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Journal Article

Calibration and Validation of Various Commercial Particle Number Measurement Systems

2009-04-20
2009-01-1115
Measurement of particle number was introduced in the Euro 5/6 light duty vehicle emissions regulation. Although particle number measurement systems have to be calibrated by the manufacturers, labs have to validate the proper operation of their systems within one year of the emissions test. The systems must achieve a >99% reduction of an aerosol containing 30 nm tetracontane (CH3(CH2)38CH3) particles (C40) with an inlet concentration >104 #/cm3. They must also include an initial heated dilution stage with dilution of at least 10 which outputs a diluted sample at a temperature of 150°C–400°C. The system as a whole must achieve a particle number concentration reduction factor for particles of 30 nm and 50 nm electrical mobility diameters, that is no more than 30% and 20% respectively higher, and no more than 5% lower than that for particles of 100 nm.
Journal Article

Heavy Duty Particle Measurement Programme (PMP): Exploratory Work for the Definition of the Test Protocol

2009-06-15
2009-01-1767
The heavy duty Particle Measurement Programme (PMP) inter-laboratory exercise consists of three parts: 1) the exploratory work to refine the measurement protocol, 2) the validation exercise where each lab will measure the emissions of a “golden” engine with two “golden” particle number systems simultaneously sampling from full and partial flow dilution systems, and 3) the round-robin where the emissions of a “reference” engine will be determined with a lab’s own particle number instrumentation. This paper presents the results of the exploratory work and describes the final protocol for testing in the validation exercise (and round robin) along with the necessary facility modifications required for compliance with the protocol. Key aspects of the protocol (e.g. filter material, flow rates at the full and partial flow systems, the pre-conditioning etc.) are explained and justified.
Journal Article

Theoretical Investigation of Volatile Removal Efficiency of Particle Number Measurement Systems

2010-04-12
2010-01-1304
Euro 5/6 light-duty vehicle emissions regulation introduced non-volatile particle number emission measurements. The particle number measurement system consists of a volatile removal unit followed by a particle number counter with a 50% cut-point diameter at 23 nm. The volatile removal unit must achieve a >99% concentration reduction of a monodisperse aerosol of tetracontane (CH 3 (CH 2 ) 38 CH 3 ) particles of diameter ≥30 nm with inlet concentration ≥10 4 cm −3 . In this paper the evaporation of tetracontane particles in the volatile removal unit is investigated theoretically. The temperature and the residence time in the evaporation tube are discussed, as well as the possibility of nucleation events of evaporated particles at the exit of the evaporation tube. In addition, sulfuric acid nucleation at the evaporation tube exit is analyzed. Theoretical calculations are, finally, compared to experimental data.
Journal Article

Impact of Biodiesel Blends on Fuel Consumption and Emissions in Euro 4 Compliant Vehicles

2010-05-05
2010-01-1484
Fatty Acid Methyl Ester (FAME) products derived from vegetable oils and animal fats are now widely used in European diesel fuels and their use will increase in order to meet mandated targets for the use of renewable products in road fuels. As more FAME enters the diesel pool, understanding the impact of higher FAME levels on the performance and emissions of modern light-duty diesel vehicles is increasingly important. Of special significance to Well-to-Wheels (WTW) calculations is the potential impact that higher FAME levels may have on the vehicle's volumetric fuel consumption. The primary objective of this study was to generate statistically robust fuel consumption data on three light-duty diesel vehicles complying with Euro 4 emissions regulations. These vehicles were evaluated on a chassis dynamometer using four fuels: a hydrocarbon-only diesel fuel and three FAME/diesel fuel blends containing up to 50% v/v FAME. One FAME type, a Rapeseed Methyl Ester (RME), was used throughout.
Technical Paper

On-Road Emissions of Euro 6d-TEMP Vehicles: Consequences of the Entry into Force of the RDE Regulation in Europe

2020-09-15
2020-01-2219
Human health and the environment are heavily impacted by air pollution. Air quality standards for Nitrogen dioxide (NO2) and particulate matter (PM) are commonly exceeded in Europe, particularly in urban areas with high density of traffic. Road transport contributed to 39% of NOx emissions, and 11% of PM emissions in the European Union (EU) in 2017. Measurements with Portable Emissions Measurement Systems (PEMS) showed that most Euro 5 and Euro 6b diesel vehicles emitted significantly more NOx on the road than their permissible limit in the laboratory type-approval test. In that context, EU Real Driving Emissions (EU-RDE) regulation aims at securing low on-road emissions of light duty vehicles under normal conditions of use. This paper assesses the tailpipe emissions performance of Euro 6d-TEMP gasoline and diesel passenger cars, type-approved after the entry into force of the RDE regulation in September 2017.
Technical Paper

Particulate Matter (PM) Emissions of Euro 5 and Euro 6 Vehicles Using Systems with Evaporation Tube or Catalytic Stripper and 23 nm or 10 nm Counters

2020-09-15
2020-01-2203
Particle number (PN) emission limits were introduced in the European Union’s regulations for light-duty and heavy duty vehicles in the years 2011-2014. Since then, PN measurements have become a common practice in the automotive sector. Many studies showed that the current methodology, which counts particles >23 nm, misses a large fraction of particles for some engine technologies, such as port fuel injection vehicles or vehicles fueled with compressed natural gas (CNG). However, data for the latest technology vehicles are lacking. For this reason, we measured PN emissions >23 nm and >10 nm of >30 CNG, gasoline and diesel-fueled vehicles. Two systems were measuring in parallel from the full dilution tunnel; one with an evaporation tube and the other with a catalytic stripper. The PN emission levels spanned over three orders of magnitude depending on whether there was a particulate filter installed or not.
Technical Paper

A Methodology for Monitoring On-Road CO2 Emissions Compliance in Passenger Vehicles

2020-06-30
2020-37-0034
The European Union road transport CO2 emissions regulation foresees mandatory targets for passenger vehicles. However, several studies have shown that there is a divergence between official and real-world values that could range up to 40% compared to the NEDC reference value. The introduction of the Worldwide Harmonized Test Protocol (WLTP) limited this divergence, but it is uncertain whether it can adequately address the problem, particularly considering future evolutions of vehicle technology. In order to address this issue, the recent EU CO2-standards regulation introduces the monitoring of on-road fuel consumption and subsequently CO2 emissions by utilizing On-Board Fuel Consumption Meters (OBFCM). In the near future, all vehicles should provide instantaneous and lifetime-cumulative fuel consumption signals at the diagnostics port. Currently, the fuel consumption signal is not always available.
Journal Article

Particle Emission Measurements from L-Category Vehicles

2015-09-06
2015-24-2512
In 2011 a particle number (PN) limit was introduced in the European Union's vehicle exhaust legislation for diesel passenger cars. The PN method requires measurement of solid particles (i.e. those that do not evaporate at 350 °C) with diameters above 23 nm. In 2013 the same approach was introduced for heavy duty engines and in 2014 for gasoline direct injection vehicles. This decision was based on a long evaluation that concluded that there is no significant sub-23 nm fraction for these technologies. In this paper we examine the suitability of the current PN method for L-category vehicles (two- or three-wheel vehicles and quadri-cycles). Emission levels of 5 mopeds, 9 motorcycles, 2 tricycles (one of them diesel) and 1 quad are presented. Special attention is given to sub-23 nm emission levels. The investigation was conducted with PN legislation compliant systems with particle counters measuring above 23 nm and 10 nm.
Journal Article

A New Constant Dilution Ratio Concept for Vehicle and Engine Exhaust Particle Sampling

2008-04-14
2008-01-0762
This paper presents a new concept of a partial flow sampling system (PFSS), involving a two-stage dilutor which operates at underpressure, while exhaust is sampled through a capillary. The sample flowrate is in the order of few cubic centimeters per minute. Due to the low flowrate, no tight fixation is required between the exhaust line and the capillary inlet. The dilutor may sample from an opening in the exhaust line which freely exhausts to ambient pressure. As a result, the PFSS operates at constant pressure conditions even upstream of diesel particle filters (DPF). A straightforward mathematical model is then developed to calculate the dilution ratio (DR), depending on the dilution air flowrate and the dilutor underpressure. The model is validated using CO2 as a trace gas, and a very good agreement is demonstrated between the calculated and the measured DR values.
Journal Article

Calibration and Validation of a Diesel Oxidation Catalyst Model: from Synthetic Gas Testing to Driving Cycle Applications

2011-04-12
2011-01-1244
To meet future stringent emission regulations such as Euro6, the design and control of diesel exhaust after-treatment systems will become more complex in order to ensure their optimum operation over time. Moreover, because of the strong pressure for CO₂ emissions reduction, the average exhaust temperature is expected to decrease, posing significant challenges on exhaust after-treatment. Diesel Oxidation Catalysts (DOCs) are already widely used to reduce CO and hydrocarbons (HC) from diesel engine emissions. In addition, DOC is also used to control the NO₂/NOx ratio and to generate the exothermic reactions necessary for the thermal regeneration of Diesel Particulate Filter (DPF) and NOx Storage and Reduction catalysts (NSR). The expected temperature decrease of diesel exhaust will adversely affect the CO and unburned hydrocarbons (UHC) conversion efficiency of the catalysts. Therefore, the development cost for the design and control of new DOCs is increasing.
Journal Article

Implications of Engine Start-Stop on After-Treatment Operation

2011-04-12
2011-01-1243
It is commonly accepted that future powertrains will be based to a large extent on hybrid architectures, in order to optimize fuel efficiency and reduce CO₂ emissions. Hybrid operation is typically achieved with frequent engine start-and-stops during real-world as well as during the legislated driving cycles. The cooling of the exhaust system during engine stop may pose problems if the substrate temperature drops below the light-off temperature. Therefore, the design and thermal management of after-treatment systems for hybrid applications should consider the 3-dimensional heat transfer problem carefully. On the other hand, the after-treatment system calculation in the concept design phase is closely linked with engine calibration, taking into account the hybridization strategy. Therefore, there is a strong need to couple engine simulation with 3d aftertreatment predictions.
Journal Article

On-Site Checks of the Particle Number Measurement Systems with Polydisperse Aerosol

2012-04-16
2012-01-0873
Since 2011 a particle number (PN) limit was introduced in the European light-duty diesel vehicles legislation. The PN measurement systems consist of i) a hot diluter and an evaporation tube at 300-400°C for the removal of the volatiles (Volatile Particle Remover, VPR) and ii) a particle number counter (PNC) with a 50% cut-point (cut-off) at 23 nm. The PN measurement systems are calibrated and validated annually with monodisperse aerosol: The VPR for the particle concentration reduction factor (PCRF) and the PNC for the linearity and the cut-off size. However, there are concerns that the PN measurement systems can drift significantly over this period of time, raising concerns regarding the validity of the previous measurements, especially if the yearly validation fails.
Journal Article

Sampling of Non-Volatile Vehicle Exhaust Particles: A Simplified Guide

2012-04-16
2012-01-0443
Recently, a particle number (PN) limit was introduced in the European light-duty vehicles legislation. The legislation requires measurement of PN, and particulate mass (PM), from the full dilution tunnel with constant volume sampling (CVS). Furthermore, PN measurements will be introduced in the next stage of the European Heavy-Duty regulation. Heavy-duty engine certification can be done either from the CVS or from a partial flow dilution system (PFDS). For research and development purposes, though, measurements are often conducted from the raw exhaust, thereby avoiding the high installation costs of CVS and PFDS. Although for legislative measurements requirements exist regarding sampling and transport of the aerosol sample, such requirements do not necessarily apply for raw exhaust measurements. Thus, measurement differences are often observed depending on where in the experimental set up sampling occurs.
Journal Article

Overview of Soot Emission Measurements Instrumentation: From Smoke and Filter Mass to Particle Number

2013-03-25
2013-01-0138
Particulate emissions cause adverse health effects and for this reason they are regulated since the 80s. Vehicle regulations cover particulate emission measurements of a model before its sale, known as type approval or homologation. For heavy-duty engines the emissions are measured on an engine dynamometer with steady state points and transient cycles. For light-duty vehicles (i.e. the full power train) the particulate emissions are assessed on a chassis dynamometer. The measurement of particulate emissions is conducted either by diluting the whole exhaust in a dilution tunnel with constant volume sampling or by extracting a small proportional part of the exhaust gas and diluting it. Particulate emissions are measured by passing part of the diluted exhaust aerosol through a filter paper. The increase of the weight of the filter is used to calculate the particulate matter mass (PM) emissions.
Journal Article

Application of the Pegasor Particle Sensor for the Measurement of Mass and Particle Number Emissions

2013-04-08
2013-01-1561
The Pegasor Particle Sensor (PPS) is a small and lightweight sensor that can be used directly in raw exhaust to provide the mass and number concentration of exhaust aerosol. Its operation principle is based on the electrical charging of exhaust aerosol and determination of particle concentration by measuring the charge accumulated on the particles. In this paper we have applied the PPS in a variety of vehicle exhaust configurations to evaluate its performance characteristics. First, the output signal of the instrument was calibrated with diesel exhaust to deliver either the mass or the number concentration of exhaust aerosol. Linear response with the soot mass concentration measured by a Photo Acoustic Soot Sensor and number concentration measured by an Electrical Low Pressure Impactor was established.
Journal Article

Use of a Catalytic Stripper as an Alternative to the Original PMP Measurement Protocol

2013-04-08
2013-01-1563
The Particle Measurement Programme (PMP) developed an exhaust particle number measurement protocol that has been adopted by current light duty vehicle emission regulations in Europe. This includes thermal treatment of the exhaust aerosol to isolate solid particles only and a number counting device with a lower cutpoint of 23 nm to avoid measurement of smaller particles that may affect the repeatability of the measurement. In this paper, we examine a potential alternative to the PMP system, where the thermal treatment is replaced by a catalytic stripper (CS). This offers oxidation and not just evaporation of the volatile components. Alternative sampling systems, either fulfilling the PMP recommendations or utilizing a CS, have been explored in terms of their volatile particle removal efficiency. Tests have been conducted on diesel exhaust, diesel equipped with DPF and gasoline direct injection emissions.
Journal Article

Engine Exhaust Solid Sub-23 nm Particles: I. Literature Survey

2014-10-13
2014-01-2834
In the current diesel vehicle exhaust emissions legislation Particle Number (PN) limits for solid particles >23 nm are prescribed. The legislation was extended to include Gasoline Direct Injection (G-DI) vehicles since September 2014. Target of this paper was to investigate whether smaller than 23 nm solid particles are emitted from engines in considerable concentration focusing on G-DI engines. The literature survey and the experimental investigation of >15 vehicles showed that engines emit solid sub-23 nm particles. The average percentage over a test cycle for G-DIs (30-40%) is similar to diesel engines. These percentages are relatively low considering the emission limit levels (6×1011 p/km) and the repeatability (10-20%) of the particle number method. These percentages are slightly higher compared to the percentages expected theoretically not to be counted due to the 23 nm cut-off size (5-15%).
Journal Article

Engine Exhaust Solid Sub-23 nm Particles: II. Feasibility Study for Particle Number Measurement Systems

2014-10-13
2014-01-2832
In the current heavy-duty engine and light-duty diesel vehicle exhaust emission legislation Particle Number (PN) limits for solid particles >23 nm are prescribed. The legislation was extended to include Gasoline Direct Injection (G-DI) vehicles since September 2014 and will be applied to Non-Road Mobile Machinery engines in the future. However there are concerns transferring the same methodology to other engine technologies, where higher concentration of sub-23 nm particles might exist. This paper focuses on the capabilities of existing PN measurement equipment on measuring solid particles smaller than 23 nm.
Journal Article

Impact of FAME Content on the Regeneration Frequency of Diesel Particulate Filters (DPFs)

2014-04-01
2014-01-1605
Modern diesel vehicles utilize two technologies, one fuel based and one hardware based, that have been motivated by recent European legislation: diesel fuel blends containing Fatty Acid Methyl Esters (FAME) and Diesel Particulate Filters (DPF). Oxygenates, like FAME, are known to reduce PM formation in the combustion chamber and reduce the amount of soot that must be filtered from the engine exhaust by the DPF. This effect is also expected to lengthen the time between DPF regenerations and reduce the fuel consumption penalty that is associated with soot loading and regeneration. This study investigated the effect of FAME content, up to 50% v/v (B50), in diesel fuel on the DPF regeneration frequency by repeatedly running a Euro 5 multi-cylinder bench engine over the European regulatory cycle (NEDC) until a specified soot loading limit had been reached.
Journal Article

A Miniature Catalytic Stripper for Particles Less Than 23 Nanometers

2013-04-08
2013-01-1570
The European Emissions Stage 5b standard for diesel passenger cars regulates particulate matter to 0.0045 g/km and non-volatile part/km greater than 23 nm size to 6.0x10₁₁ as determined by the PMP procedure that uses a heated evaporation tube to remove semi-volatile material. Measurement artifacts associated with the evaporation tube technique prevents reliable extension of the method to a lower size range. Catalytic stripper (CS) technology removes possible sources of these artifacts by effectively removing all hydrocarbons and sulfuric acid in the gas phase in order to avoid any chemical reactions or re-nucleation that may cause measurement complications. The performance of a miniature CS was evaluated and experimental results showed solid particle penetration was 50% at 10.5 nm. The sulfate storage capacity integrated into the CS enabled it to chemically remove sulfuric acid vapor rather than rely on dilution to prevent nucleation.
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