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Stochastic Pre-Ignition (SPI) or Low Speed Pre-Ignition (LSPI) is an abnormal combustion event that can occur during the operation of modern, highly boosted direct-injection gasoline engines. This abnormal combustion event is characterized by an undesired and early start of combustion that is not initiated by the spark plug. Early SPI events can subsequently lead to violent auto-ignitions that are referred to as Mega- or Super-Knock in literature and have the potential to severely damage engines in the field. Numerous studies to analyze impact factors on SPI occurrence and severity have been conducted in recent years. While initial studies have focused strongly on engine oil formulation, calibration and engine design and their respective impact on SPI initiation, the impact of physical and chemical properties of the fuel have also become of interest in recent years.

Controlled Auto Ignition combustion systems have a high potential for fuel consumption and emissions reduction for gasoline engines in part load operation. Controlled auto ignition is initiated by reaching thermal ignition conditions at the end of compression. Combustion of the CAI process is controlled essentially by chemical kinetics, and thus differs significantly from conventional premixed combustion. Consequently, the CAI combustion process is determined by the thermodynamic state, and can be controlled by a high amount of residual gas and stratification of air, residual gas and fuel. In this paper both fundamental and application relevant aspects are investigated in a combined approach. Fundamental knowledge about the auto-ignition process and its dependency on engine operating conditions are required to efficiently develop an application strategy for CAI combustion.

Stringent global emissions legislation demands effective NOx reduction strategies, particularly for the aftertreatment, and current typical liquid urea SCR systems achieve efficiencies greater than 90% [1]. However, with such high-performing systems comes the trade-off of requiring a tank of reductant (urea water solution) to be filled regularly, usually as soon as the fuel fillings or as far as oil changes. Advantages of solid reductants, particularly ammonium carbamate, include greater ammonia densities, enabling the reductant refill interval to be extended several multiples versus a given reductant volume of urea, or diesel exhaust fluid (DEF) [2]. An additional advantage is direct gaseous ammonia dosing, enabling reductant injection at lower exhaust temperatures to widen its operational coverage achieving greater emissions reduction potential [3], as well as eliminating deposits, reducing mixing lengths, and avoiding freeze/thaw risks and investments.

The occurrence of abnormal combustion events leading to high peak pressures and severe knock can be considered to be one of the main challenges for modern turbocharged, direct-injected gasoline engines. These abnormal combustion events have been referred to as Stochastic Pre-Ignition (SPI) or Low-Speed Pre-Ignition (LSPI). The events are characterized by an undesired, early start of combustion of the cylinder charge which occurs before or in parallel to the intended flame kernel development from the spark plug. Early SPI events can subsequently lead to violent auto-ignitions that are often referred to as Mega- or Super-Knock. These heavy knock events lead to strong pressure oscillations which can destroy production engines within a few occurrences. SPI occurs mainly at low engine speed and high engine load, thus limiting the engine operating area that is in particular important to achieve good drivability in downsized engines.