal resistance implicit in the original correlation. The modified correlation gives predictions in agreement with experimental data. Compared to 100% water, mixtures of 50% ethylene glycol/50% water lower heat rejection rates by typically 5% and up to 25% in the extreme. This depends upon local conditions in the coolant circuit, which can give rise to different heat transfer regimes. Application of the modified correlation is outlined and illustrated.

Previously reported studies of heat transfer between the intake port surface, gas flows in the port, and fuel deposited in surface films have been extended to examine details of the heat flux variations which occur within the engine cycle. The dynamic response characteristics of the surface-mounted heat flux sensors have been determined, and measured heat flux data corrected accordingly to account for these characteristics. Details of the model and data processing technique used are described. Corrected intra-cycle variations of heat transfer to fuel deposited have been derived for engine operating conditions at 1000 RPM covering a range of manifold pressures, fuel supply rates, port surface temperatures, and fuel injection timings. Both pump-grade gasoline and isooctane fuel have been used. The effects of operating conditions on the magnitude and features of the heat flux variations are described.

Surface heat transfer measurements have been taken in the intake port of a single cylinder four valve SI engine running on isooctane fuel. The objective has been to establish how fuel characteristics affect trends in surface heat transfer rates for a range of engine operating conditions. The heat transfer measurements were made using heat flux gauges bonded to the intake port surface in the region where highest rates of fuel deposition occur. The influence on heat transfer rates of the deposited fuel and its subsequent behaviour has been examined by comparing fuel-wetted and dry-surface heat transfer measurements. Heat transfer changes are consistent with trends predicted by convective mass transfer over much of the range of surface temperatures from 20°C to 100°C. Towards the upper temperature limit heat transfer reaches a maximum limited by the rate and distribution of fuel deposition.