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Diesel soot suppression effects of catalytic fuel additives for a range of fuels with different properties were investigated with calcium naphthenate. A single cylinder DI diesel engine and a thermobalance were used to determine the soot reduction and its mechanism for seven kinds of fuels. Experimental results showed that the catalytic effect of the fuel additive was different for the different fuels, and could be described by a parameter considering cetane number and kinematic viscosity. The fuel additives reduced soot more effectively for fuels with higher cetane number and lower kinematic viscosity. This result was explained by soot oxidation characteristics for the different fuels. Oxidation of soot with the metallic additive proceeds in two stages: stage I, a very rapid oxidation stage; and stage II, a following slow or ordinary oxidation stage.

This research investigates the influences of the injection timing, injection pressure, and compression ratio on the combustion and exhaust emissions in a single cylinder 1.0 L DI diesel engine operating with ultra-high EGR. Longer ignition delays due to either advancing or retarding the injection timing reduced the smoke emissions, but advancing the injection timing has the advantages of maintaining the thermal efficiency and preventing misfiring. Smokeless combustion is realized with an intake oxygen content of only 9-10% regardless of the injection pressure. Reduction in the compression ratio is effective to reduce the in-cylinder temperature and increase the ignition delay as well as to expand the smokeless combustion range in terms of EGR and IMEP. However, the thermal efficiency deteriorates with excessively low compression ratios.

In a DI diesel engine, THC emissions increase significantly with lower compression ratios, a low coolant temperature, or during the transient state. During the transient after a load increase, THC emissions are increased significantly to very high concentrations from just after the start of the load increase until around the 10th cycle, then rapidly decreased until the 20th cycle, before gradually decreasing to a steady state value after 1000 cycles. In the fully-warmed steady state operation with a compression ratio of 16 and diesel fuel, THC is reasonably low, but THC increases with lower coolant temperatures or during the transient period just after increasing the load. This THC increase is due to the formation of over-lean mixture with the longer ignition delay and also due to the fuel adhering to the combustion chamber walls. A low distillation temperature fuel such as normal heptane can eliminate the THC increase.

The thermal cracking and polyaromatic hydrocarbon (PAH) formation processes of dimethyl ether (DME), ethanol, and ethane were investigated with chemical kinetics to determine the soot formation mechanism of oxygenated fuels. The modeling analyzed three processes, an isothermal constant pressure condition, a temperature rising condition under a constant pressure, and an unsteady condition approximating diesel combustion. With the same mole number of oxygen atoms, the DME rich mixtures form much carbon monoxide and methane and very little non-methane HC and PAH, in comparison with ethanol or ethane mixtures. This suggests that the existence of the C-C bond promotes the formation of PAH and soot.

Time resolved changes in unburned hydrocarbon emissions and their components were investigated in a DI diesel engine with a specially developed gas sampling system and gas chromatography. The tested transient operations include starting and increasing loads. At start-up with high equivalence ratios the total hydrocarbon (THC) at first increased, and after a maximum gradually decreased to reach a steady state value. Reducing the equivalence ratio of the high fueling at start-up and shortening the high fueling duration are effective to reduce THC emissions as long as sufficient startability is maintained. Lower hydrocarbons, mainly C1-C8, were the dominant components of the THC and mainly determined the THC behavior in the transient operations while the proportion of hydrocarbon (HC) components did not significantly change. The unregulated toxic substances, 1,3 butadiene and benzene were detected in small quantities.

Smokeless and ultra low NOx combustion without knocking in a dual-fuel diesel engine with induced LPG as the main fuel was established with a uniquely developed piston cavity divided by a lip in the sidewall. A small quantity of diesel fuel was directly injected at early compression stroke into the lower part of the cavity as an ignition source for this confined area, and this suppressed explosively rapid combustion just after ignition and spark-knock like combustion at later stage. A combination of the divided cavity, EGR, and intake air throttling was effective to simultaneously eliminate knocking, and reduce THC and NOx significantly.

Fuel properties are a very important factor to reduce particulate matter (PM) and other emissions with diesel engines. Especially the effect of aromatic contents has been discussed, though details of the influence differ in different reports. In this study the mechanism of PM formation was investigated in a small direct injection diesel engine. The fuels tested were paraffinic hydrocarbons (C7∼C12) with different boiling points (98∼216 °C), and the blending of aromatic hydrocarbons (1∼4 rings) with paraffinic and olefinic hydrocarbons. The effect of the structure of fuels with the same carbon numbers (dodecane and dodecene) was also investigated. The results showed that the amount of SOF decreases to about one tenth of that of diesel oil when using low boiling point paraffinic hydrocarbons like heptane. However, the total amount of unburned hydrocarbon increases due to over-leaning of the mixture due to the early evaporation.

This study proposes a new combustion chamber concept for small DI diesel engines. Reduction of fuel adhering to the cavity wall, improvements in mixture formation, and an optimum distribution of mixture inside and outside the cavity are the main characteristics of the combustion chamber. The spray formation and it's distribution inside and outside the combustion chamber was investigated photographically in a small DI diesel engine with transparent cylinder and piston. Optimization of the fuel spray distribution inside and outside the cavity was attempted by changing the shape of the cavity entrance and the location where spray impinges on the lip. In addition improvements in the mixture formation of the impinging spray and reductions in the fuel adhering to the cavity wall were attempted by introducing a small step on the cavity side wall. The results were confirmed by analyzing the combustion and emission in an actual DI diesel engine.

The fundamental parameters related to engine combustion and performances, such as, heating value, theoretical air-fuel ratio, adiabatic flame temperature, carbon dioxide (CO2), and nitric oxide (NO) emissions, specific heat and engine thermal efficiency were investigated with computations for a wide range of oxygenated fuels. The computed results showed that almost all of the above combustion-related parameters are closely related to oxygen content in the fuels regardless of the kinds or chemical structures of oxygenated fuels. An interesting finding was that with the increase in oxygen content in the fuels NO emission decreased linearly, and the engine thermal efficiency was almost unchanged below oxygen content of 30 wt-% but gradually decreased above 30 wt-%.

This study investigated the effects of injection pressure and split injection on exhaust odor and engine noise in DI diesel engines. At idle, an injection pressure of 60 to 80 MPa resulted in the minimum exhaust odor with the least aldehyde and minimum THC formation. This is because of decreases in fuel adhering to the combustion chamber walls due to the shortest ignition delay and improved mixture formation at this pressure range. However, above 60 MPa there is no further shortening of the ignition delay and overleaning of the local mixture dominates at injection pressures above 100 MPa, where the exhaust odor increases again. The higher injection pressure of 60 to 80 MPa is favorable for emission reductions, but there are increases in engine noise and engine instability at idle. To reduce engine noise, further experiments with split injection were attempted.

This study investigated the odorous components in the exhaust of DI diesel engines. The complete products of combustion are H2O and CO2, which have no odor. Therefore, other products of incomplete combustion like unburned fuel components, partially burned components, cracked products from thermal cracking and others are thought to be responsible for exhaust odor. The THC in the exhaust is the result of incomplete combustion. This study measured THC in the exhaust, and a good correlation was found between THC and exhaust odor at different engine conditions. The low boiling point hydrocarbon components, especially CH4 in diesel exhaust were found to show a good correlation with exhaust odor. Aldehydes in exhaust gases correlate with exhaust odor very well and among the aldehydes, formaldehyde is found to be the most important component in causing irritating odor. The other part of this study is devoted to the improvement in the odor assessment used for DI diesel engines.

This study investigated the effect of ignition delay and exhaust gas speed on exhaust odor in DI diesel engines. From the investigation of many engine parameters like injection timing and injection pressure, it has been found that the optimum ignition start position is more important than the shorter ignition delay, but the optimum ignition start position along with the shorter ignition delay is the best scenario for minimum odor. Further, it has been found that good mixture formation is more important than shorter ignition delay in reducing odor, but the optimum mixture formation together with shorter ignition delay results in the lowest odorous emissions. From the investigation of various fuels in the diesel engine, it seems that the combustion pattern and the raw odor of fuel are more important than ignition delay. A fuel with low raw odor and high cetane number with optimum boiling point significantly improves the exhaust odor.

Direct injection of various ignition suppressors, including water, methanol, ethanol, 1-propanol, hydrogen, and methane, was implemented to control ignition timing and expand the operating range in an HCCI engine with induced DME as the main fuel. Ultra-low NOx and smoke-less combustion was realized over a wide operating range. The reaction suppressors reduced the rate of low-temperature oxidation and consequently delayed the onset of high-temperature oxidation. Analysis of the chemical kinetics showed a reduction of OH radical in the premixed charge with the suppressors. Among the ignition suppressors, alcohols had a greater impact on OH radical reduction resulting in stronger ignition suppression. Although water injection caused a greater lowering of the temperature, which also suppressed ignition, the strong chemical effect of radical reduction with methanol injection resulted in the larger impact on suppression of oxidation reaction rates.

The effects of several fuel property variables on the emissions from a D.I. diesel engine were individually analyzed. The results showed that the smoke and dry soot increased with increased kinematic viscosity, shorter ignition lag, and higher aromatic content, especially at high equivalence ratios. Over the whole range of equivalence ratios, SOF depended on and increased with only ignition lag. The NOx improved slightly with increased kinematic viscosity, higher ignitability, and decreased aromatic content. The unburnt HC also improved with decreased kinematic viscosity and higher ignitability. The distribution shape of distillation curves had little influence on the emissions.

Blue smoke and HC emissions from a direct injection diesel engine increase gradually during long idling operation (for a few hours). The extent of this increase depends on the injection nozzle specification and engine operating conditions. The accumulation of carbon deposits on the nozzle tip and combustion chamber wall will depend on these factors. Since the carbon absorbs fuel well, low volatility components can not evaporate during the combustion period and the unburned fuel emissions increase over time. This tendency changes according to fluctuations of spray shape and cylinder to cylinder fuel quantity variations.

A new concept DISC engine equipped with a two-stage injection system was developed. The engine was modified from a single cylinder DI diesel engine with large cylinder diameter (135mm). Combustion characteristics and exhaust emissions with regular gasoline were examined, and the experiments were also made with gasoline-diesel fuel blends with higher boiling temperatures and lower octane numbers. To realize stratified mixture distribution in combustion chamber flexibly, the fuel was injected in two-stages: the first stage was before the compression stroke to create a uniform premixed lean mixture and the second stage was at the end of the compression stroke to maintain stable ignition and faster combustion. In this paper, the effect of the two-stage injection on combustion and exhaust emissions were analyzed under several operating conditions.

The effect of direct water injection into the combustion chamber on NOx reduction in an IDI diesel engine was investigated. The temperature distribution in the swirl chamber was analyzed quantitatively with high speed photography and the two color method. Direct water injection into a swirl chamber prior to fuel injection reduced NOx emission significantly over a wide output range without sacrifice of BSFC. Other emissions were almost unchanged or slightly decreased with water injection. Water injection reduced the flame temperature at the center of the swirl chamber, while the mean gas temperature in the cylinder and the rate of heat release changed little.

The effect of eight kinds of oxygenated agents added to diesel fuels on the combustion and emissions was investigated in a DI diesel engine. The results showed significant smoke and particulate suppression without increases in NOx with every oxygenated agent. The emissions decreased linearly with increasing oxygen content in the fuels, almost regardless of the kind of oxygenated agent. The improvement in smoke and particulate emissions with the oxygenated agent addition was more significant for lower volatility fuels. Combustion analysis with the two-dimensional two color method showed that soot concentration in the flame during the combustion process decreased with the addition of the oxygenated agent while the flame temperature distribution was almost unchanged.

The effect of several aqueous metal-salt solutions on NOx and smoke lowering in an IDI diesel engine were examined. The solutions were directly injected into a divided chamber independent of the fuel injection. The results showed that significant lowering in NOx and smoke over a wide operation range could be achieved simultaneously with alkali metal solutions which were injected just prior to the fuel injection. With sodium-salt solutions, for instance, NOx decreased by more than 60 % and smoke decreased 50 % below conventional operation. The sodium-salt solution reduced dry soot significantly, while total particulate matter increased with increases in the water soluble fractions.

In a four-cycle, naturally aspirated, pre-chamber diesel engine, the combustion characteristics such as the rates of fuel injection, the ignition lag, the rates of heat release, the combustion peak pressure, the maximum rates of pressure rise, and the smoke density, were investigated for over 70 consecutive cycles under acceleration, with the aid of an on-line data handling system developed for this experiment. The effects of operating conditions such as the fuel injection timing, the fuel spray angle, the wall temperature of the combustion chamber, and the coolant temperature, on the combustion characteristics were also investigated.