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In this work hemp fibers were chemically treated in order to improve the fiber/matrix interaction in hemp fiber/unsaturated polyester composites prepared by a Resin Transfer Molding (RTM) process. Chemicals used for paper sizing (AKD, ASA, Rosin Acid and SMA) as well as a silane compound and sodium hydroxide were used to modify the fibers' surface. The tensile, flexural and impact properties of the resulting materials were measured. A slight improvement in mechanical properties was observed for the SMA, silane and alkali treated specimens. However close analysis of these tests and of the fracture surface of the samples showed that there was no amelioration of the fiber/matrix adhesion. It was found that predicted tensile strengths using the rule of mixture were very close to the experimental values obtained in this work. Finally the properties of an hybrid glass fiber/hemp fiber composite were found to be very promising

Natural fiber reinforced polymer composites are beginning to find their way into the commercial automotive market. But, inadequate adhesion between hydrophilic natural fibers and hydrophobic matrix materials affects the performance of the resulting composites. In this study the effect of an environmental friendly fungal treatment on the adhesion characteristics of natural fibers is investigated. Firstly, changes in acid-base characteristics of the modified hemp fibers were studied using Inverse Gas Chromatography (IGC). Afterwards, composites were prepared using Resin Transfer Molding (RTM) process and the effect of modification on performance and durability of the composites was investigated.