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The Selective Catalytic Reduction (SCR) is a promising approach to meet future legislation regarding the nitric oxide emissions of diesel engines. In automotive applications a liquid urea-water solution (UWS) is injected into the hot exhaust gas. It evaporates and decomposes to ammonia vapor acting as the reducing agent. Significant criteria for an efficient SCR system are a fast mixture preparation of the UWS and a high ammonia uniformity at the SCR catalyst. Multiphase CFD simulation is capable to support the development of this process. However, major challenges are the correct description of the liquid phase behavior and the simulation of the ammonia vapor mixing in the turbulent exhaust gas upstream of the SCR catalyst. This paper presents a systematic study of the impact of the turbulence model and the numerical spatial discretization scheme on the prediction of the turbulent mixing process of the gaseous ammonia.

Long-term reliability is one of the major requirements for the operation of automotive exhaust aftertreatment systems based on selective catalytic reduction (SCR). For an efficient reduction of nitrogen oxides in the SCR catalyst it is desirable that the thermolysis of the injected urea water solution (UWS) is completed within the mixing section of the exhaust system. Urea might undergo a number of secondary reactions leading to the formation of solid deposits on system walls. A deeper understanding of the mechanisms and influence factors is a basic requirement to prevent and predict undesired decomposition products. This paper outlines the mechanisms of UWS transport and deposition on a typical mixing element geometry. The conditions leading to deposit formation were investigated based on optical and temperature measurements in a box with optical access. A good correlation with the deposit location observed at the close-to-series exhaust system was found.

This study presents a methodology to predict particle number (PN) generation on a naturally aspirated 4-cylinder gasoline engine with port fuel injection (PFI) from wall wetting, employing numerical CFD simulation and fuel film analysis. Various engine parameters concerning spray pattern, injection timing, intake valve timing, as well as engine load/speed were varied and their impact on wall film and PN was evaluated. The engine, which was driven at wide open throttle (WOT), was equipped with soot particle sampling technology and optical access to the combustion chamber of cylinder 1 in order to visualise non-premixed combustion. High-speed imaging revealed a notable presence of diffusion flames, which were typically initiated between the valve seats and cylinder head. Their size was found to match qualitatively with particulate number measurements. A validated CFD model was employed to simulate spray propagation, film transport and droplet impingement.

Current commercial vehicles' engines are complex systems with multiple degrees of freedom. In conjunction with current emissions regulations manufacturers are forced to combine highly developed engines with complex aftertreatment systems. A comprehensive simulation model including the engine and aftertreatment system has been set up in order to study and optimize the overall system. The model uses a phenomenological spray combustion model to predict fuel consumption and NO emissions. In addition physical models for the material temperatures and the reaction kinetics were generated for the aftertreatment system. Steady state and transient measurements were used to calibrate the engine as well as the aftertreatment model. The aim for a system-level optimization was a reduction of fuel consumption while meeting emission standards.

In exhaust systems with selective catalytic reduction (SCR) a fast conversion of liquid urea to gaseous ammonia and a uniform distribution of the ammonia vapor upstream of the SCR catalyst are essential to reduce the nitric oxides efficiently. For the prediction of the mixing process and the transport of ammonia vapor with the CFD method an accurate description of the turbulent flow field is a basic requirement. This paper presents the comparison of simulation results using three different turbulence models (high-Re kε-RNG model, low-Re kω-SST model, Reynolds stress model) with measurements of the turbulent velocity field using Laser Doppler Anemometry (LDA). The investigations were carried out for a SCR system with a swirl mixer on a cold flow test bench for two different volume flows. From the measured velocity signals different components of the Reynolds-tensor were derived.

As a consequence of the global warming, more strict maritime emission regulations are globally in force or will become applicable in the near future (e.g. NOX and SOX emission control areas). The tough competition puts economic pressure on the maritime transport industry. Therefore, the demand for efficient and mostly environmental neutral propulsion systems that meet the environmental legislations and minimize the cargo costs are immense. Medium speed dual fuel engines are in accordance with the strict maritime emissions legislation IMO Tier III. They do not require any exhaust gas aftertreatment, are economically competitive, and allow fuel flexibility. These engines deliver the highest efficiency in high load operation. A valuable approach to improve the efficiency and reduce the environmental impact in low and part load is represented by the electronic cylinder cut-out. Thereby, the natural gas admission is deactivated and the valves are kept activated.

The introduction of the so called Emission Controlled Areas within the IMO Tier III legislation forces manufacturers of maritime propulsion systems to adherence to stringent emission thresholds. Dual fuel combustion, which is characterized by the injection of a small amount of fuel oil to ignite a premixed natural gas air mixture, constitutes an option to meet this target. At high diesel substitution rates and very short pilot injection events, the injector is operated in the ballistic regime. This influences spray penetration, mixture formation and ignition behavior. In the present work, a seven-hole dual fuel injector was measured in a combustion chamber to provide data for the generation of a CFD model using the commercial code AVL FIRE®. The liquid and the vapor phase of the fuel spray were quantified by Mie-scattering and Schlieren-imaging technique for different chamber conditions.

The combustion efficiency of large gas engines is limited by knocking combustion. Due to fact that the quality of the fuel gas has a high impact on the self-ignition of the mixture, it is the aim of this work to model the knocking combustion for fuel gases with different composition using detailed chemistry. A cycle-resolved knock simulation of the fast burning cycles was carried out in order to assume realistic temperatures and pressures in the unburned mixture Therefore, an empirical model that predicts the cyclic variations on the basis of turbulent and chemical time scales was derived from measured burn rates and implemented in a 1D simulation model. Based on the simulation of the fast burning engine cycles the self-ignition process of the unburned zone was calculated with a stochastic reactor model and correlated to measurements from the engines test bench. A good agreement of the knock onset could be achieved with this approach.

One promising application in the emission control is the Selective Catalytic Reduction (SCR) system for the reduction of nitric oxides from exhaust emissions. Previous works at the institute have highlighted the importance of accurate CFD turbulence modeling with respect to the turbulent mixing of ammonia vapor [1]. With the help of Laser Doppler Anemometry (LDA) measurements it was confirmed that RANS approaches are capable of predicting the velocity field adequately. In contrast, the turbulence level was underestimated for all RANS approaches [2]. Based on this work the paper at hand presents CFD results using Large Eddy Simulation (LES). The sensitivity of the solution with respect to spatial and temporal resolution as well as the boundary conditions is demonstrated. In accordance with the Kolmogorov theory grid sizes ranging from 3.2 to 20 million cells were investigated using LES methodology.

The permanently tightening emission regulations for nitrogen oxides (NOx) pollutants force further development of mobile exhaust aftertreatment systems with selective catalytic reduction (SCR). Of particular interest is the long-term reliability of SCR-systems with regard to unfavorable operating conditions, such as high injection rates of urea water solution (UWS) or low exhaust gas temperatures. Both may lead to the formation of solid deposits which decrease system efficiency by increasing backpressure and impairing ammonia formation. In order to study the most relevant processes of deposit formation, an optical box with heat resistant glass was designed. Three UWS injectors with different spray characteristics were used to study their influence on the deposit formation under a wide range of stationary and transient operating conditions. Infrared thermography was applied to observe spray-induced wall cooling, both below and above the Leidenfrost point.