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We are witnessing a rapid and ongoing expansion of nanoscience, driven by potential applications in advanced materials and nanotechnology. There is a race to develop techniques that may allow controlling the size, shape of nanostructures that can allow the tuning of their optical and electronic properties. Plasmonics is a field that encompasses and profits from the optical enhancement in nanostructures that support plasmon excitations. One of these new techniques is surface-enhanced Raman scattering (SERS), commonly used for nanostructure characterization. In the present report, we present a theoretical model for plasmon excitation and electric field enhancement that help to provide an explanation for the special features observed in experimental SERS. Two sets of experimental results are discussed illustrating the make out of the signature of the plasmonics producing the optical enhancement.

Gray cast iron brake rotor experiences substantial wear during braking and contributes largely to the wear debris emissions. Surface coating on the gray cast iron rotor represents a trending approach dealing with the problems. In this research, a new plasma electrolytic aluminating (PEA) process was used for preparing an alumina-based ceramic coating with metallurgical bonding to the gray cast iron. Three different types of brake pads (ceramic, semi-metallic and non asbestos organic (NAO)) were used for tribotests. Performances of PEA coatings vs. different brake pad materials were comparatively investigated with respect to their coefficients of friction (COFs) and wear. The PEA-coated brake rotor has a dimple-like surface which promotes the formation of a thin transferred film to protect the rotor from wear. The transferred film materials come from the wear debris of the pads. The secondary plateaus are regenerated on the brake pads through compacting wear debris of the pads.

Empirical work has been conducted with an EGR fuel reformer configured in a flow reversal and central fueling embedment to improve the fuel dispersion quality and the reforming energy efficiency. Comprehensive comparison analyses are made between the unidirectional flow and the periodic reversal flow embodiments of similar substrate size and properties; and between the inlet and central heating schemes. With a unidirectional EGR reformer, a large amount of supplemental heating is commonly required prior to reforming. The central-fueling and flow-reversal embedment in this study is shown to significantly reduce the supplemental heating energy. The EGR cooler loading for the two strategies is also analyzed. One-dimensional modeling analyses are conducted to evaluate the fuel delivery strategies and temperature profiles of the reformer at various reforming gas flow rates and engine-out exhaust temperatures and compositions.

Sliding wear of magnesium (Mg) engine cylinder bore surfaces and corrosion of Mg engine coolant channels are the two unsolved critical issues that automakers have to deal with in development of magnesium-intensive engines. In this paper, Plasma Electrolytic Oxidation (PEO) process was used to produce oxide coatings on AJ62 Mg alloy to provide wear and corrosion protection. In order to optimize the PEO process, orthogonal experiments were conducted to investigate the effect of PEO process parameters on the wear properties of PEO coatings. The PEO coatings showed a much better wear resistance, as well as a smaller friction coefficient, than the AJ62 substrate. The galvanic corrosion property of AJ62 Mg coupled with stainless steel and aluminum (Al) was investigated via immersion corrosion test in an engine coolant. Applying PEO coating on Mg can effectively prevent the galvanic corrosion attack to Mg.

Friction between the piston and cylinder accounts for large amount of the friction losses in an internal combustion (IC) engine. Therefore, any effort to minimize such a friction will also result in higher efficiency, lower fuel consumption and reduced emissions. Plasma electrolytic oxidation (PEO) coating is considered as a hard ceramic coating which can provide a dimpled surface for oil retention to bear the wear and reduce the friction from sliding piston rings. In this work, a high speed pin-on-disc tribometer was used to generate the boundary, mixed and hydrodynamic lubrication regimes. Five different lubricating oils and two different loads were applied to do the tribotests and the COFs of a PEO coating were studied. The results show that the PEO coating indeed had a lower COF in a lower viscosity lubricating oil, and a smaller load was beneficial to form the mixed and hydrodynamic lubricating regimes earlier.

Ultra-high strength steel (UHSS) and magnesium (Mg) alloy have found their importance in response to automotive strategy of light weighting. UHSS to be metal-formed by hot stamping usually has a hot-dipped aluminum-silicon alloy layer on its surface to prevent the high temperature scaling during the hot stamping and corrosion during applications. In this paper, a plasma electrolytic oxidation (PEO) process was used to produce ceramic oxide coatings on aluminized UHSS and Mg with intention to further improve their corrosion resistances. A potentiodynamic polarization corrosion test was employed to evaluate general corrosion properties of the individual alloys. Galvanic corrosion of the aluminized UHSS and magnesium alloy coupling with and without PEO coatings was studied by a zero resistance ammeter (ZRA) test. It was found that the heating-cooling process simulating the hot stamping would reduce anti-corrosion properties of aluminized UHSS due to the outward iron diffusion.

Alumina (Al2O3) thin film coatings are applied on Al alloys using Plasma Electrolytic Oxidation (PEO) method to reduce the wear and corrosion problems. Plasma Electrolytic Aluminating (PEA) is a technique which could generate Alumina coatings on cast iron, mild steel and copper alloys. In this study, the aim is to explore the anti-wear and anti-corrosion behaviours of PEA Alumina coatings on gray cast iron. The dry sliding tribology test data was obtained from Pin-on-Disk (POD) tests against SAE 52100 steel and Tungsten Carbide (WC) counterfaces. Comparing with the PEO Alumina coatings, the PEA Alumina coating has much lower Coefficient of Friction (COF) and less wear. The microstructure, chemical composition and phase composition of this coating were investigated with Scanning Electron Microscope (SEM), Energy-Dispersive X-Ray Spectroscopy (EDX) and X-Ray Diffraction (XRD), respectively. There was FeO (or FeAl2O4) found on the PEA Alumina coating.

In recent years, bearing electrical failures have been a significant concern in electric cars, restricting electric engine life. This work aims to introduce a coating approach for preventing electrical erosion on 52100 alloy steel samples, the most common material used on manufacturing bearings. This paper discusses the causes of shaft voltage and bearing currents, and summarizes standard electrical bearing failure mechanisms, such as morphological damages and lubrication failures. Alumina coatings are suitable for insulating the 52100 alloy steel samples because alumina coatings provide excellent insulation, hardness, and corrosion resistance, among other characteristics. The common method to coat an insulated alumina coating on the bearing is thermal spraying, but overspray can cause environmental issues, and the coating procedures are costly and time-consuming.

In order to reduce the weight of an automotive engine, an aluminum (Al) alloy engine block with cast iron liner has been successfully used to replace the gray cast iron engine. For newly emerging Al linerless engine in which the low surface hardness of the aluminum alloy has to be overcome, a few surface processing technologies are used to protect the surface of cylinders. Among them, plasma transferred wire arc (PTWA) thermal spraying coating is becoming popular. Plasma electrolytic oxidation (PEO) coating is also proposed for increasing the wear resistance of aluminum alloy and reducing the friction between the cylinder and piston. In this work, a PEO coating with a thickness of ∼20 μm was prepared, and a high speed pin-on-disc tribometer was used to study the tribological behavior of the coating at oil lubricant conditions. Different surface roughness of the coating and a large range of the sliding speeds were employed for the tests.

Aluminum engines have been successfully used to replace heavy gray cast engines to lighten the car's weight and reduce the fuel consumption. To overcome the aluminum alloys' poor wear resistance, cast iron liners and thermal spraying coatings were used as cylinder bore materials for wear protection. A plasma electrolytic oxidation (PEO) technique had also been proposed to produce an oxide coating on aluminum cylinder bore. The oxide coating can have a low coefficient of friction (COF) and minimum wear shown in the lab tests. To conserve more fuel, the stopping and restarting system was introduced when the vehicle was forced to stop immediately for a short time. When the engine was forced to stop and restart, the reciprocating speed of the piston was very slow, and the friction between the piston and the cylinder was high. In this research, a pin-on-disc tribometer was used to investigate tribological behavior of the oxide coating on an aluminum alloy.

The development of a collision severity model can serve as an important tool in understanding the requirements for devising countermeasures to improve occupant safety and traffic safety. Collision type, weather conditions, and driver intoxication are some of the factors that may influence motor vehicle collisions. The objective of this study is to use artificial neural networks (ANNs) to identify the major determinants or contributors to fatal collisions based on various driver, vehicle, and environment characteristics obtained from collision data from Transport Canada. The developed model will have the capability to predict similar collision outcomes based on the variables analyzed in this study. A multilayer perceptron (MLP) neural network model with feed-forward back-propagation architecture is used to develop a generalized model for predicting collision severity. The model output, collision severity, is divided into three categories - fatal, injury, and property damage only.

Amid all nondestructive testing (NDT) methods Ultrasound is considered the most practically feasible modality for quality assessment and detection of defects in automobile industry. Pattern recognition of the ultrasonic signals gives us important information about the interrogated object. This information includes size, geometric shape and location of the defect zone. However, this would not be straightforward to extract this information from the backscattered echoes due to the overlapping signals and also the presence of noise. Here in this study, we suggest a new method for classification of different defects in inspection of adhesively bonded joint. At the first step of this method, the problem of parameter estimation of the reflected echoes is defined in a Maximum Likelihood Estimation (MLE) framework. Then a space alternating generalized Expectation Maximization (SAGE) algorithm is implemented to solve the MLE problem.

Following the development of new technologies in Vehicle Thermal Management aiming to both enhancing the MAC System efficiency and reducing the thermal load to be managed, a prediction tool based on the AMEsim platform was developed at Advanced PD EMEA. This tool is dedicated to predict the effect of the implementation of sensors monitoring both the relative humidity and the carbon dioxide (CO2) concentration (taking into account passengers' generated moisture and CO2). This model implemented with the usual comfort inputs (CO2 and RH acceptable ranges) considers the system variables influencing the comfort and predicts the increase of both RH and CO2 concentration in the cabin compartment in any driving cycle depending on the number of occupants.

Light-weighting of vehicles is one of the challenges for transportation industry due to the increasing pressure of demands in better fuel economy and environment protection. Advanced high strength steels (AHSS) are considered as prominent material of choice to realize lightweight auto body and structures at least in near term. Stamping of AHSS with conventional die materials and surface coatings, however, results in frequent die failures and undesired panel surface finish. A chromium nitride (CrN) coating with plasma nitriding case hardened layer on a die material (duplex treatment) is found to offer good wear and galling resistances. The coating failure initiates from fatigue cracking on the coating surface due to cyclic sliding frictions. In this work, cyclic inclined sliding wear test was used to imitate a stamping process for study on development of coating fatigue cracking, including crack length and spacing vs. sliding-cycles and sliding energy densities.