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Depleting fossil-fuels and increasing harmful emissions by the combustion of fossil fuels in IC engine is a matter of great concern. It is necessary to explore solutions complying with the prevailing emission norms in different sectors. Methanol has the potential amongst all primary alcohols for widespread use in transport sector due to its clean-burning, high octane rating, sources of production like high ash coal, and biomass. The addition of methanol to gasoline can significantly reduce engine-out emissions. Gasoline-Methanol blends (Gasohols) can be used to reduce dependence of the transport sector on fossil fuels. This study deals with investigation of spray characteristics of methanol-gasoline blends as it affects engine performance and emissions characteristics to a great extent.

Biodiesel is mono alkyl ester derived from vegetable oils through transesterification reaction and can be used as an alternative to mineral diesel. In the present research, methyl ester of rice-bran oil (ROME) is produced through transesterification of rice-bran oil using methanol in presence of sodium hydroxide (NaOH) catalyst. Various properties like viscosity, density, flash point, calorific value of the biodiesel thus prepared are characterized and found comparable to diesel. On the basis of previous research for performance, emission and combustion characteristics, a 20% blend of ROME (B20) was selected as optimum biodiesel blend for endurance test. Endurance test of 100 hours was conducted on a medium duty direct injection transportation diesel engine. Tests were conducted under predetermined loading cycles in two phases: engine operating on mineral diesel and engine fuelled with 20% biodiesel blend.

Poor oxidation stability is the central problem associated with the commercial acceptance of the biodiesel. The EU standard (EN14214) specifies a minimum value of 6 h for biodiesel induction period at 110°C, measured with Rancimat instrument. Most of the freshly prepared biodiesel generally have lower induction periods than prescribed by the standards. Anti-oxidants are therefore added to enhance the oxidation/ storage stability of biodiesel. Oxidation is an exothermic process, and the reaction heat evolved makes it possible to use thermo gravimetric analysis (TGA). In the present study, the oxidation stability of methyl esters derived from Karanja oil and Neem oil, stabilized with anti-oxidant pyrogalol (PY) was studied by DSC. Onset temperature of freshly prepared Karanja biodiesel (KOME) and Neem biodiesel (NOME) was observed to be 148 and 153°C respectively. The stability increases with increasing anti-oxidant dosage.

New combustion concepts developed in internal combustion engines such as homogeneous charge compression ignition (HCCI) have attracted serious attention due to the possibilities to simultaneously achieve higher efficiency and lower emissions, which will impact the environment positively. The HCCI combustion concept has potential of ultra-low NOX and particulate matter (PM) emission in comparison to a conventional gasoline or a diesel engine. Environmental Legislation Agencies are becoming increasingly concerned with particulate emissions from engines because the health and environmental effects of particulates emitted are now known and can be measured by sophisticated instruments. Particulate emissions from HCCI engines have been usually considered negligible, and the measurement of mass emission of PM from HCCI combustion systems shows their negligible contribution to PM mass. However some recent studies suggest that PM emissions from HCCI engines cannot be neglected.

Homogeneous charge compression ignition (HCCI) engines are attracting attention as next-generation internal combustion engines mainly because of very low NOx and PM emission potential and excellent thermal efficiency. Particulate emissions from HCCI engines have been usually considered negligible however recent studies suggest that PM number emissions from HCCI engines cannot be neglected. This study is therefore conducted on a modified four cylinder diesel engine to investigate this aspect of HCCI technology. One cylinder of the engine is modified to operate in HCCI mode for the experiments and port fuel injection technique is used for preparing homogenous charge in this cylinder. Experiments are conducted at 1200 and 2400 rpm engine speeds using gasoline, ethanol, methanol and butanol fuels. A partial flow dilution tunnel was employed to measure the mass of the particulates emitted on a pre-conditioned filter paper.

Biodiesel (fatty acid methyl ester) is a non-toxic and biodegradable alternative fuel that is obtained from renewable sources. A major hurdle in the commercialization of biodiesel from virgin oil, in comparison to petroleum-based diesel, is its cost of production, primarily the raw material cost. Used cooking oils or waste cooking oils are economical sources for biodiesel production, which can help in commercialization of biodiesel. However, the products formed during cooking/frying (such as free fatty acids and various polymerized triglycerides) affect the transesterification reaction and the biodiesel properties. In present experimental investigations, wastecooking oil obtained from restaurant was used to produce biodiesel through transesterification process and the chemical kinetics of biodiesel production was studied. Biodiesel was blended with petroleum diesel in different proportions.

Biodiesel is being explored as a sustainable renewable fuel for vehicles in India due to mounting foreign exchange expenditure to import crude petroleum. Significant amount of research and development work is being undertaken in India to investigate various aspects of biodiesel utilisation in different types of engines. This study is an effort to jointly investigate the use of biodiesel (B100) in an unmodified BS-III compliant sports utility vehicle (SUV) by a consortium of academia (IIT Kanpur) and Industry (M&M) to realistically assess whether biodiesel is compatible with modern engine technology vehicles. Two identical vehicles were operated in tandem using biodiesel (B100) and mineral diesel (B00) respectively for 30,000 kilometers in field conditions. The lubricating oil samples were collected and detailed analysis for assessing the comparative effect of new fuel (B100) vis-à-vis mineral diesel was carried out.

Increased environmental awareness and depletion of resources are driving industry to develop alternative fuels that are environmentally more acceptable. Fatty acids esters (biodiesel) are known to be good alternative fuels. Due to economic reasons, the use of cheap raw materials for biodiesel production is preferred. In this case, ricebran oil, non-edible grade is used. Base catalyzed transesterification of ricebran oil is investigated and process parameters for ricebran biodiesel production are optimized. Various properties like viscosity, density, flash point, calorific value of biodiesel thus prepared are characterized as per ASTM D6751 and found comparable to mineral diesel. Steady state engine dynamometer test at 1800 rpm has been carried out to evaluate the performance and emission characteristics of a medium duty transportation DI diesel engine. Emission tests with all the fuel blends have also been carried out using European 13 MODE test (ECE R49).

Environmental concerns have increased significantly world over in the past decade. Regulatory agencies are becoming increasingly concerned with particulate emissions as the health and environmental effects are getting understood better due to rapid development in instrumentation. Biodiesel is one of the most promising alternative diesel fuels, which is getting global acceptability among the automotive/ engine manufactures as well as users due to numerous benefits it offers over the conventional diesel. While much of literature is available on particulate emitted by diesel fuelled engine, little is known by particulate emissions from biodiesel fuelled compression ignition (CI) engine. This study concentrates on the characterization of particulate emissions from mineral diesel vis-à-vis biodiesel (B100) and its optimum blend (20%, B20) with mineral diesel.

Increased environmental awareness and depletion of fossil fuel resources are driving industry to develop alternative fuels that are environmentally more acceptable. Vegetable oils are potential alternative fuels. Vegetable oils in India are produced from numerous oil-seed crops. While all vegetable oils have high energy content, most require some processing to ensure safe usage in internal combustion engines. Most detrimental properties of oils are its high viscosity, low volatility and polyunsaturated character. The most widely used method is to convert vegetable oils into biodiesel. Biodiesel fuels are primary esters, which are produced by transesterifcation of vegetable oils. Several vegetable oil esters have been investigated so far in different parts of the world and found suitable to be used in diesel engines.

In this study, macroscopic spray characteristics of Waste cooking oil (WCO), Jatropha oil, Karanja oil based biodiesels and baseline diesel were compared under simulated engine operating condition in a constant volume spray chamber (CVSC). The high pressure and high temperature ambient conditions of a typical diesel engine were simulated in the CVSC by performing pre-ignition before the fuel injection. The spray imaging was conducted under absence of oxygen in order to prevent the fuels from igniting. The ambient pressure and temperature for non-evaporating condition were 3 MPa and 300 K. Meanwhile, the spray tests were performed under the ambient pressure and temperature of 4.17 MPa and 804 K under evaporating condition. The fuels were injected by a common-rail injection system with injection pressure of 80 MPa. High speed Mie-scattering technique was employed to visualize the evaporating sprays.

Biodiesel made from Jatropha oil by transesterification process has viscosity and other important physical properties comparable to mineral diesel hence it can be used as an alternate fuel in conventional diesel engines. It is important to investigate the spray characteristics of biodiesel because emissions from the engines are dependent on fuel atomization process and resulting fuel-air mixing. This study focuses on the Jatropha biodiesel spray investigations using Phase Doppler Interferometry (PDI) for measurement of various microscopic spray parameters such as Sauter mean diameter (SMD) and spray droplet size and velocity distributions. The spray and engine experiments were carried out for Jatropha biodiesel (JB100) and their 20% blends (JB20) with mineral diesel as baseline. Fuel injection pressure during the spray experiments was maintained at 200 bars for all tests, quite similar to small horse power agricultural engines, and the fuel injection quantity was varied.

The development of advanced gasoline direct injection (GDI) injector requires in-depth investigations of macroscopic and microscopic spray characteristics. Over the years, GDI injectors have undergone exponential improvement to be able to deliver fuel at high injection pressure. High fuel injection pressure (FIP) leads to superior fuel atomization, and consequently superior fuel-air mixing. Present investigations aim to improve our fundamental knowledge of the furl-air mixture preparation mechanisms of different test fuels. Experiments were conducted to study spray breakup of GDI injector. This study focuses on the spray investigations using Phase Doppler Interferometry (PDI) for the measurement of various spray related studies such as determination of arithmetic mean diameter (AMD), sauter mean diameter (SMD) and spray droplet velocity distributions.

Fuel injection pressure (FIP) is one of the most important factors affecting diesel engine performance and particulate emissions. Higher FIP improves the fuel atomization, which results in lower soot formation due to superior fuel-air mixing. The objective of this spray study was to investigate macroscopic and microscopic spray parameters in FIP range of 500-1500 bar, using a solenoid injector for biodiesel blends (KB20 and KB40) and baseline mineral diesel. For these test fuels, effect of ambient pressure on macroscopic spray characteristics such as spray penetration, spray area and cone angle were investigated in a constant volume spray chamber (CVSC). Microscopic spray characteristics such as velocity distribution of droplets and spray droplet size distribution were measured in the CVSC at atmospheric pressure using Phase Doppler Interferometry (PDI).

Fuel atomization and air-fuel mixing processes play a dominant role on engine performance and emission characteristics in a direct injection compression ignition engine. Understanding of microscopic spray characteristics is essential to predict combustion phenomena. The present work investigated near nozzle flow and atomization characteristics of biodiesel fuels in a constant volume chamber. Waste cooking oil, Jatropha, and Karanja biodiesels were applied and the results were compared with those of conventional diesel fuel. The tested fuels were injected by a solenoid injector with a common-rail injection system. A high-speed camera with a long distance microscopic lens was utilized to capture the near nozzle flow. Meanwhile, Sauter mean diameter (SMD) was measured by a phase Doppler particle analyzer to compare atomization characteristics.

Mono alkyl esters of long-chain fatty acids derived from renewable lipid feedstock, such as vegetable oils or animal fats, also known as biodiesel are well positioned to replace mineral diesel. The outstanding technical problem with biodiesel is that it is more susceptible to oxidation owing to its exposure to oxygen present in the air and high temperature. This happens mainly due to the presence of varying numbers of double bonds in the free fatty acid molecules. The chemical reactivity of esters can therefore be divided into oxidative and thermal instability, which can be determined by the amount and configuration of the olefinic unsaturation in the fatty acid chains. Many of the plant-derived fatty oils contain polyunsaturated fatty acids that are more prone to oxidation. Increasing production of biodiesel from vegetable oils (edible) places strain on food production, availability and price and leads to food versus fuel conflict.

Premixed charge compression ignition (PCCI) combustion is an advanced combustion technique, which has the potential to be operated by alternative fuels such as alcohols. PCCI combustion emits lower oxides of nitrogen (NOx) and particulate matter (PM) and results thermal efficiency similar to conventional compression ignition (CI) engines. Due to extremely high heat release rate (HRR), PCCI combustion cannot be used at higher engine loads, which make it difficult to be employed in production grade engines. This study focused on development of an advanced combustion engine, which can operate in both combustion modes such as CI combustion as well as PCCI combustion mode. This Hybrid combustion system was controlled by an open engine control unit (ECU), which varied the fuel injection parameters for mode switching between CI and PCCI combustion modes.

Homogeneous charge compression ignition (HCCI) is an advanced combustion concept that is developed as an alternative to diesel engines with higher thermal efficiency along with ultralow NOx and PM emissions. To study the performance of this novel technique, experiments were performed in a two cylinder engine, in which one cylinder is modified to operate in HCCI mode while other cylinder operates in conventional CI mode. The quality of homogeneous mixture of air and fuel is the key feature of HCCI combustion. Low volatility of diesel is a major hurdle in achieving HCCI combustion because it is difficult to make a homogeneous mixture of air and fuel. This problem is resolved by external mixture preparation technique in uses a dedicated diesel vaporizer with an electronic control system. All the injection parameters such as fuel quantity, fuel injection timing, injection delay etc., are controlled by the injection driver circuit.

Adverse health effects of particulate matter (PM) originating from diesel engine exhaust are largely attributed to the complex chemical composition of the exhaust species. This study was set out to characterize particulate emissions from a Euro-III-compliant modern automotive common rail direct injection (CRDI) sports utility vehicle (SUV) diesel engine operated at different loads at rated engine speed (1800 rpm), employing diesel and 20% biodiesel blends (B20) produced from Karanja oil. This study is mainly divided into two main sections, first one includes the gravimetric analysis in order to assess the amount of Benzene Soluble Organic Fraction (BSOF) and trace metals using Inductively Coupled Plasma-Optical Emission Spectrometer (ICPOES). The second section includes real-time measurements for Organic Carbon (OC), Elemental Carbon (EC) and total particle-bound Polycyclic Aromatic Hydrocarbons (PAHs).

Diesel engines are very efficient prime movers in their power range. Fuel is directly injected into the combustion chamber. Performance and emission characteristics of diesel engines are highly influenced by the fuel spray parameters and atomization of the injected fuel. As the emission regulations become stringent, it is very important to optimize the combustion in internal combustion engines for different fuels including alternative fuels. Spray visualization using optical techniques play a very important role to analyze macroscopic spray parameters and fuel atomization behavior. In the present experimental study, an important alternative CI engine fuel, Karanja oil and its blends with diesel have been investigated for their spray parameters and fuel atomization relative to mineral diesel. These parameters are different for the two fuels because of difference in the viscosity and density of the fuels.