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For real working-process simulations it is essential to know the caloric properties of the working fluid, such as the specific enthalpy and the real gas constant. When using standard-fuels there are established models which describe the caloric variables as functions of temperature, air/fuel-ratio and pressure. In each case, these models were developed for a certain fuel composition and their application to alternative fuels is limited or not valid at all. Thus, an approach is discussed, which is valid for any user-defined fuel. This work presents the formulations for the caloric modelling of burnt gas and fuel vapor, respectively. An algorithm is introduced that provides a very fast calculation of the chemical equilibrium condition of burnt gas. The influence of the equilibrium coefficients and the fuel composition on the chemical equilibrium composition is discussed.