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Increasing concerns due to global warming have led to stringent regulation of greenhouse gas (GHG) emissions from diesel engines. Specifically, for GHG phase-2 regulation (2027), more than 4% improvement is needed when compared to phase-1 regulation (2017) in the light heavy-duty (LHD) diesel engine category. At the same time, California Air Resources Board (CARB) and Environmental Protection Agency (EPA) have proposed the new Low NOx standards that require up to 90% reduction in tailpipe (TP) NOx emissions in comparison to the current TP NOx standards that were implemented in 2010. In addition, CARB and EPA have proposed new certification requirements – Low Load Cycle (LLC) and revised heavy-duty in-use testing (HDIUT) based on the moving average window (MAW) method that would require rigorous thermal management. Hence, strategies for simultaneous reduction in GHG and TP NOx emissions are required to meet future regulations.

Various techniques are constantly being devised to accelerate model generation leading to shorter product development cycle. This work proposes and implements a reduced synthetic gas bench (SGB) test protocol for a commercial Pt-Pd diesel oxidation catalyst (DOC) that can be used to develop global reaction kinetics. The kinetics thus developed were implemented in a 1D model to predict DOC emissions accurately over a wide operating window. Hydrocarbons (HCs) in the exhaust were categorized as Propylene (C3H6) representing partially oxidized hydrocarbons and n-Decane (C10H22) representing unburnt fuel. Test protocols were defined using the order of inhibition of the various species present in the exhaust, namely, CO, NOx (NO+NO2) and HC for the specific reaction under consideration. The oxidation reactions for CO and HCs were found to be inhibited competitively by CO and HCs; both the NOx species inhibited these reactions to the same extent.