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Journal Article

A New Constant Dilution Ratio Concept for Vehicle and Engine Exhaust Particle Sampling

2008-04-14
2008-01-0762
This paper presents a new concept of a partial flow sampling system (PFSS), involving a two-stage dilutor which operates at underpressure, while exhaust is sampled through a capillary. The sample flowrate is in the order of few cubic centimeters per minute. Due to the low flowrate, no tight fixation is required between the exhaust line and the capillary inlet. The dilutor may sample from an opening in the exhaust line which freely exhausts to ambient pressure. As a result, the PFSS operates at constant pressure conditions even upstream of diesel particle filters (DPF). A straightforward mathematical model is then developed to calculate the dilution ratio (DR), depending on the dilution air flowrate and the dilutor underpressure. The model is validated using CO2 as a trace gas, and a very good agreement is demonstrated between the calculated and the measured DR values.
Journal Article

Calibration and Validation of a Diesel Oxidation Catalyst Model: from Synthetic Gas Testing to Driving Cycle Applications

2011-04-12
2011-01-1244
To meet future stringent emission regulations such as Euro6, the design and control of diesel exhaust after-treatment systems will become more complex in order to ensure their optimum operation over time. Moreover, because of the strong pressure for CO₂ emissions reduction, the average exhaust temperature is expected to decrease, posing significant challenges on exhaust after-treatment. Diesel Oxidation Catalysts (DOCs) are already widely used to reduce CO and hydrocarbons (HC) from diesel engine emissions. In addition, DOC is also used to control the NO₂/NOx ratio and to generate the exothermic reactions necessary for the thermal regeneration of Diesel Particulate Filter (DPF) and NOx Storage and Reduction catalysts (NSR). The expected temperature decrease of diesel exhaust will adversely affect the CO and unburned hydrocarbons (UHC) conversion efficiency of the catalysts. Therefore, the development cost for the design and control of new DOCs is increasing.
Journal Article

Implications of Engine Start-Stop on After-Treatment Operation

2011-04-12
2011-01-1243
It is commonly accepted that future powertrains will be based to a large extent on hybrid architectures, in order to optimize fuel efficiency and reduce CO₂ emissions. Hybrid operation is typically achieved with frequent engine start-and-stops during real-world as well as during the legislated driving cycles. The cooling of the exhaust system during engine stop may pose problems if the substrate temperature drops below the light-off temperature. Therefore, the design and thermal management of after-treatment systems for hybrid applications should consider the 3-dimensional heat transfer problem carefully. On the other hand, the after-treatment system calculation in the concept design phase is closely linked with engine calibration, taking into account the hybridization strategy. Therefore, there is a strong need to couple engine simulation with 3d aftertreatment predictions.
Technical Paper

Development of Metal Foam Based Aftertreatment System on a Diesel Passenger Car

2008-04-14
2008-01-0619
An alternative metal foam substrate for exhaust aftertreatment applications has been recently presented and characterized. The present paper focuses on the potential of the metal foam technology as an efficient DOC and CDPF substrates on real-world conditions. The target platform is a mid-size passenger car and the methodology includes both modeling and experiments. The experimental testing starts from small-scale reactor characterization of the basic heat/mass transfer properties and chemical kinetics. The results show that the foam structure exhibits excellent mass-transport properties offering possibilities for precious metal and catalyst volume savings for oxidation catalyst applications. These results are also used to calibrate an advanced 2-dimensional model which is able to predict the transient filtration and reaction phenomena in axial and radial flow systems.
Technical Paper

Flow Maldistribution Effects on DPF Performance

2009-04-20
2009-01-1280
This paper focuses on some of the DPF system design issues where 3-dimensional modeling is necessary. The study is based on an existing 3-dimensional DPF model (axitrap) which is coupled to a commercial CFD code (Star-CD, CD-Adapco). The main focus is the effect of the inlet pipe geometry on soot distribution in the filter during loading and regeneration mode. The results show that due to the self-balancing effect, the resulting soot distribution in the filter under typical loading modes with low flow rates is quite uniform. With the assumption of adiabatic inlet pipe, the effect of non-symmetric inlet pipe is also negligible even during regeneration. However, under the realistic assumption of a non-adiabatic inlet pipe, the effect of inlet pipe geometry becomes very significant. Especially, for the case of a bent-shaped inlet pipe, the risk of impartial regeneration of the filter increases significantly.
Technical Paper

Optimization Methodologies for DPF Substrate-catalyst Combinations

2009-04-20
2009-01-0291
As the Diesel Particulate Filter (DPF) technology is nowadays established, research is currently focusing on meeting the emission and durability requirements by proper system design. This paper focuses on the optimum combination between the catalytic coating and substrate structural properties using experimental and simulation methodologies. The application of these methodologies will be illustrated for the case of SiC substrates coated with innovative sol-gel coatings. Coated samples are characterized versus their uncoated counterparts. Multi-dimensional DOC and DPF simulation models are used to study several effects parametrically and increase our understanding on the governing phenomena. The comparative analysis of DOC/DPF systems covers filtration – pressure drop characteristics, CO/HC/NO oxidation performance, effect of washcoat amount and catalyst dispersion on oxidation activity and finally passive regeneration performance.
Technical Paper

A Modeling and Experimental Investigation on an Innovative Substrate for DPF Applications

2010-04-12
2010-01-0891
XP-SiC is an innovative type of a porous substrate material on the basis of a reaction formed SiC for DPF applications. The high porosity, large pore size inside the cell wall and low specific weight are the special characteristics of this substrate. The aim of the current paper is to present an investigation based on the experimental and modeling approaches to evaluate the back pressure, filtration efficiency and the thermal durability. The latter one was assessed by measuring and predicting the temperature field, as well as calculating the thermal stresses. For this purpose the filter was modeled in the commercial computational code axitrap as a stand-alone tool, in which the conservation equations of mass continuity, momentum, energy and species were solved. The soot filtrations, loading as well as the regeneration by fuel-borne catalyst were modeled.
Technical Paper

Modeling and Experimental Study of Uncontrolled Regenerations in SiC Filters with Fuel Borne Catalyst

2004-03-08
2004-01-0697
The objective of this paper is to study the parameters affecting the evolution of “uncontrolled” regeneration in diesel particulate filters with fuel-borne catalyst (FBC) support with emphasis on the development of thermal stresses critical for filter durability. The study is based on experiments performed on engine dynamometer, corresponding to “worst-case” scenario, as well as on advanced, multi-dimensional mathematical modeling. A new 2-dimensional mathematical model is presented which introduces an additional dimension across the soot layer and wall. With this dimension it is possible to take into account the variability of catalyst/soot ratio in the layer and to compute intra-layer composition gradients. The latter are important since they induce interesting O2 diffusion phenomena, which affect the regeneration evolution.
Technical Paper

Reaction and Diffusion Phenomena in Catalyzed Diesel Particulate Filters

2004-03-08
2004-01-0696
The objective of this study is to explain the physical and chemical mechanisms involved in the operation of a catalyzed diesel particulate filter. The study emphasizes on the coupling between reaction and diffusion phenomena (with emphasis on NO2 “back-diffusion”), based on modeling and experimental data obtained on the engine dynamometer. The study is facilitated by a novel multi-dimensional mathematical model able to predict both reaction and diffusion phenomena in the filter channels and through the soot layer and wall. The model is thus able to predict the species concentration gradients in the inlet/outlet channels, in the soot layer and wall, taking into account the effect of NO2 back diffusion. The model is validated versus engine dyno measurements. Two sets of measurements are employed corresponding to low-temperature “controlled” regenerations as well as high-temperature “uncontrolled” conditions.
Technical Paper

Exhaust Particle Sensor for OBD Application

2011-04-12
2011-01-0626
Efforts to develop a sensor for on-board diagnostics (OBD) of diesel vehicles are intensive as diesel particulate filters (DPFs) have become widespread around the world. This study presents a novel sensor that has been successfully tested for OBD diagnosis of damaged DPFs. The sensor is based on the "escaping current" technique. Based on this, a sample of exhaust gas is charged by a corona-ionized flow and is pumped by an ejector dilutor built in the sensor's construction. While the majority of ions return to the grounded sensor's body, a small quantity is lost with the charged particles exiting the sensor. This "escaping current" is a measurement of the particle concentration in the exhaust gas. Such a sensor has been developed and tested in real-exhaust of a diesel car and a diesel engine. The sensor provides high resolution (1 Hz, 0.3 s response time) and high sensitivity superseding OBD requirements. The sensor was used on an engine to monitor the efficiency of damaged DPFs.
Technical Paper

Description of a Novel Concentric Rotary Engine

2018-04-03
2018-01-0365
The present work presents the concept of a new rotary engine, and provides first investigations for its implementation in the energy sector. The main focus of this work is to provide a theoretical description of the engine and its differences from the state-of-the-art technologies. Its innovative principle consists of concentric operation, with two pistons of different rotation radius and the addition of a third intermediate chamber between the compression and combustion chamber. A description of the engine’s physical model is provided, followed by an analysis of the selected specific geometrical features. Additionally, a thermodynamic analysis clarifies the operational advantage compared to the existing cycles and, finally, a numerical investigation on the engine’s bulk performance is provided to quantify the anticipated results of the theoretical analysis.
Technical Paper

Modeling the Interactions Of Soot and SCR Reactions in Advanced DPF Technologies with Non-homogeneous Wall Structure

2012-04-16
2012-01-1298
The pressure for compact and efficient deNO systems has led to increased interest of incorporating SCR coatings in the DPF walls. This technology could be very attractive especially if high amounts of washcoat loadings could be impregnated in the DPF porous walls, which is only possible with high porosity filters. To counterbalance the filtration and backpressure drawbacks from such high porosity applications, the layered wall technology has already been proposed towards minimizing soot penetration in the wall and maximizing filtration efficiency. In order to deal with the understanding of the complex interactions in such advanced systems and assist their design optimization, this paper presents an advanced modeling framework and selected results from simulation studies trying to illustrate the governing phenomena affecting deNO performance and passive DPF regeneration in the above combined systems.
Technical Paper

SCR System Optimization and Control Supported by Simulation Tools

2013-04-08
2013-01-1075
The successful design and especially the control of the SCR system is a challenging process that can be supported by the application of simulation tools. As a first step, we employ physico-chemically informed ‘off-line’ models that are calibrated with the help of targeted small- and full-scale tests. Despite their high level of sophistication, this SCR model is able to be integrated in a control-oriented simulation software platform and connected to other powertrain simulation blocks. The target is to use this simulation platform as a virtual environment for the development and optimization of SCR control strategies. The above process is demonstrated in the case of a passenger car SCR. The model is calibrated at both fresh and aged catalyst condition and validated using experimental data from the engine bench under a wide variety of operating conditions. Next, the calibrated model was coupled with embedded control models, developed for Euro 6 passenger car powertrains.
Technical Paper

Filtration and Regeneration Performance of a Catalyzed Metal Foam Particulate Filter

2006-04-03
2006-01-1524
The objective of this study is to present a particulate filter concept, based on a new porous material: INCOFOAM® HighTemp, a Ni-based superalloy foam. The paper examines the filtration and pressure drop characteristics as well as the regeneration performance of different filter configurations, based on experimental data and modeling. A number of different foam structures with variable pore characteristics are studied. The experimental testing covers flow and pressure drop behavior with air and exhaust gas, filtration efficiency measurements as function of particle size and regeneration rate measurements. The testing starts from mini-scale reactors and proceeds to real exhaust testing on the engine bench as well as vehicle tests on the chassis dynamometer and on-road. In parallel, a previously developed mathematical model is applied to study and understand the filtration and pressure drop mechanisms in the case of clean and soot loaded filters.
Technical Paper

Diesel Particle Exhaust Emissions from Light Duty Vehiclesand Heavy Duty Engines

2006-04-03
2006-01-0866
Diesel engines are widespread in both passenger car and heavy duty truck applications. However, despite that the combustion concepts are similar in the two cases, the engine calibration required for compliance with the different emission standards leads to distinct particle emission behavior from the two categories. This paper compares the exhaust particle emissions from heavy duty engines with typical diesel passenger cars of similar emission standard and/or emission control technology. Measurements were conducted with the same sampling system and sampling protocol to avoid interferences induced by the sampling methodology. A range of particle properties were studied, including mass, number of solid and total particles and total particle surface. For comparability, the results are expressed per unit of exhaust volume, per unit of fuel consumed and per unit of distance driven.
Technical Paper

Development and Experimental Validation of a NOx Trap Model for Diesel Exhaust

2006-04-03
2006-01-0471
This paper presents a mathematical model for the simulation of NOx traps during the storage and the regeneration phases. The objective is to validate the model under realistic exhaust gas conditions during NOx storage and release phases. The model is based on a previous modeling platform developed by Aristotle University which simulates the behavior of 3-way catalysts. The previous model is extended to include the additional reactions taking place on a NOx trap, with particular emphasis on the calculation of thermodynamic equilibrium effects. Moreover, the model includes the necessary reactions to simulate catalyst sulfation and de-sulfation processes. In parallel, a set of measurements are conducted under well controlled conditions with real diesel exhaust to study the storage and release phenomena under various operating conditions. The experimental data are used to calibrate the reaction kinetics and validate the model.
Technical Paper

3-Dimensional Modeling of the Regeneration in SiC Particulate Filters

2005-04-11
2005-01-0953
In order to use modeling as a predictive tool for real-world particulate filter designs (segmented filters, non-axisymmetric designs), it is necessary to develop reliable 3-dimensional models. This paper presents a 3 d modeling approach, which is validated against engine-bench measurements with both FBC and CDPF systems. Special emphasis is given to the prediction of the transient inlet flow distribution, which is realized without resorting to external CFD software. The experimental and modeling results illustrate the 3-d nature of the problem, induced by the heat capacity and conductivity effects of the cement layers. It is possible to predict the localization of regeneration in certain areas of the filter (partial regeneration), as a result of poor heat transfer to thermally isolated regions in the filter. The accuracy of the model was validated by extensive comparisons with temperature measurements in 30 positions inside the filters and at various operating conditions.
Technical Paper

Performance of Catalyzed Particulate Filters without Upstream Oxidation Catalyst

2005-04-11
2005-01-0952
The possibility to employ a single-brick system with a catalyzed filter (CDPF) for the after-treatment of diesel engines is potentially a promising and cost-effective solution. In the first part of this paper, the effectiveness of a single brick CDPF system towards reducing the gaseous CO and HC emissions is investigated experimentally and computationally. The second part of the paper deals with the behavior of single brick catalyzed filters compared with two brick systems comprising an upstream oxidation catalyst. The main differences of the two systems are highlighted in terms of regeneration efficiency and thermal loading, based on simulation results. The modeling work is based on a 3-dimensional model of the catalyzed filter and an axi-symmetric model of the oxidation catalyst. Model validations are presented based on engine bench testing.
Technical Paper

A Model Based Definition of a Reference CO2 Emissions Value for Passenger Cars under Real World Conditions

2018-05-30
2018-37-0031
With the adoption of the Worldwide harmonized Light Vehicles Test Procedure (WLTP) and the Real Driving Emissions (RDE) regulations for testing and monitoring the vehicle pollutant emissions, as well as CO2 and fuel consumption, the gap between real world and type approval performances is expected to decrease to a large extent. With respect to CO2, however, WLTP is not expected to fully eliminate the reported 40% discrepancy between real world and type approval values. This is mainly attributed to the fact that laboratory tests take place under average controlled conditions that do not fully replicate the environmental and traffic conditions experienced over daily driving across Europe. In addition, any uncertainties of a pre-defined test protocol and the vehicle operation can be optimized to lower the CO2 emissions of the type approval test. Such issues can be minimized in principle with the adoption of a real-world test for fuel consumption.
Technical Paper

Development of a Template Model and Simulation Approach for Quantifying the Effect of WLTP Introduction on Light Duty Vehicle CO2 Emissions and Fuel Consumption

2015-09-06
2015-24-2391
The paper describes the development of a modelling approach to simulate the effect of the new Worldwide harmonized Light duty Test Procedure (WLTP) on the certified CO2 emissions of light duty vehicles. The European fleet has been divided into a number of segments based on specific vehicle characteristics and technologies. Representative vehicles for each segment were selected. A test protocol has been developed in order to generate the necessary data for the validation of the vehicle simulation models. In order to minimize the sources of uncertainty and the effects of flexibilities, a reference “template model” was developed to be used in the study. Subsequently, vehicle models were developed using AVL Cruise simulation software based on the above mentioned template model. The various components and sub-modules of the models, as well as their input parameters, have been defined with the support of the respective OEMs.
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