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Most of the new Diesel combustion concepts are mainly based on reducing local combustion temperatures and enhancing the fuel/air mixing with the aim of simultaneously reducing soot and NOx emissions. In this framework, Premixed Charge Compression Ignition (PCCI) has revealed as one of the best options to combine both low emissions and good combustion controllability. During last years, PCCI strategy has been widely explored using high EGR levels and different early or late injection timings to extend the ignition delay. Recently, the use of lower cetane fuels is under investigation. Despite the great quantity of research work performed, there are still some aspects related to PCCI combustion that are not completely well known. In this paper an experimental and numerical study is carried out focused on understanding the mixing and auto-ignition processes in PCCI combustion conditions using Diesel and Gasoline fuels.

Methanol is currently being evaluated as a promising alternative fuel for internal combustion engines, due to being attainable by carbon neutral or negative pathways (renewable energy and carbon capture technology). The low ignitability of methanol has made it attractive mostly as a fuel for spark ignition engines, however the low sooting properties of the fuel could potentially reduce the NOx-soot tradeoff present in compression ignition engines. In this work, using a 4-cylinder engine with compression ratio modified from 16:1 to 19:1, methanol combustion is evaluated under five operating conditions in terms of fuel consumption, criteria pollutants, CO2 emissions and engine efficiency in addition to the qualitative assessment of the combustion stability. It was found that combustion is stable at medium to high loads, with medium load NOx emissions levels at least 30% lower than the original diesel engine and comparable emissions at maximum load conditions.

De-fossilization is an increasingly important trend in the energy sector. In the transport sector the de-fossilization efforts have been centered in promoting the electrification of vehicles, nonetheless other pathways, like the use of carbon neutral or carbon-offsetting fuels under current vehicle fleets, are also worth considering. Low-carbon fuels (LCF) can be synthetized from sources that can take advantage of the carbon already present in the atmosphere (either by technologies like direct carbon capture or biological processes like photosynthesis in biofuels) and use energy from renewable sources for the necessary industrial processes. Although, LCFs can be compared to fossil fuels as energy sources for internal combustion engines, their composition is not the same and their properties can modify the engine combustion and emissions.