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A newly-developed time resolved exhaust gas analysis system was utilized in this study. The hydrocarbon compositions upstream and downstream of the catalytic converter were investigated during cold start and warm up of the Federal Test Procedure(FTP), with three fuels of different aromatic contents. Although engine-out hydrocarbon emissions had high concentrations right after cold start, the specific reactivity was low. This can be explained by the selective adsorption of the high boiling point components which had a high Maximum Incremental Reactivity (MIR) in the intake manifold and engine-oil films. Thereafter, the high boiling point components were desorbed rapidly and consequently specific reactivity increased. Hydrocarbon adsorption of high boiling point components and hydrocarbon conversion of low boiling point components occurred simultaneously on the catalyst during warm up.

The application of emulsified fuel for diesel engines is expected to reduce NOx and soot simultaneously. The purpose of this study is to clarify the influence of water content in emulsified fuel and fuel injection timing on diesel engine performance. The engine performance of emulsified fuel was compared with the water injection method. In the water injection test, water was injected to intake manifold and diesel fuel was directly injected into combustion chamber. Two emulsified fuels of which mixing ratio of water and emulsifier to diesel fuel were 15 and 30 vol.% were tested. Engine performance and exhaust gas emission of water injection method were almost similar to those of diesel fuel, so that water presented in combustion chamber had almost no influence on engine performance. Therefore, it can be considered that the micro explosion of fuel droplet enhanced the fuel atomization and mixing of fuel and air.