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We are witnessing a rapid and ongoing expansion of nanoscience, driven by potential applications in advanced materials and nanotechnology. There is a race to develop techniques that may allow controlling the size, shape of nanostructures that can allow the tuning of their optical and electronic properties. Plasmonics is a field that encompasses and profits from the optical enhancement in nanostructures that support plasmon excitations. One of these new techniques is surface-enhanced Raman scattering (SERS), commonly used for nanostructure characterization. In the present report, we present a theoretical model for plasmon excitation and electric field enhancement that help to provide an explanation for the special features observed in experimental SERS. Two sets of experimental results are discussed illustrating the make out of the signature of the plasmonics producing the optical enhancement.

Gray cast iron brake rotor experiences substantial wear during braking and contributes largely to the wear debris emissions. Surface coating on the gray cast iron rotor represents a trending approach dealing with the problems. In this research, a new plasma electrolytic aluminating (PEA) process was used for preparing an alumina-based ceramic coating with metallurgical bonding to the gray cast iron. Three different types of brake pads (ceramic, semi-metallic and non asbestos organic (NAO)) were used for tribotests. Performances of PEA coatings vs. different brake pad materials were comparatively investigated with respect to their coefficients of friction (COFs) and wear. The PEA-coated brake rotor has a dimple-like surface which promotes the formation of a thin transferred film to protect the rotor from wear. The transferred film materials come from the wear debris of the pads. The secondary plateaus are regenerated on the brake pads through compacting wear debris of the pads.

Sliding wear of magnesium (Mg) engine cylinder bore surfaces and corrosion of Mg engine coolant channels are the two unsolved critical issues that automakers have to deal with in development of magnesium-intensive engines. In this paper, Plasma Electrolytic Oxidation (PEO) process was used to produce oxide coatings on AJ62 Mg alloy to provide wear and corrosion protection. In order to optimize the PEO process, orthogonal experiments were conducted to investigate the effect of PEO process parameters on the wear properties of PEO coatings. The PEO coatings showed a much better wear resistance, as well as a smaller friction coefficient, than the AJ62 substrate. The galvanic corrosion property of AJ62 Mg coupled with stainless steel and aluminum (Al) was investigated via immersion corrosion test in an engine coolant. Applying PEO coating on Mg can effectively prevent the galvanic corrosion attack to Mg.

Friction between the piston and cylinder accounts for large amount of the friction losses in an internal combustion (IC) engine. Therefore, any effort to minimize such a friction will also result in higher efficiency, lower fuel consumption and reduced emissions. Plasma electrolytic oxidation (PEO) coating is considered as a hard ceramic coating which can provide a dimpled surface for oil retention to bear the wear and reduce the friction from sliding piston rings. In this work, a high speed pin-on-disc tribometer was used to generate the boundary, mixed and hydrodynamic lubrication regimes. Five different lubricating oils and two different loads were applied to do the tribotests and the COFs of a PEO coating were studied. The results show that the PEO coating indeed had a lower COF in a lower viscosity lubricating oil, and a smaller load was beneficial to form the mixed and hydrodynamic lubricating regimes earlier.

Ultra-high strength steel (UHSS) and magnesium (Mg) alloy have found their importance in response to automotive strategy of light weighting. UHSS to be metal-formed by hot stamping usually has a hot-dipped aluminum-silicon alloy layer on its surface to prevent the high temperature scaling during the hot stamping and corrosion during applications. In this paper, a plasma electrolytic oxidation (PEO) process was used to produce ceramic oxide coatings on aluminized UHSS and Mg with intention to further improve their corrosion resistances. A potentiodynamic polarization corrosion test was employed to evaluate general corrosion properties of the individual alloys. Galvanic corrosion of the aluminized UHSS and magnesium alloy coupling with and without PEO coatings was studied by a zero resistance ammeter (ZRA) test. It was found that the heating-cooling process simulating the hot stamping would reduce anti-corrosion properties of aluminized UHSS due to the outward iron diffusion.

Modularity in product architecture and its significance in product development have become an important product design topics in the last few decades. Several Product Modularity definitions and methodologies were developed by many researchers; however, most of the definitions and concepts have proliferated to the extent that it is difficult to apply one universal definition for modular product architecture and in product development. Automotive seat modular strategy and key factors for consideration towards modular seat design and assemblies are the main focus of this work. The primary objectives are focused on the most “natural segmentation” of the seat elements (i.e., cushions, backs, trims, plastics, head restraints, etc.) to enable the greatest ease of final assembly and greatest flexibility for scalable feature offerings around common assembly “hard-points.”

Alumina (Al2O3) thin film coatings are applied on Al alloys using Plasma Electrolytic Oxidation (PEO) method to reduce the wear and corrosion problems. Plasma Electrolytic Aluminating (PEA) is a technique which could generate Alumina coatings on cast iron, mild steel and copper alloys. In this study, the aim is to explore the anti-wear and anti-corrosion behaviours of PEA Alumina coatings on gray cast iron. The dry sliding tribology test data was obtained from Pin-on-Disk (POD) tests against SAE 52100 steel and Tungsten Carbide (WC) counterfaces. Comparing with the PEO Alumina coatings, the PEA Alumina coating has much lower Coefficient of Friction (COF) and less wear. The microstructure, chemical composition and phase composition of this coating were investigated with Scanning Electron Microscope (SEM), Energy-Dispersive X-Ray Spectroscopy (EDX) and X-Ray Diffraction (XRD), respectively. There was FeO (or FeAl2O4) found on the PEA Alumina coating.

In recent years, bearing electrical failures have been a significant concern in electric cars, restricting electric engine life. This work aims to introduce a coating approach for preventing electrical erosion on 52100 alloy steel samples, the most common material used on manufacturing bearings. This paper discusses the causes of shaft voltage and bearing currents, and summarizes standard electrical bearing failure mechanisms, such as morphological damages and lubrication failures. Alumina coatings are suitable for insulating the 52100 alloy steel samples because alumina coatings provide excellent insulation, hardness, and corrosion resistance, among other characteristics. The common method to coat an insulated alumina coating on the bearing is thermal spraying, but overspray can cause environmental issues, and the coating procedures are costly and time-consuming.

In order to reduce the weight of an automotive engine, an aluminum (Al) alloy engine block with cast iron liner has been successfully used to replace the gray cast iron engine. For newly emerging Al linerless engine in which the low surface hardness of the aluminum alloy has to be overcome, a few surface processing technologies are used to protect the surface of cylinders. Among them, plasma transferred wire arc (PTWA) thermal spraying coating is becoming popular. Plasma electrolytic oxidation (PEO) coating is also proposed for increasing the wear resistance of aluminum alloy and reducing the friction between the cylinder and piston. In this work, a PEO coating with a thickness of ∼20 μm was prepared, and a high speed pin-on-disc tribometer was used to study the tribological behavior of the coating at oil lubricant conditions. Different surface roughness of the coating and a large range of the sliding speeds were employed for the tests.

Aluminum engines have been successfully used to replace heavy gray cast engines to lighten the car's weight and reduce the fuel consumption. To overcome the aluminum alloys' poor wear resistance, cast iron liners and thermal spraying coatings were used as cylinder bore materials for wear protection. A plasma electrolytic oxidation (PEO) technique had also been proposed to produce an oxide coating on aluminum cylinder bore. The oxide coating can have a low coefficient of friction (COF) and minimum wear shown in the lab tests. To conserve more fuel, the stopping and restarting system was introduced when the vehicle was forced to stop immediately for a short time. When the engine was forced to stop and restart, the reciprocating speed of the piston was very slow, and the friction between the piston and the cylinder was high. In this research, a pin-on-disc tribometer was used to investigate tribological behavior of the oxide coating on an aluminum alloy.

Light-weighting of vehicles is one of the challenges for transportation industry due to the increasing pressure of demands in better fuel economy and environment protection. Advanced high strength steels (AHSS) are considered as prominent material of choice to realize lightweight auto body and structures at least in near term. Stamping of AHSS with conventional die materials and surface coatings, however, results in frequent die failures and undesired panel surface finish. A chromium nitride (CrN) coating with plasma nitriding case hardened layer on a die material (duplex treatment) is found to offer good wear and galling resistances. The coating failure initiates from fatigue cracking on the coating surface due to cyclic sliding frictions. In this work, cyclic inclined sliding wear test was used to imitate a stamping process for study on development of coating fatigue cracking, including crack length and spacing vs. sliding-cycles and sliding energy densities.