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Pre-chamber ignition systems are considered as an effective technique to achieve an ultra-lean burn combustion. Hot combustion products and flames generated from pre-chamber combustion create high-speed turbulent jets, which ignite an ultra-lean mixture in the main chamber. This turbulent ignition can be classified as a jet and flame ignition process with thermal and chemical kinetic effects imposed on the main chamber by the pre-chamber. The purpose of this paper is to investigate the chemical effects of pre-chamber combustion products on main chamber ignition performance over a range of operating conditions in pre-chamber. A zero-dimensional pre-chamber combustion model was developed using CHEMKIN-PRO software. By varying the equivalence ratio of reactants, simulation results indicated that the pre-chamber generated more active radicals when burning around stoichiometric conditions but more low-carbon species when burning in rich conditions.

Over the years, spark-ignition engine operation has changed significantly, driven by many factors including changes in operating conditions. The variation in operating conditions impacts the state of the end-gas, and therefore, its auto-ignition. This can be quantified in terms of K-factor, which weighs the relative contribution of Research Octane Number (RON) and Motor Octane Number (MON) to knocking tendency at any operating condition. The current study investigates the fuel requirements when operating an engine at increasing intake air pressures. A model engine was operated at varying intake air pressure in GT-Power software, from naturally aspirated intake air to heavily boosted intake air pressure of 4 bar absolute. The pressure-temperature information from the GT-Power model was used to calculate ignition delay times of the unburnt end-gas composed of a sensitive and a non-sensitive fuel in ChemKin software.

The US Department of Energy has formulated different gasoline fuels called ''Fuels for Advanced Combustion Engines (FACE)'' to standardize their compositions. FACE I is a low octane number gasoline fuel with research octane number (RON) of approximately 70. The detailed hydrocarbon analysis (DHA) of FACE I shows that it contains 33 components. This large number of components cannot be handled in fuel spray simulation where thousands of droplets are directly injected in combustion chamber. These droplets are to be heated, broken-up, collided and evaporated simultaneously. Heating and evaporation of single droplet FACE I fuel was investigated. The heating and evaporation model accounts for the effects of finite thermal conductivity, finite liquid diffusivity and recirculation inside the droplet, referred to as the effective thermal conductivity/effective diffusivity (ETC/ED) model.

Numerical simulations were conducted to systematically assess the effects of different spray models on the ignition delay predictions and compared with experimental measurements obtained at the KAUST ignition quality tester (IQT) facility. The influence of physical properties and chemical kinetics over the ignition delay time is also investigated. The IQT experiments provided the pressure traces as the main observables, which are not sufficient to obtain a detailed understanding of physical (breakup, evaporation) and chemical (reactivity) processes associated with auto-ignition. A three-dimensional computational fluid dynamics (CFD) code, CONVERGE™, was used to capture the detailed fluid/spray dynamics and chemical characteristics within the IQT configuration. The Reynolds-averaged Navier-Stokes (RANS) turbulence with multi-zone chemistry sub-models was adopted with a reduced chemical kinetic mechanism for n-heptane and iso-octane.

Investigating combustion characteristics of oxygenated gasoline and gasoline blended ethanol is a subject of recent interest. The non-linearity in the interaction of fuel components in the oxygenated gasoline can be studied by developing chemical kinetics of relevant surrogate of fewer components. This work proposes a new reduced four-component (isooctane, heptane, toluene, and ethanol) oxygenated gasoline surrogate mechanism consisting of 67 species and 325 reactions, applicable for dynamic CFD applications in engine combustion and sprays. The model introduces the addition of eight C1-C3 species into the previous model (Li et al; 2019) followed by extensive tuning of reaction rate constants of C7 - C8 chemistry. The current mechanism delivers excellent prediction capabilities in comprehensive combustion applications with an improved performance in lean conditions.

Designing advanced combustion engines requires a better understanding of the physical and chemical processes occurring during spray combustion. In this study, the ignition characteristics of conventional diesel and palm biodiesel fuels were simulated using the two-stage Lagrangian (TSL) simulation, a zero dimensional (0-D) modeling technique. For the diesel fuel surrogate, a detailed chemical kinetic model for n-heptane from LLNL (Lawrence Livermore National Laboratory), with 550 chemical species and 2450 elementary reactions was utilized. For the palm biodiesel, detailed mechanism (4800 species and 2450 elementary reactions) for the 5 basic biodiesel components; methyl palmitate, methyl stearate, methyl oleate, methyl linoleate and methyl linolenate was used. Also, simulations were performed using a reduced mechanism (115 species and 460 reactions) for surrogates of palm oil biodiesel comprising mixtures of methyl decanoate, methyl decenoate and n-heptane.