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The influence of oil related emissions became more important in the past due to reduced engine-out emissions of combustion engines. Additionally the efficiency of exhaust gas after treatment components is influenced by oil derived components. A balancing of relevant engine oil components (Ca, Mg, Zn, P, S, Mo, B, Fe, Al, Cu) is presented in this paper. The oil components deposited in the combustion chamber, in the exhaust system as well as in the aftertreatment devices were determined and quantified. Therefore a completely cleaned DI Diesel engine with oxidation catalyst, Diesel particulate filter (DPF) and NOx adsorber catalyst (LNT) was operated in different operating conditions for 500 h in a development test cell. The operation included lean/rich cycling for NOx trap regeneration. After finishing the 500 h test procedure the engine was completely disassembled and all deposits were analyzed.

The development and validation of detailed simulation models of in-cylinder combustion, emission formation mechanisms and reaction kinetics in the exhaust system are of crucial importance for the design of future low-emission powertrain concepts. To investigate emission formation mechanisms on one side and to create a solid basis for the validation of simulation methodologies (e.g. 3D-CFD, multi-dimensional in-cylinder models, etc.) on the other side, specific detailed measurements in the exhaust system are required. In particular, the hydrocarbon (HC) emissions are difficult to be investigated in simulation and experimentally, due to their complex composition and their post-oxidation in the exhaust system. In this work, different emission measurement devices were used to track the emission level and composition at different distances from the cylinder along the exhaust manifold, from the exhaust valve onwards.