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The pretreatment of aluminum sheet material in preparation for further paint application can be challenging due to the presence of a thick oxide layer. The composition of the oxide layer is primarily aluminum oxide, but it may also contain magnesium that is typically dispersed unevenly throughout the oxide layer. Zinc-phosphate systems remove much of the oxide layer on aluminum, but questions remain on the extent of removal of the oxide layer by zirconium oxide-based pretreatments and how these oxide layers may affect the zirconium oxide-based pretreatment deposition on aluminum. Several methods have been used to characterize the coating of zirconium oxide-based pretreatments on aluminum. Scanning electron microscopy at very high magnification reveals a coating on aluminum that is significantly different in morphology than the same coating chemistry on steel substrates.

This study reports the corrosion performance of three different coating strategies tested on an AE44 high performance magnesium strut tower brace used on the 2020 Ford Mustang Shelby GT500. The alloy was selected due to its improved structural performance at higher temperatures over conventional AM60B magnesium die castings. The first coating strategy used no pretreatment, conversion coating, or topcoat to gage the baseline corrosion performance of the uncoated alloy. The second coating strategy used a conventional pretreatment commonly used on AM60B alloy. The third used a ceramic-based conversion coating. A textured (stipple) powder coat was then applied to the two non-baseline parts over the pretreatment. All three coating strategies were then evaluated by comparing the corrosion performance after cyclic corrosion testing for 12 weeks using the Ford L-467 test.