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The focus of this paper is to understand, from experimental data, the R134a refrigerant emission rates of various hose materials due to permeation. This paper focuses on four main points for hose assembly emission of R134a: (1) characteristics of hose permeation in response to the effect of oil in R134a and the characteristics of hose permeation of vapor vs. liquid refrigerant; (2) conditioning of the hose material over time to reach steady state R134a emission; (3) the relative contribution of hose permeation and coupling emission to the overall hose assembly refrigerant emission; (4) transient emission rates due to transient temperature and pressure conditions. Studies include hoses with different materials and constructions resulting in various levels of R134a permeation.

As automotive power-train systems become more efficient, less waste heat is available for vehicle passenger cabin warming. As a result, alternative heating technologies are being investigated to alleviate this shortcoming. One alternative is to operate the existing A/C system in reverse (heat pump mode), thus providing supplemental heat. Recently, the environmental impact of refrigerant emissions has come under global scrutiny. The concern is their potential for global warming. Thus, the environmental characteristic of merit that makes for a more benign refrigerant in terms of emissions is lower Global Warming Potential (GWP). R-152a is a more environmentally benign refrigerant compared to R-134a with a GWP of 120 vs. 1,300 [1] and [2]. Both refrigerants are hydro-fluorocarbons - HFCs - (contain no chlorine) and hence, have zero ozone depletion potential. An environmentally benign refrigerant touted as a potential replacement for R-134a, is CO2.