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The Hybrid Electric Vehicle Team of Virginia Tech participated in the three-year EcoCAR Advanced Vehicle Technology Competition organized by Argonne National Laboratory, and sponsored by General Motors and the U.S. Department of Energy. The team established goals for the design of a plug-in, range-extended hybrid electric vehicle that meets or exceeds the competition requirements for EcoCAR. The challenge involved designing a crossover SUV powertrain to reduce fuel consumption, petroleum energy use, regulated tailpipe emissions, and well-to-wheel greenhouse gas emissions. To interface with and control the hybrid powertrain, the team added a Hybrid Vehicle Supervisory Controller, which enacts a torque split control strategy. This paper builds on an earlier paper [1] that evaluated the petroleum energy use, criteria tailpipe emissions, and greenhouse gas emissions of the Virginia Tech EcoCAR vehicle and control strategy from the 2nd year of the competition.

Biodiesel has been widely accepted as an alternative for fossil-derived diesel fuel for use in compression ignition (CI) engines. Poor oxidative stability and cold flow properties restrict the use of biodiesel beyond current B20 blend levels (20% biodiesel in 80% ULSD) for vehicle applications. Maintaining the properties of B20 as specified by ASTM D7476-08 is important because, once out of spec, B20 may cause injector coke formation, fuel filter plugging, increased exhaust emissions, and overall loss of engine performance. While the properties of fresh B20 may be within the specifications, under engine operating and longer storage conditions B20 could deteriorate. In a diesel engine, the fuel that goes to the injector and does not enter the cylinder is recycled back to the fuel tank. The re-circulated fuel returns to the fuel tank at an elevate temperature, which can cause thermal oxidation.

The use of butanol as an alternative biofuel blend component for conventional diesel fuel has been under extensive investigation. However, some fuel properties such as cetane number and lubricity fall below the accepted values as described by the ASTM D 975 diesel specifications. Blending 10% butanol with #2 ULSD decreases the cetane number by 7% (from 41.6 to 39.0). At higher butanol blend levels, i.e., 20% v/v, the cetane number decrease cannot be compensated for; even with the addition of a 2000 ppm level commercial cetane improver. The decreased cetane number, or in other words, increased ignition delay, can be attributed to the increased blend level of low cetane butanol as well as the critical physical properties for better atomization of fuels during auto ignition such as viscosity. The kinematic viscosity dropped sharply with increasing butanol blend level up to 25 % v/v, then increased with further increase of butanol blend level.

Under the borderline autoignition conditions experienced during cold-starting of diesel engines, the amount and composition of residual gases may play a deterministic role. Among the intermediate species produced by misfiring and partially firing cycles, formaldehyde (HCHO) is produced in significant enough amounts and is sufficiently stable to persist through the exhaust and intake strokes to kinetically affect autoignition of the following engine cycle. In this work, the effect of HCHO addition at various phases of autoignition of n-heptane-air mixtures is kinetically modeled. Results show that HCHO has a retarding effect on the earliest low-temperature heat release (LTHR) phase, largely by competition for hydroxyl (OH) radicals which inhibits fuel decomposition. Conversely, post-LTHR, the presence of HCHO accelerates the occurrence of high-temperature ignition.

Low temperature combustion through in-cylinder blending of fuels with different reactivity offers the potential to improve engine efficiency while yielding low engine-out NOx and soot emissions. A Navistar MaxxForce 13 heavy-duty compression ignition engine was modified to run with two separate fuel systems, aiming to utilize fuel reactivity to demonstrate a technical path towards high engine efficiency. The dual-fuel engine has a geometric compression ratio of 14 and uses sequential, multi-port-injection of a low reactivity fuel in combination with in-cylinder direct injection of diesel. Through control of in-cylinder charge reactivity and reactivity stratification, the engine combustion process can be tailored towards high efficiency and low engine-out emissions. Engine testing was conducted at 1200 rpm over a load sweep.

The study of spray-wall interaction is of great importance to understand the dynamics that occur during fuel impingement onto the chamber wall or piston surfaces in internal combustion engines. It is found that the maximum spreading length of an impinged droplet can provide a quantitative estimation of heat transfer and energy transformation for spray-wall interaction. Furthermore, it influences the air-fuel mixing and hydrocarbon and particle emissions at combusting conditions. In this paper, an analytical model of a single diesel droplet impinging on the wall with different inclined angles (α) is developed in terms of βm (dimensionless maximum spreading length, the ratio of maximum spreading length to initial droplet diameter) to understand the detailed impinging dynamic process.

Use of ethanol as gasoline replacement can contribute to the reduction of nitrogen oxide (NOx) and carbon oxide (CO) emissions. Depending on ethanol production, significant reduction of greenhouse-gas emissions is possible. Concentration of certain species, such as unburned ethanol and acetaldehyde in the engine-out emissions are known to rise when ratio of ethanol to gasoline increases in the fuel. This research explores on hydrous ethanol fueled port-fuel injection (PFI) spark ignition (SI) engine emissions that contribute to photochemical formation of ozone, or so-called ozone precursors and the precursor of peroxyacetyl nitrates (PANs). The results are compared to engine operation on gasoline. Concentration obtained by FTIR gas analyzer, and mass-specific emissions of formaldehyde (HCHO), acetaldehyde (MeCHO) and methane (CH4) under two engine speed, four load and two spark advance settings are analyzed and presented.

Interest in natural gas as an alternative fuel source to petroleum fuels for light-duty vehicle applications has increased due to its domestic availability and stable price compared to gasoline. With its higher hydrogen-to-carbon ratio, natural gas has the potential to reduce engine out carbon dioxide emissions, which has shown to be a strong greenhouse gas contributor. For part-load conditions, the lower flame speeds of natural gas can lead to an increased duration in the inflammation process with traditional port-injection. Direct-injection of natural gas can increase in-cylinder turbulence and has the potential to reduce problems typically associated with port-injection of natural gas, such as lower flame speeds and poor dilution tolerance. A study was designed and executed to investigate the effects of direct-injection of natural gas at part-load conditions.

The 4th Workshop of the Engine Combustion Network (ECN) was held September 5-6, 2015 in Kyoto, Japan. This manuscript presents a summary of the progress in experiments and modeling among ECN contributors leading to a better understanding of soot formation under the ECN “Spray A” configuration and some parametric variants. Relevant published and unpublished work from prior ECN workshops is reviewed. Experiments measuring soot particle size and morphology, soot volume fraction (fv), and transient soot mass have been conducted at various international institutions providing target data for improvements to computational models. Multiple modeling contributions using both the Reynolds Averaged Navier-Stokes (RANS) Equations approach and the Large-Eddy Simulation (LES) approach have been submitted. Among these, various chemical mechanisms, soot models, and turbulence-chemistry interaction (TCI) methodologies have been considered.

The importance of radiative heat transfer on the combustion and soot formation characteristics under nominal ECN Spray A conditions has been studied numerically. The liquid n-dodecane fuel is injected with 1500 bar fuel pressure into the constant volume chamber at different ambient conditions. Radiation from both gas-phase as well as soot particles has been included and assumed as gray. Three different solvers for the radiative transfer equation have been employed: the discrete ordinate method, the spherical-harmonics method and the optically thin assumption. The radiation models have been coupled with the transported probability density function method for turbulent reactive flows and soot, where unresolved turbulent fluctuations in temperature and composition are included and therefore capturing turbulence-chemistry-soot-radiation interactions. Results show that the gas-phase (mostly CO2 ad H2O species) has a higher contribution to the net radiation heat transfer compared to soot.

The Department of Defense (DOD) has adopted the use of JP-8 under the “single battlefield fuel” policy. Fuel properties of JP-8 which are different from ULSD include cetane number, density, heating value and compressibility (Bulk modulus). While JP8 has advantages compared to ULSD, related to storage, combustion and lower soot emissions, its use cause a drop in the peak power in some military diesel engines. The engines that has loss in power use the Hydraulically actuated Electronic Unit Injection (HEUI) fuel system. The paper explains in details the operation of HEUI including fuel delivery into the injector and its compression to the high injection pressure before its delivery in the combustion chamber. The effect of fuel compressibility on the volume of the fuel that is injected into the combustion chamber is explained in details.

Stringent emission standards are driving the development of diesel-fuel injection concepts to mitigate in-cylinder formation of particulates. While research has demonstrated significant reduction in particulate formation using micro-orifice technology, implementation requires development of industrial processes to fabricate micro-orifices with diameters as low as 50 μm and with large length-to-diameter ratios. This paper reviews the different processes being pursued to fabricate micro-orifices and the advanced techniques applied to characterize the performance of micro-orifices. The latter include the use of phase-contrast x-ray imaging of electroless nickel-plated micro-orifices and laser imaging of fuel sprays at elevated pressures. The experimental results demonstrate an industrially viable process to create small uniform orifices that improve spray formation for fuel injection.

Misfiring or partial combustion during diesel engine operation results in the production of partial oxidation products such as ethylene (C₂H₄), carbon monoxide and aldehydes, in particular formaldehyde (HCHO). These compounds remain in the cylinder as residual gases to participate in the following engine cycle. Carbon monoxide and formaldehyde have been shown to exhibit a dual nature, retarding ignition in one temperature regime, yet decreasing ignition delay periods of hydrocarbon mixtures as temperatures exceed 1000°K. Largely unknown is the synergistic effects of such species. In this work, varying amounts of C₂H₄ and HCHO are added to the intake air of a naturally aspirated optical diesel engine and their combined effect on autoignition and subsequent combustion is examined. To observe the effect of these dopants on the low-temperature heat release (LTHR), ultraviolet chemiluminescent images are recorded using intensified CCD cameras.

Striving for sustainable transportation solutions, hydrogen is often identified as a promising energy carrier and internal combustion engines are seen as a cost effective consumer of hydrogen to facilitate the development of a large-scale hydrogen infrastructure. Driven by efficiency and emissions targets defined by the U.S. Department of Energy, a research team at Argonne National Laboratory has worked on optimizing a spark-ignited direct injection engine for hydrogen. Using direct injection improves volumetric efficiency and provides the opportunity to properly stratify the fuel-air mixture in-cylinder. Collaborative 3D-CFD and experimental efforts have focused on optimizing the mixture stratification and have demonstrated the potential for high engine efficiency with low NOx emissions. Performance of the hydrogen engine is evaluated in this paper over a speed range from 1000 to 3000 RPM and a load range from 1.7 to 14.3 bar BMEP.

A new fuel injection strategy is proposed for DME engines. Under this strategy, a pre-injection up to 40% demand is conducted after intake valves closing. Due to high volatility of DME, a lean homogeneous mixture can be formed during the compression stroke. Near TDC, a pilot injection is conducted. Combined fuel mass for the pre-injection and pilot injection is under the lean combustion limit of DME. Thus, the mixture is enriched and combustion can take place only in the neighborhood of sprays of the pilot injection. The main injection is conducted after TDC. Because only about half of the demand needs to be injected and DME evaporates almost immediately, combustion duration for the main injection plus the unburnt fuel in the cylinder should not be long because a large portion of the fuel has been premixed with air. With a high EGR rate and proper timing for the main injection, low temperature combustion could be realized.

Due to the single fuel concept implemented by the US military, the soot production of diesel engines fueled with JP-8 has important implications for military vehicle visual signature and survivability. This work compares in-cylinder soot formation and oxidation of JP-8 and ULSD in a small-bore, optical diesel engine. Experimental engine-out soot emission measurements are compared to crank-angle resolved two-color measurements of soot temperature and optical thickness, KL. A 3-D chemical kinetic-coupled CFD model with line of sight integration is employed in order to investigate the soot distribution in a 2-D projection associated with the imaging plane, as well as to aid in interpreting the third dimension along the optical depth which is not available within the experimental work. The study also examines the effect of volatility on soot emission characteristics by CFD simulation.

Mobile source emissions standards are becoming more stringent and particulate emissions from gasoline direct injection (GDI) engines represent a particular challenge. Gasoline particulate filter (GPF) is deemed as one possible technical solution for particulate emissions reduction. In this work, a study was conducted on eight formulations of lubricants to determine their effect on GDI engine particulate emissions and GPF performance. Accelerated ash loading tests were conducted on a 2.4L GDI engine with engine oil injection in gasoline fuel by 2%. The matrix of eight formulations was designed with changing levels of sulfated ash (SASH) level, Zinc dialkyldithiophosphates (ZDDP) level and detergent type. Comprehensive evaluations of particulates included mass, number, size distribution, composition, morphology and soot oxidation properties. GPF performance was assessed through filtration efficiency, back pressure and morphology.

Modeling plume interaction and collapse for direct-injection gasoline sprays is important because of its impact on fuel-air mixing and engine performance. Nevertheless, the aerodynamic interaction between plumes and the complicated two-phase coupling of the evaporating spray has shown to be notoriously difficult to predict. With the availability of high-speed (100 kHz) Particle Image Velocimetry (PIV) experimental data, we compare velocity field predictions between plumes to observe the full temporal evolution leading up to plume merging and complete spray collapse. The target “Spray G” operating conditions of the Engine Combustion Network (ECN) is the focus of the work, including parametric variations in ambient gas temperature. We apply both LES and RANS spray models in different CFD platforms, outlining features of the spray that are most critical to model in order to predict the correct aerodynamics and fuel-air mixing.

The performance of Gasoline Direct Injection (GDI) engines is governed by multiple physical processes such as the internal nozzle flow and the mixing of the liquid stream with the gaseous ambient environment. A detailed knowledge of these processes even for complex injectors is very important for improving the design and performance of combustion engines all the way to pollutant formation and emissions. However, many processes are still not completely understood, which is partly caused by their restricted experimental accessibility. Thus, high-fidelity simulations can be helpful to obtain further understanding of GDI injectors. In this work, advanced simulation and experimental methods are combined in order to study the spray characteristics of two different 3-hole GDI injectors.

The dense spray region in the near-field of diesel fuel injection remains an enigma. This region is difficult to interrogate with light in the visible range and difficult to model due to the rapid interaction between liquid and gas. In particular, modeling strategies that rely on Lagrangian particle tracking of droplets have struggled in this area. To better represent the strong interaction between phases, Eulerian modeling has proven particularly useful. Models built on the concept of surface area density are advantageous where primary and secondary atomization have not yet produced droplets, but rather form more complicated liquid structures. Surface area density, a more general concept than Lagrangian droplets, naturally represents liquid structures, no matter how complex. These surface area density models, however, have not been directly experimentally validated in the past due to the inability of optical methods to elucidate such a quantity.