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Designing advanced, clean and fuel-efficient engines requires detailed understanding of fuel chemistry. While knowledge of fuel combustion chemistry has grown rapidly in recent years, the representation of conventional fossil fuels in full detail is still intractable. A popular approach is to use a model-fuel or surrogate blend that can mimic various characteristics of a conventional fuel. Despite the use of surrogate blends, there remains a gap between detailed chemistry and its utilization in computational fluid dynamics (CFD), due to the prohibitive computational cost of using thousands of chemical species in large numbers of computational cells. This work presents a set of software tools that help to enable the use of detailed chemistry in representing conventional fuels in CFD simulation. The software tools include the Surrogate Blend Optimizer and a suite of automated mechanism reduction strategies.

Lean burn or EGR diluted combustion with enhanced charge motion is effective in improving the efficiency of spark ignition engines. However, the ignition process under these conditions is getting more challenging due to higher ignition energy required by the lean or diluted mixture, as well as the interactions of the gas flow on the flame kernel. Enhanced spark discharge energy is essential to initiate the combustion under these conditions. Moreover, the discharge process should be more carefully controlled to improve the effectiveness of the spark. In this study, spark ignition systems with boosted discharge energy are used to ignite diluted air-fuel mixture under forced flow conditions. The impacts of the discharge current level, the discharge duration and the discharge current profile on the ignition are investigated in detail using optical diagnosis.

To meet the request of China National 6b emission regulations which will be officially implemented in China, firstly including the RDE emission test limits, the transient emissions on real road condition are paid more attention. A non-plug-in hybrid light-duty gasoline vehicles (HEV) sold in the Chinese market was selected to study real road emissions employed fast response NOx analyzer from Cambustion Ltd. with a sampling frequency of 100Hz, which can measure the missing NO peaks by standard RDE gas analyzer now. Emissions from PEMS were also recorded and compared with the results from fast response NOx analyzer. The concentration of NOx emissions before and after the Three Way Catalyst (TWC) of the hybrid vehicle were also sampled and analyzed, and the working efficiency of the TWC in real road driving process was investigated.

For internal combustion engine systems, lean and diluted combustion is an important technology applied for fuel efficiency improvement. Because of the thermodynamic boundary conditions and the presence of in-cylinder flow, the development of a well-sustained flame kernel for lean combustion is a challenging task. Reliable spark discharge with the addition of enhanced delivered energy is thus needed at certain time durations to achieve successful combustion initiation of the lean air-fuel mixture. For a conventional transistor coil ignition system, only limited amount of energy is stored in the ignition coil. Therefore, both the energy of the spark discharge and the duration of the spark discharge are bounded. To break through the energy limit of the conventional transistor coil ignition system, in this work, an adaptive spark ignition system is introduced. The system has the ability to reconstruct the conductive ion channels whenever it is interrupted during the spark discharge.

The first firing cycle is very important for cold-start. Misfire of the first firing cycle can lead to significant HC emissions and affect the subsequent cycles. The first firing cycle for Gasoline SI engine have been reported in many studies. Liquefied petroleum gas (LPG) as an alternative fuel has been widely used in commercial vehicles during the last decade. However, the properties of the first firing cycle for LPG SI engine have been seldom reported. This paper presents an investigation of the characteristics of transient HC emissions of the first firing cycle during cold start on a LPG SI engine. A fast-response flame ionization detector (FFID) was applied to measure transient HC emissions of the first firing cycle in the exhaust port of the engine. At the same time, the transient cylinder pressure and instantaneous crankshaft speed of the engine were measured and recorded.

By changing the top-land radial clearance, this paper presents the effect of the piston crevice on the transient HC emissions of the first firing cycle at cold start on an LPG SI Engine. A fast-response flame ionization detector (FFID) was employed to measure transient HC emissions of the first firing cycle. At the same time, the transient cylinder pressure and instantaneous crankshaft speed of the engine were measured and recorded. The results show that increasing 50% crevice volume leads to 25% increase of HC emissions in the lean region and 18% increase of HC emissions in the rich region, however, the 50% increase of crevice volume contributes to 32% decease of HC emissions in the stable combustion region. For LPG SI engine, the HC emissions of the first firing cycle during cold start are relatively low in a wide range of the excess air ratio.

The effectiveness of after-treatment systems depends on the exhaust gas temperature, which is low during cold-start. As a result, Euro III, Euro IV and FTP75 require that the emissions tests include exhaust from the beginning of cold start. It is proved that 50%∼80% of HC and CO emissions are emitted during the cold start and the amount of unburned fuel from the crevices during starting is much higher than that under warmed engine conditions. The piston crevices is the most part of combustion chamber crevices, and results of mathematical simulations show that the piston crevice contribution to HC emissions is expected to increase during cold engine operation. Based on the transient HC test data and the double zone combustion model, this paper presents the study of the crevice HC Mechanism of the first firing cycle at cold start on an LPG SI Engine. A fast-response flame ionization detector (FFID) was employed to measure transient HC emissions of the first firing cycle.

The exhaust aftertreatment strategy is one of the most fundamental aspects of spark ignition engine technologies. For various types of engines (e.g., carburetor engine, PFI engine and GDI engine), measuring, purifying, modeling, and control strategies regarding the exhaust aftertreatment systems vary significantly. The primary goal of exhaust aftetreatment systems is to reduce the exhaust emission levels of NOx, HC and CO as well as to lower combustion soot. In general, there is a tradeoff among different engine performance aspects. The exhaust catalytic systems, such as the three way catalyst (TWC) and lean NOx trap (LNT) converters, can be applied together with the development of other engine technologies (e.g., variable valve timing, cold start). With respect to engine soot, some advanced diagnosing techniques are essential to obtain thorough investigation of exhaust emission mechanisms.

Combustion and emission characteristics of diesel and biodiesel blends (soybean methyl ester) were studied in a single-cylinder Direct Injection (DI) engine at different loads and a constant speed. The results show that NOx emission and fuel consumption are increased with increasing biodiesel percentage. Reduction of smoke opacity is significant at higher loads with a higher biodiesel ratio. Compared with the baseline diesel fuel, B20 (20% biodiesel) has a slight increase of NOx emission and similar fuel consumption. Smoke emission of B20 is close to that of diesel fuel. Results of combustion analysis indicate that start of combustion (SOC) for biodiesel blends is earlier than that for diesel. Higher biodiesel percentage results in earlier SOC. Earlier SOC for biodiesel blends is due to advanced injection timing from higher density and bulk modulus and lower ignition delay from higher cetane number.

In this paper, the characteristics of performance and emissions of diesel and biodiesel blends are studied in a four-cylinder DI engine employing common rail injection system. The results show that engine output power is further reduced and brake specific fuel consumption (BSFC) increased with the increase of the blend concentration. B100 provides average reduction by 8.6% in power and increase by 11% in BSFC. With respect to the emissions, although NOx emissions were increased with increasing the blend concentration, the increase depends on the load. Filter smoke number is reduced with increasing the blend concentration. At the same time, NO, NO2 and other specific emissions are also investigated. In addition, difference of performance and emission between standard parameters of ECU and modified parameters of ECU is investigated for B10 and B20 based on same output power. The results show that NOx emission and FSN are still lower than baseline diesel.

In this paper, characteristics of gas emission and particle size distribution are investigated in a common rail diesel engine fueled with biodiesel blends. Gas emission and particle size distribution are measured by AVL FTIR - SESAM and SMPS respectively. The results show that although biodiesel blends would result in higher NOx emissions, characteristics of NOx emissions were also dependent on the engine load for waste cooking oil methyl ester. Higher blend concentration results in higher NO2 emission after two diesel oxidation catalyst s (DOC). A higher blend concentration leads to lower CO and SO2 emissions. No significant difference of Alkene emission is found among biodiesel blends. The particle size distributions of diesel exhaust aerosol consist of a nucleation mode (NM) with a peak below 50N• m and an accumulation mode with a peak above 50N • m. B100 will result in lower particulates with the absence of NM.

The active components, such as OH and their concentrations in the coflow, have a strong effect on the combustion process of diesel fuel spray flames in the Controllable Active Thermo-Atmosphere (CATA), which then will affect the soot incandescence of the spray flames. CO2 and H2O2, the additives which have contrary effect on the concentration of the active components, were mixed separately into the thermo-atmosphere before the jet spray were issued into the coflow, which changed the boundary condition around the central jet and influenced the combustion characteristics and soot incandescence. The combustion characteristics such as ignition delay and flame liftoff height of the central spray flames are measured and the linkage between these two parameters is investigated at different coflow temperatures.

The effects of biodiesel on the swelling of the elastomers and plastics and the corrosion of metals are studied by the immersion tests. The results indicate that biodiesels make little corrosion effect on aluminum, steel and little swelling impact on plastics, but a significant corrosion may be taken place on cooper and brass for some sourced biodiesels. For nitrile-butadiene rubber, the variation of swelling properties in biodiesels is slightly higher than that in diesel. For the non-diesel-resistant elatomers, the variation of swelling properties is lower than those in diesel. The production process and biodiesel source have an influence on the result of elastomer swelling and corrosion. The relationship between the impact of biodiesel on materials and biodiesels properties are also discussed.

Surrogate fuels used in simulations need to capture the physical, combustion and emission characteristics of the real diesel and gasoline fuels they represent. This requirement can result in complex surrogate fuels that are blends of components representing several chemical classes, such as normal-, cyclo- and iso-alkanes, alkenes and aromatics. With a palette of around 20 potential surrogate-fuel components we can identify a blend to represent the most important physical and chemical properties of a particular real fuel. However, a detailed chemical kinetics mechanism is required to use such a surrogate in a model of the in-cylinder combustion processes. The detailed mechanism must capture the relevant kinetic pathways for all of the surrogate-fuel components. To this end, we have assembled a large comprehensive kinetic mechanism that includes several thousands of species to represent the combustion behavior of a wide range of surrogate fuels for gasoline and diesel.

The swelling of ‘O’ rings of 3 typical rubbers (NBR, FKM, EPDM) and the corrosion of 2 typical copperish metal pieces (Copper, Brass) were investigated. The fuel samples included 14 kinds of biodiesels, 1 kind of diesel, and 4 kinds of blends respectively for 2 kinds of biodiesels. The changes in mass and size of ‘O’ rings were measured with an electronic balance and a vernier caliper. The surface corrosion of copperish metals was recorded with photos. It was found that the swelling of NBR in pure biodiesels were generally larger than those in diesel. The mass and size of FKM almost did not change in both pure biodiesels and diesel. The swelling of EPDM became less in pure biodiesels than that in diesel. When the blend ratios of biodiesels were less than 10%, the change rates in mass, inner diameter and section diameter of NBR, FKM and EPDM were similar between blended fuels and diesel.

This paper presents the simulation of in-cylinder stratified mixture formation, spray motion, combustion and emissions in a four-stroke and four valves direct injection spark ignition (DISI) engine with a pent-roof combustion chamber by the computational fluid dynamics (CFD) code. The Extended Coherent Flame Combustion Model (ECFM), implemented in the AVL-Fire codes, was employed. The key parameters of spray characteristics related to computing settings, such as skew angle, cone angle and flow per pulse width with experimental measurements were compared. The numerical analysis is mainly focused on how the tumble flow ratio and geometry of piston bowls affect the motion of charge/spray in-cylinder, the formation of stratified mixture and the combustion and emissions (NO and CO₂) for the wall-guided stratified-charge spark-ignition DISI engine.

Biodiesel has been paid more and more attention as a renewable fuel due to some excellent properties such as renewable, high cetane number, ultralow sulfur content, no aromatic hydrocarbon, high flash point, low CO2 emission when compared with diesel. While others physical properties like high viscosity, high surface tension, big density and bad volatility would spoil the spray characteristics of biodiesel fuel, which will affect the thermal efficiency when running in diesel engine. Accompanied with constant volume vessel and high speed video camera system, a high pressure common rail system, which could provide an injection pressure of 180 MPa, is used to investigate the characteristics of jatropha curcas biodiesel, palm oil biodiesel and diesel fuel. The effects of injection pressures and ambient densities on spray characteristics of these fuels are studied.

Detailed knowledge of hydrocarbon fuel combustion chemistry has grown tremendously in recent years. However, the gap between detailed chemistry and computational fluid dynamics (CFD) remains, because of the high cost of solving detailed chemistry in a large number of computational cells. This paper presents the results of applying a suite of techniques aimed at closing this gap. The techniques include use of a surrogate blend optimizer and a guided mechanism reduction methodology, as well as advanced methods for efficiently and accurately coupling the pre-reduced kinetic models with the multidimensional transport equations. The advanced methods include dynamic adaptive chemistry (DAC) and dynamic cell clustering (DCC) algorithms.

This paper presents the development of an electronic control LPG gas injection system and its application in a small SI engine. The tests results show that the developed LPG gas injection system can meet the needs for the goal of high engine power output and low exhaust emissions based on the engine bench tests. With the LPG electronic gas injection system, the air-fuel ratio can be optimized based on the requirements and CO and NOx emission levels are decreased significantly compared with the LPG mechanical mixer fuel supply system, based on the same HC emission levels. With the new gas phase LPG electronic control injection system, the HC emission level is controlled below the 300 ppm under most engine conditions and under 200 ppm when the engine speed is over 3000 r/min. The NOx emission level is under 2600 ppm in the whole range of engine operation conditions and is decreased by 2000 ppm compared with the LPG mechanical mixer system.

An air-cooled, four-stroke, 125 cc electronic gasoline fuel injection SI engine for motorcycles is altered to burn ethanol fuel. The effects of nozzle orifice size, fuel injection duration, spark timing and the excess air/ fuel ratio on engine power output, fuel and energy consumptions and engine exhaust emission levels are studied on an engine test bed. The results show that the maximum engine power output is increased by 5.4% and the maximum torque output is increased by 1.9% with the ethanol fuel in comparison with the baseline. At full load and 7000 r/min, HC emission is decreased by 38% and CO emission is decreased 46% on average over the whole engine speed range. However, NOx levels are increased to meet the maximum power output. The experiments of the spark timing show that the levels of HC and NOx emission are decreased markedly by the delay of spark timing.