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Further improvements of internal combustion engines to reduce fuel consumption and to face future legislation constraints are strictly related to the study of mixture formation. The reason for that is the desire to supply the engine with homogeneous charge, towards the direction of a global stoichiometric blend in the combustion chamber. Fuel evaporation and thus mixture quality mostly depend on injector atomization features and charge motion within the cylinder. 3D-CFD simulations offer great potential to study not only injector atomization quality but also the evaporation behavior. Nevertheless coupling optical measurements and simulations for injector analysis is an open discussion because of the large number of influencing parameters and interactions affecting the fuel injection’s reproducibility. For this purpose, detailed numerical investigations are used to describe the injection phenomena.