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The 4th Workshop of the Engine Combustion Network (ECN) was held September 5-6, 2015 in Kyoto, Japan. This manuscript presents a summary of the progress in experiments and modeling among ECN contributors leading to a better understanding of soot formation under the ECN “Spray A” configuration and some parametric variants. Relevant published and unpublished work from prior ECN workshops is reviewed. Experiments measuring soot particle size and morphology, soot volume fraction (fv), and transient soot mass have been conducted at various international institutions providing target data for improvements to computational models. Multiple modeling contributions using both the Reynolds Averaged Navier-Stokes (RANS) Equations approach and the Large-Eddy Simulation (LES) approach have been submitted. Among these, various chemical mechanisms, soot models, and turbulence-chemistry interaction (TCI) methodologies have been considered.

In order to better understand in-flame diesel soot oxidation processes, soot particles at the oxidation-dominant periphery of diesel spray flame were sampled by a newly developed “suck” type soot sampler employing a high-speed solenoid valve and their morphology and nanostructure were observed via high-resolution transmission electron microscopy (HR-TEM). A single-shot diesel spray flame for the soot sampling experiment was achieved in a constant-volume vessel under a diesel-like condition. The sampler instantaneously sucks out a small portion of soot laden gases from the flame. A TEM grid holds inside the flow passage close to its entrance is immediately exposed to the gas flow induced by the suction at the upstream of the solenoid valve, so that the quick thermophoretic soot deposition onto the grid surface can effectively freeze morphology variation of soot particles during the sampling processes.

For a better understanding of soot formation and oxidation processes in conventional diesel and biodiesel spray flames, the morphology, microstructure and sizes of soot particles directly sampled in spray flames fuelled with US#2 diesel and soy-methyl ester were investigated using transmission electron microscopy (TEM). The soot samples were taken at 50mm from the injector nozzle, which corresponds to the peak soot location in the spray flames. The spray flames were generated in a constant-volume combustion chamber under a diesel-like high pressure and high temperature condition (6.7MPa, 1000K). Direct sampling permits a more direct assessment of soot as it is formed and oxidized in the flame, as opposed to exhaust PM measurements. Density of sampled soot particles, diameter of primary particles, size (gyration radius) and compactness (fractal dimension) of soot aggregates were analyzed and compared. No analysis of the soot micro-structure was made.

In-flame soot sampling based on the thermophoresis of particles and subsequent transmission electron microscope (TEM) imaging has been conducted in a diesel engine to study size, shape and structure of soot particles within the reacting diesel jet. A direct TEM sampling is pursued, as opposed to exhaust sampling, to gain fundamental insight about the structure of soot during key formation and oxidation stages. The size and shape of soot particles aggregate structure with stretched chains of spherical-like primary particles is currently an unknown for engine soot modelling approaches. However, the in-flame sampling of soot particles in the engine poses significant challenges in order to extract meaningful data. In this paper, the engine modification to address the challenges of high-pressure sealing and avoiding interference with moving valves and piston are discussed in detail.

For better understanding of soot formation and oxidation processes in a diesel spray flame, two kinds of planar soot imaging techniques, Laser-Induced Incandescence (LII) and Laser Scattering (LS) techniques, were applied simultaneously to a diesel spray flame in a constant-volume combustion vessel under a diesel-like condition (2.5MPa, 940K). An analysis of LII and LS images yielded 2-dimensional distribution images of concentration, size and number density of soot particles in the spray flame, based on an assumption that LII and LS signals are proportional to the soot particle size to the power of 3 and 6, respectively. In order to obtain clearer variation trend in the soot concentration, size and number density distribution in significantly fluctuating single-shot diesel spray flames, spontaneous and time-integrated ensemble averaging of the laser-measured images were employed.

In order to examine the effect of aromatic addition to Fischer-Tropsch Diesel (FTD) fuel on formation and oxidation processes of soot particles in diesel spray flame, small amount of naphthalene (0 to 65,000 ppm) was added to the FTD fuel and variation of soot morphology and nanostructure of primary soot particles directly sampled in a diesel spray flame were investigated via High-Resolution Transmission Electron Microscopy (HRTEM). A single-shot diesel spray flame was achieved in a constant volume combustion chamber under a diesel-like condition (Ta=1000K, Pa=2.7MPa) and a grid for HRTEM observation was directly exposed to the spray flame to thermophoretically sample soot particles onto the grid surface. The primary particle diameter, aggregate gyration radius, lattice fringe length, lattice fringe tortuosity and lattice fringe separation of soot particles sampled at different locations (from 60 to 90mm from nozzle tip) in the spray flame were analyzed.

The environmental impact of aircraft, specifically in the areas of noise and NOx emissions, has been a growing community concern. Coupled with the increasing cost and diminishing supply of traditional fossil fuels, these concerns have fueled substantial interest in the research and development of alternative power sources for aircraft. In 2003, NASA and the Department of Defense awarded a five year research cooperative agreement to a team of researchers from three different universities to address the design and analysis of revolutionary aeropropulsion technologies.

The accelerated ash loading of diesel particulate filters (DPFs) with diesel oxidation catalysts (DOCs) mounted upstream by lube-oil derived products was investigated using a single cylinder diesel engine and fuel blended with 5% lube oil. An ash loading protocol is developed which combines soot loading, active soot regeneration, and periodic shutdowns for filter weighing. Active regeneration is accomplished by exhaust injection of diesel fuel, initiated by a backpressure criteria and providing DPF temperatures up to 700°C. In developing this protocol, five DPFs of various combinations of substrates (cordierite, silicon carbide, and mullite) and washcoats (none, low PGM, and high PGM) are used and evaluated. The initial backpressure and rate of backpressure increase with ash varied with each of the DPFs and ash was observed to have an effect on the active soot light-off temperature for the catalyzed DPFs.

Carbon monoxide poisoning from the exhaust of gasoline fueled electric generators on houseboats is a recognized safety hazard. Reducing this hazard by changing the exhaust termination from the waterline location to above the vessel is examined. A CO concentration survey is discussed and the use of smoke to follow the exhaust gas flow patterns is presented with photographs. Conventional waterline exhaust terminations produced CO concentrations above the 1200 PPM that is the Immediately Dangerous to Life and Health value. A vertical stack with a termination above the highest point on the vessel was examined and no CO concentrations of significance were measured on or near the vessel.

In gasoline direct injection engines, fuel is injected into the port walls and the valve. During the engine startup cycle, the temperature of these parts is not adequate to evaporate all the fuel that impacts the walls. As a result, a fraction of the injected fuel does not contribute to the combustion cycle. This fraction forms fuel puddles (wall-wetting) and a portion of it passes to the crankcase. The efficiency of the engine during the startup cycle is decreased and hydrocarbon emissions increased. It is obvious that a control strategy is necessary to minimize the effects of this transient performance of the engine. This paper investigates a modeling framework for the valve, and simulation results validate model performance when compared to available experimental data. The simulation studies lead to a conceptual control design, which is briefly outlined.

Laser plasma ignition has been pursued by engine researchers as an alternative to electric spark-ignition systems, potentially offering benefits by avoiding quenching surfaces and extending breakdown limits at higher boost pressure and lower equivalence ratio. For this study, we demonstrate another potential benefit: the ability to control the timing of ignition with short, nanosecond pulses, thereby optimizing the type of mixture that burns in rapidly changing, stratified fuel-air mixtures. We study laser ignition at various timings during single and double injections at simulated gasoline engine conditions within a controlled, high-temperature, high-pressure vessel. Laser ignition is accomplished with a single low-energy (10 mJ), short duration (8 ns) Nd:YAG laser beam that is tightly focused (0.015 mm average measured 1/e₂ diameter) at a typical GDI spark plug location.

For better understanding of soot formation and oxidation processes in a biodiesel spray flame, the morphology, microstructure and sizes of soot particles directly sampled in a spray flame fuelled with soy-methyl ester were investigated using transmission electron microscopy (TEM). The soot samples were taken at different axial locations in the spray flame, 40, 50 and 70 mm from injector nozzle, which correspond to soot formation, peak, and oxidation zones, respectively. The biodiesel spray flame was generated in a constant-volume combustion chamber under a diesel-like high pressure and temperature condition (6.7 MPa, 1000K). Density, diameter of primary particles and radius of gyration of soot aggregates reached a peak at 50 mm from the injector nozzle and was lower or smaller in the formation or oxidation zones of the spray.

This presentation is an assessment of the turbulence-stress scale-similarity in an IC engine, which is used for modeling subgrid dissipation in LES. Residual stresses and Leonard stresses were computed after applying progressively smaller spatial filters to measured and simulated velocity distributions. The velocity was measured in the TCC-II engine using planar and stereo PIV taken in three different planes and with three different spatial resolutions, thus yielding two and three velocity components, respectively. Comparisons are made between the stresses computed from the measured velocity and stress computed from the LES resolved-scale velocity from an LES simulation. The results present the degree of similarity between the residual stresses and the Leonard stresses at adjacent scales. The specified filters are systematically reduced in size to the resolution limits of the measurements and simulation.

For better understanding of soot formation and oxidation processes in diesel spray flame, the nanostructure of primary soot particles directly sampled in a diesel spray flame was investigated via High-Resolution Transmission Electron Microscopy (HRTEM). A single-shot diesel spray flame was achieved in a constant volume combustion vessel under diesel-like conditions (Ta=1000K, Pa=2.7 MPa) and a micro-grid for HRTEM observation was directly exposed to the spray flame to thermophoretically sample soot particles onto the grid surface. A preliminary nanostructure investigation was conducted for x500k magnification HRTEM images of soot particles directly sampled in diesel spray flames of Fischer-Tropsch Diesel (FTD) fuel seeded with naphthalene as a representative aromatic substance. A MATLAB code for HRTEM image processing and analysis of lattice fringes within primary soot particles was developed and used to characterize the length, tortuosity and separation of lattice fringes.

Proof-of-concept testing was performed to determine the effectiveness of a computer controlled air pump (CCAP) in reducing the unburned hydrocarbons (UHC) and carbon monoxide (CO) emitted from automobile engines. For the initial phase of testing, a prototype CCAP was designed and evaluated on a dynamometer test-stand at the University of Tennessee. This CCAP maintained the engine's exhaust at a stoichiometric air/fuel ratio by utilizing a second oxygen sensor mounted downstream from the catalyst. In this way, the catalyst's conversion efficiency for CO and UHC was always high, even if the engine was running rich. Results of this steady-state testing indicated that the CCAP was able to reduce UHC and CO emissions without a corresponding increase in oxide of nitrogen (NOx) emissions. Additionally, catalyst temperatures did not increase dramatically.

The highly successful Galileo mission made a number of startling and remarkable discoveries during its eight-year tour in the harsh Jupiter radiation environment. Two of these revelations were: 1) salty oceans lying under an icy crust of the Galilean moons: Europa, Ganymede and Callisto, and 2) the possible existence or remnants of life, especially on Europa, which has a very tenuous atmosphere of oxygen. Galileo radiation measurement data from the Energetic Particle Detector (EPD) have been used (Garrett et al., 2003) to update the trapped electron environment model, GIRE: Galileo Interim Radiation Environment, in the range of L (L: McIlwain parameter – see ref. 6) = 8–16 Rj (Rj: radius of Jupiter ≈ 71,400 km) with plans to extend the model for both electrons and protons as more data are reduced and analyzed.

A rapid compression-expansion machine which can simulate the combustion processes in diesel engines is developed. The configuration of the combustion chamber is a 100 mm bore and a 90 mm stroke, and the compression ratio is 15. The piston is driven by an electro-hydraulic system with a thrust of 90 kN and the maximum frequency of 20 Hz. The whole system composed of a hydraulic actuator, a fuel injection system, and a valve driving unit is sequentially controlled by a computer. The reproducibility of the stop position of the piston at the end of compression is achieved with an accuracy of ±0.1 mm by employing a hydraulic-mechanical brake mechanism. The experiment shows that the combustion in the expansion stroke is achieved, and that the combustion characteristics such as the rate of heat release and indicated output as well as the exhaust emission can be measured.

As interest has grown in diesel emissions and diesel engine aftertreatment, so has the importance of analyzing all components of the exhaust. One of the more costly and difficult measurements to make is the collection and analysis of semivolatile organic compounds (SOCs) in the exhaust. These compounds include alkane and alkenes from C12-C24, and the 2-5 ring polycyclic aromatic hydrocarbons (PAH). These compounds can be present in both the particulate (i.e. on the filter) and gaseous phase, and cannot be collected with bag samples. Typically, a sorbent is used downstream of the particulate collection filters to collect these compounds. Sorbent phases include polyurethane foam (PUF), Tenax™, XAD-type resins, and activated carbon. The SOCs are removed from the sorbent either by solvent extraction (PUF and XAD) or thermal desorption (Tenax™ and activated carbon). Each of these methods have advantages and disadvantages.

A mixed timescale subgrid model of a large eddy simulation was used to simulate the turbulence regime in diesel engine combustion. The combustion model used the direct integration approach with a diesel oil surrogate mechanism (developed at Chalmers University of Technology and consisting of 70 species and 309 reactions). Additional reactions for the generation and consumption of OH*, CO2*, and CH* species were added from recent kinetic studies. Collisional quenching and spontaneous emission resulted in de-excitation of the excited state radical. A phenomenological soot formation model (developed at Waseda University) was combined with the LES code. The following important steps were considered in the soot model: particle inception where naphthalene grows irreversibly to form soot, surface growth with the addition of C2H2, surface oxidation (induced by OH radicals and O2 attack), and particle coagulation.

Currently, the interest in using alternative clean types of fuels has been extensively increased all over the world because of the global approach in reducing engine emissions and creating new sources of fuel for internal combustion engines. The hydrogen-methane blend is one of the alternative fuels which includes the benefits of both of the fuels compared to the traditional petrol/gasoline fuel. This paper addresses a two-zone quasi-dimensional model to investigate the performance of an SI engine which uses a mixture of methane and hydrogen. In this model, gases inside the cylinder are divided into two regions: burned and the unburned. The chemical reactions are supposed to be in equilibrium in each zone, but the extended Zedlovich mechanism is utilized to determine the amount of the NOx available in the exhaust gas. Also, CO concentration is determined by two steps kinematic reactions. The flame front is assumed to be a surface with no thickness in adiabatic flame temperature.