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Auto-ignition and combustion processes of dual-component fuel spray were numerically studied. A source code of SUPERTRAPP (developed by NIST), which is capable of predicting thermodynamic and transportation properties of pure fluids and fluid mixtures containing up to 20 components, was incorporated into KIVA3V to provide physical fuel properties and vapor-liquid equilibrium calculations. Low temperature oxidation reaction, which is of importance in ignition process of hydrocarbon fuels, as well as negative temperature coefficient behavior was taken into account using the multistep kinetics ignition prediction based on Shell model, while a global single-step mechanism was employed to account for high temperature oxidation reaction. Computational results with the present multi-component fuel model were validated by comparing with experimental data of spray combustion obtained in a constant volume vessel.

The authors have explored the potential of fuel to control spray and its combustion processes in a diesel engine. Fuel has some potential for low emission and high thermal efficiency because its volatility and ignitability are one of the ultimate performing factors of the engines. In present study, the ignition process of mixed fuel spray was investigated in a constant volume combustion vessel and in a rapid compression and expansion machine, The ignition delay based on the diagram of rate of the heat release, the imaging of natural flame emissions and the numerical simulation were carried out to clarify the effect of the physical and chemical properties of mixed fuel on ignition characteristics.

The Flame structure and combustion characteristics for two waste-cooking oils were investigated in detail. One fuel is the waste-cooking oil methyl esters. This fuel is actually applied to the garbage collection vehicle with DI diesel engine (B100) and the city bus (B20; 80% gas oil is mixed into B100 in volume) as an alternative fuel of gas oil in Kyoto City. Another one is the fuel with ozone treatment by removing impurities from raw waste-cooking oils. Here, in order to improve the fuel properties, kerosene is mixed 70% volume in this fuel. This mixed fuel (i-BDF) is applied into several tracks and buses in Wakayama City. In the experiments, the used fuels were gas oil, i-BDF, B100 and B20. Spray characteristics and basic combustion properties were measured inside a rapid compression and an expansion machine (RCEM).

The maximum liquid-phase penetration and vaporization behavior was investigated by using simultaneous measurement for mie-scattered light images and shadowgraph ones. The objective of this study was to analyze effect of variant parameters (injection pressure, ambient gas condition and fuel temperature) and fuel properties on vaporization behavior, and to investigate liquid phase penetration for the single- and multi-component fuels. The experiments were conducted in a constant-volume vessel with optical access. Fuel was injected into the vessel with electronically controlled common rail injector.

This work investigates the soot formation process in diesel jet flame using a detailed kinetic soot model implemented into the KIVA-3V multidimensional CFD code and 2D imaging by use of time-resolved laser induced incandescence (LII). The numerical model is based on the KIVA code which is modified to use CHEMKIN as the chemistry solver using Message Passing Interface (MPI). This allows for the chemical reactions to be simulated in parallel on multiple CPUs. The detailed soot model used is based on the method of moments, which begins with fuel pyrolysis, followed by the formation of polycyclic aromatic hydrocarbons, their growth and coagulation into spherical particles, and finally, surface growth and oxidation of the particles. The model can describe the spatial and temporal characteristics of soot formation processes such as soot precursors distributions, nucleation rate and surface reaction rate.

This paper confirms a structure for the soot formation process inside a burning diesel jet plume of oxygenated fuels. An explanation of how the soot formation process changes by the use of oxygenated fuel in comparison with that for using a conventional diesel fuel, and why oxygenated fuel drastically suppresses the soot formation has been derived from the chemical kinetic analysis. A detailed chemical kinetic mechanism, which is combined with various proposed chemical kinetic models including normal paraffinic hydrocarbon oxidation, oxygenated hydrocarbon oxidation, and poly-aromatic hydrocarbon (PAH) formation, was developed in present study. The calculated results are presented to elucidate the influence of fuel mixture composition and fuel structure, especially relating to oxygenated fuels, on PAH formation. The analysis also provides a new insight into the initial soot formation process in terms of the temperature range of PAH formation.

Large Eddy Simulation (LES) is applied to non-evaporative and evaporative diesel spray simulations. KIVALES, which is LES version of KIVA code, is used as the LES computational code. Modified TAB model is used as breakup model, and interpolated donor cell differencing scheme is employed to calculate convective terms. To validity LES simulation, LES results using KIVALES are compared with experimental results and simulated results with conventional RANS approach using KIVA3V res.2. The results show that the LES simulation of non-evaporative spray depends on the grid size in comparison with RANS simulation, and good agreement is obtained between experimental results and the LES results with fine grid (720,000 cells). Furthermore, asymmetric non-evaporative spray which has intermittency at the outer edge of sprays is simulated, since instantaneous turbulent flow field can be predicted directly in LES case.

This paper deals with the particle distribution in Diesel spray under the non-evaporating condition from the analytical aspect based on our experimental results. In the analysis, TAB method of KIVA II code and the k-ε turbulent model were used, and the mono-disperse distribution of the initial parcel's diameter, whose size equals to the nozzle hole diameter, was utilized in conjunction with the breakup model. The size distribution of atomized droplets (i.e. the χ-squared distribution function) is justified with the degree of freedom. It is shown that the ambient gas, which is initially quiescent, is induced and led to a turbulent gas jet. The turbulent gas jet which has a equivalent momentum with the Diesel spray was also examined by Discrete Vortex method. The quantitative jet growth was shown to be possible for the estimation and determination in its initial boundary values at the nozzle.

In SI engines with port injection system, the injected fuel spray adheres surely on the port wall and the inlet valve, consequently, the spray-wall interaction process leads to the generation of unburned hydrocarbons and uncontrollable mixture formation. This paper deals with the fuel mixture preparation process including basic research on characteristics of the wall-wetted fuel film on a flat wall inside a constant volume vessel. In the experiments, iso-octane mixed with biacetyl as a tracer dopant was injected through a pintle type injector against a flat glass wall under the ambient conditions of atmospheric pressure and room temperature. The thickness of the adhered fuel film on the wall was quantitatively measured by using laser induced fluorescence (LIF) technique, which provides 2-D distribution information with high special resolution as a function of the injection duration, the impingement distance from the injector to the wall, and the impingement angle against the wall.