Search Results

Hydrogen crossover and membrane hydration are significant issues for polymer electrolyte fuel cells (PEFC). Hydrogen crossover amounts to a quantity of unspent fuel, thereby reducing the fuel efficiency of the cell, but more significantly it also gives rise to the formation of hydrogen peroxide in the cathode catalyst layer which acts to irreversibly degenerate the polymer electrolyte. Membrane hydration not only strongly governs the performance of the cell, most noticeable through its effect on the ionic conductivity of the membrane, it also influences the onset and propagation of internal degradation and failure mechanisms that curtail the reliability and safety of PEFCs. This paper focuses on how hydrogen crossover and membrane hydration are affected by; (a) characteristic cell geometries, and (b) operating conditions relevant to automotive fuel cells.

Valve timing strategies aimed at producing internal exhaust gas re-circulation in a conventional spark ignition, SI, engine have recently demonstrated the ability to initiate controlled auto-ignition, CAI. Essentially the exhaust valves close early, to trap a quantity of hot exhaust gases in-cylinder, and the fresh air-fuel charge is induced late into the cylinder and then mixing takes place. As a logical first step to understanding the fluid mechanics, the effects of the standard and modified valve timings on the in-cylinder flow fields under motored conditions were investigated. Laser Doppler anemometry has been applied to an optical engine that replicates the engine geometry and different valve cam timings. The cycle averaged time history mean and RMS velocity profiles for the axial and radial velocity components in three axial planes were measured throughout the inlet and compression stroke.

Extensive research has been performed for on-board hydrogen generation, such as pyrolysis of metal hydrides (e.g., LiH, MgH₂), hydrogen storages in adsorption materials (e.g., carbon nanotubes and graphites), compressed hydrogen tanks and the hydrolysis of chemical hydrides. Among these methods, the hydrolysis of NaBH₄ has attracted great attention due to the high stability of its alkaline solution and the relatively high energy density, with further advantages such as moderate temperature range (from -5°C to 100°C) requirement, non-flammable, no side reactions or other volatile products, high purity H₂ output. The H₂ energy density contained by the system is fully depend on the solubility of the complicated solution contains reactant, product and the solution stabilizer. In this work, an approach based on thermodynamic equilibrium was proposed to model the relationship between the solubility of an electrolyte and temperature, and the effect of another component on its solubility.

The control of Homogeneous Charge Compression Ignition (HCCI) (also known as Controlled Auto Ignition (CAI)) has been a major research topic recently, since this type of combustion has the potential to be highly efficient and to produce low NOx and particulate matter emissions. Ion current has proven itself as a closed loop control feedback for SI engines. Based on previous work by the authors, ion current was acquired through HCCI operation too, with promising results. However, for best utilization of this feedback signal, advanced interpretation techniques such as artificial neural networks can be used. In this paper the use of these advanced techniques on experimental data is explored and discussed. The experiments are performed on a single cylinder cam-less (equipped with a Fully Variable Valve Timing (FVVT) system) research engine fueled with commercially available gasoline (95 ON).

Closed-loop electronic control is a proven and efficient way to optimize spark ignition engine performance and to control pollutant emissions. In-cylinder pressure sensors provide accurate information on the quality of combustion. The conductivity of combustion flames can alternatively be used as a measure of combustion quality through ion-current measurements. In this paper, combustion diagnostics through ion-current sensing are studied. A single cylinder research engine was used to investigate the effects of misfire, ignition timing, air to fuel ratio, compression ratio, speed and load on the ion-current signal. The ion-current signal was obtained via one, or both, of two additional, remote in-cylinder ion sensors (rather than by via the firing spark plug, as is usually the case). The ion-current signals obtained from a single remote sensor, and then the two remote sensors are compared.