Search Results

Selective Catalytic Reduction (SCR) catalysts have been designed to reduce NOx with the assistance of an ammonia-based reductant. Diesel Particulate Filters (DPF) have been designed to trap and eventually oxidize particulate matter (PM). Combining the SCR function within the wall of a high porosity particulate filter substrate has the potential to reduce the overall complexity of the aftertreatment system while maintaining the required NOx and PM performance. The concept, termed Selective Catalytic Reduction Filter (SCRF) was studied using a synthetic gas bench to determine the NOx conversion robustness from soot, coke, and hydrocarbon deposition. Soot deposition, coke derived from propylene exposure, and coke derived from diesel fuel exposure negatively affected the NOx conversion. The type of soot and/or coke responsible for the inhibited NOx conversion did not contribute to the SCRF backpressure.

A 2005 prototype diesel aftertreatment system consisting of diesel oxidation catalysts (DOC), Cu/zeolite Selective Catalytic Reduction (SCR) catalyst, and Catalyzed Diesel Particulate Filter (CDPF) was aged to an equivalent of 120k mi on an engine dynamometer using an aging cycle that incorporated both city and highway driving modes. The program demonstrated durable reduction in particulate matter (PM) and nitrogen oxides (NOx) emissions to federal Tier 2 levels on a 6000 lbs light-duty truck application. Very low sulfur diesel fuel (∼15 ppm) enabled lower PM emissions, reduced the fuel penalty associated with the emission control system, and improved long-term system durability. A total of 643 filter regenerations occurred during the aging that raised the entire catalyst system to high temperatures on a regular basis. After testing the aged system on a 6000 lbs light-duty diesel truck, a post mortem analysis was completed on core samples taken from the DOC, SCR catalyst, and filter.

Operation of flex fuel vehicles requires operation with a range of fuel properties. The significant differences in the heat of vaporization and energy density of E0-E100 fuels and the effect on spray development need to be fully comprehended when developing engine control strategies. Limited enthalpy for fuel vaporization needs to be accounted for when developing injection strategies for cold start, homogeneous and stratified operation. Spray imaging of multi-hole gasoline injectors with fuels ranging from E0 to E100 and environmental conditions that represent engine operating points from ambient cold start to hot conditions was performed in a spray chamber. Schlieren visualization technique was used to characterize the sprays and the results were compared with Laser Mie scattering and Back-lighting technique. Open chamber experiments were utilized to provide input and validation of a CFD model.

In present GDI engines, multiple injection strategies are often employed for engine cold start mixture formation. In the future, these strategies may also be used to control the combustion process, and to prevent misfiring or high emission levels. While the processes occurring during individual injections of GDI injectors have been investigated by a number of researchers, this paper concentrates on the interactions of multiple injection events. Even though multiple injection strategies are already applied in most GDI engines, the impact of the first injection event on the second injection event has not been analyzed in detail yet. Different optical measurement techniques are used in order to investigate the interaction of the two closely timed injection events, as well as the effect of dwell time and the in-cylinder conditions. The injector investigated is a GDI piezo injector with an outwardly opening needle.

Effects of fuel cell material properties on water management were numerically investigated using Volume of Fluid (VOF) method in the FLUENT. The results show that the channel surface wettability is an important design variable for both serpentine and interdigitated flow channel configurations. In a serpentine air flow channel, hydrophilic surfaces could benefit the reactant transport to reaction sites by facilitating water transport along channel edges or on channel surfaces; however, the hydrophilic surfaces would also introduce significantly pressure drop as a penalty. For interdigitated air flow channel design, it is observable that liquid water exists only in the outlet channel; it is also observable that water distribution inside GDL is uneven due to the pressure distribution caused by interdigitated structure. An in-situ water measurement method, neutron imaging technique, was used to investigate the water behavior in a PEM fuel cell.

Lithium-ion polymer battery has been widely used for vehicle onboard electric energy storage ranging from 12V SLI (Starting, Lighting, and Ignition), 48V mild hybrid electric, to 300V battery electric vehicle. Formulation on cell parameters acquired from minimum numbers of experiments, the modeling and simulation could be an effective approach in predicting battery performance, thermal effectiveness, and degradation. This paper describes the modeling, simulation, and validation of Lithium-Nickel-Manganese-Cobalt-Oxide (LiNiMnCoO2) based cell with 3.6V nominal voltage and 20Ah capacity. Constant current 20A, 40A, 60A, and 80A discharge tests are conducted in the computer-controlled cycler and temperature chamber. Discharging voltage curves and cell surface temperature distributions are recorded in each discharging test. A three-dimensional cell model is constructed in the COMSOL multi-physics platform based on the cell parameters.

The purpose of this work was to examine gasoline particle filters (GPFs) at high mileages. Soot levels for gasoline direct injection (GDI) engines are much lower than diesel engines; however, noncombustible material (ash) can cause increased backpressure, reduced power, and lower fuel economy. In this study, a post mortem was completed of two GPFs, one at 130,000 mi and the other at 150,000 mi, from two production 3.5L turbocharged GDI vehicles. The GPFs were ceramic wall-flow filters containing three-way catalytic washcoat and located downstream of conventional three-way catalysts. The oil consumption was measured to be approaching 23,000 mpqt for one vehicle and 30,000 mpqt for the other. The ash contained Ca, P, Zn, S, Fe, and catalytic washcoat. Approximately 50 wt% of the collected ash was non-lubricant derived. The filter capture efficiency of lubricant-derived ash was about 50% and the non-lubricant metal (mostly Fe) deposition rate was 0.9 to 1.2 g per 10,000 mi.

To meet future particle mass and particle number standards, gasoline vehicles may require particle control, either by way of an exhaust gas filter and/or engine modifications. Soot levels for gasoline engines are much lower than diesel engines; however, non-combustible material (ash) will be collected that can potentially cause increased backpressure, reduced power, and lower fuel economy. The purpose of this work was to examine the ash loading of gasoline particle filters (GPFs) during rapid aging cycles and at real time low mileages, and compare the filter performances to both fresh and very high mileage filters. Current rapid aging cycles for gasoline exhaust systems are designed to degrade the three-way catalyst washcoat both hydrothermally and chemically to represent full useful life catalysts. The ash generated during rapid aging was low in quantity although similar in quality to real time ash. Filters were also examined after a low mileage break-in of approximately 3000 km.

Passenger and light duty diesel vehicles will require up to 90% NOx conversion over the Federal Test Procedure (FTP) to meet future Tier 2 Bin 5 standards. This accomplishment is especially challenging for low exhaust temperature applications that mostly operate in the 200 - 350°C temperature regime. Selective catalytic reduction (SCR) catalysts formulated with Cu/zeolites have shown the potential to deliver this level of performance fresh, but their performance can easily deteriorate over time as a result of high temperature thermal deactivation. These high temperature SCR deactivation modes are unavoidable due to the requirements necessary to actively regenerate diesel particulate filters and purge SCRs from sulfur and hydrocarbon contamination. Careful vehicle temperature control of these events is necessary to prevent unintentional thermal damage but not always possible. As a result, there is a need to develop thermally robust SCR catalysts.

It is well know that the internal flow field and nozzle geometry affected the spray behavior, but without high-speed microscopic visualization, it is difficult to characterize the spray structure in details. Single-hole diesel injectors have been used in fundamental spray research, while most direct-injection engines use multi-hole nozzle to tailor to the combustion chamber geometry. Recent engine trends also use smaller orifice and higher injection pressure. This paper discussed the quasi-steady near-nozzle diesel spray structures of an axisymmetric single-hole nozzle and a symmetric two-hole nozzle configuration, with a nominal nozzle size of 130 μm, and an attempt to correlate the observed structure to the internal flow structure using computational fluid dynamic (CFD) simulation. The test conditions include variation of injection pressure from 30 to 100 MPa, using both diesel and biodiesel fuels, under atmospheric condition.

In this paper, an Electronic Control System (ECS) is designed to manage a 125 cc single-cylinder air-cooled motorcycle engine. The aim of this study was to accomplish low cost, high reliability and mainly meet the motorcycle engine emission standard of China Stage III. The intake port fuel injection mode was chosen with a redesigned part of intake pipe. Gathering information of speed, throttle position (TP), inlet temperature and pressure, cylinder temperature, switch-type exhaust gas oxygen sensor and the battery voltage, an Engine Control Unit (ECU) was devised to calculate fuel injecting pulse width, advance ignition angle and control the working conditions of the fuel pump and the exhaust gas oxygen sensor. Additionally, a three-way catalytic converter (TWC) was used to reduce exhaust gas emissions.

The improvement of spray atomization and penetration characteristics of GDI multi-hole injector sprays is a major component of the engine combustion developments, in order to achieve the fuel economy and emissions standards. Significant R&D efforts are directed towards optimization of the nozzle designs, in order to achieve optimum multi-objective spray characteristics. The Volume-of-Fluid Large-Eddy-Simulation (VOF-LES) of the injector internal flow and spray break-up processes offers a computational capability to aid development of a fundamental knowledge of the liquid jet breakup process. It is a unique simulation method capable of simultaneous analysis of the injector nozzle internal flow and the near-field jet breakup process. Hence it provides a powerful toll to investigate the influence of nozzle design parameters on the spray geometric and atomization features and, consequently, reduces reliance on hardware trial-and-tests for multi-objective spray optimizations.

Surrogates for JP-8 have been developed in the high temperature gas phase environment of gas turbines. In diesel engines, the fuel is introduced in the liquid phase where volatility plays a major role in the formation of the combustible mixture and autoignition reactions that occur at relatively lower temperatures. In this paper, the role of volatility on the combustion of JP-8 and five different surrogate fuels was investigated in the constant volume combustion chamber of the Ignition Quality Tester (IQT). IQT is used to determine the derived cetane number (DCN) of diesel engine fuels according to ASTM D6890. The surrogate fuels were formulated such that their DCNs matched that of JP-8, but with different volatilities. Tests were conducted to investigate the effect of volatility on the autoignition and combustion characteristics of the surrogates using a detailed analysis of the rate of heat release immediately after the start of injection.

Experiments were conducted on a single cylinder engine to measure the ionization current across the spark plug electrodes as a function of key operating parameters including air/fuel ratio. A unique ignition circuit was adapted to measure the ion current as early as 300 microseconds after the initiation of spark discharge. A strong relationship between air/fuel ratio and features of the measured ion current was observed. This relationship can be exploited via relatively simple algorithms in a wide range of electronic engine control strategies. Measurements of spark plug ion current for approximating air/fuel ratio may be especially useful for use with low cost mixture control in small engine applications. Cylinder-to-cylinder mixture balancing in conjunction with a global exhaust gas oxygen sensor is another promising application of spark plug ion current measurement.

Gasoline direct injection (GDI) has the potential to greatly improve internal combustion engine performance through precise control of the injection rate, timing, and combustion of the fuel. A thorough characterization of the hydrodynamics of fuel injection has to come from a precise, quantitative analysis of the sprays, especially in the near-nozzle region. A lack of knowledge of the fuel-spray dynamics has severely limited computational modeling of the sprays and design of improved injection systems. Previously, the structure and dynamics of highly transient fuel sprays have never been visualized or reconstructed in three dimensions (3D) due to numerous technical difficulties. By using an ultrafast x-ray detector and intense monochromatic x-ray beams from synchrotron radiation, the fine structures and dynamics of 1-ms GDI fuel sprays from an outwardly opening nozzle were elucidated by a newly developed, ultrafast, microsecond computed microtomography (CT) technique.

Present knowledge of the velocity of the fuel in diesel sprays is quite limited due to the obscuring effects of fuel droplets, particularly in the high-density core of the spray. In recent years, x-ray radiography, which is capable of penetrating dense fuel sprays, has demonstrated the ability to probe the structure of the core of the spray, even in the dense near-nozzle region. In this paper, x-ray radiography data was used to determine the average axial velocity in diesel sprays as a function of position and time. Here, we report the method used to determine the axial velocity and its application to three common-rail diesel sprays at 250 bar injection pressure. The data show that the spray velocity does not reach its steady state value near the nozzle until approximately 200 μs after the start of injection. Moreover, the spray axial velocity decreases as one moves away from the spray orifice, suggesting transfer of axial momentum to the surrounding ambient gas.

This paper presents the development of an analytical model that complements laboratory based experiments to provide a tool for Selective Catalyst Reduction (SCR) applications. The model calibration is based on measured data from NOx reduction performance tests as well as ammonia (NH3) adsorption/desorption tests over select SCR catalyst formulations in a laboratory flow reactor. Only base metal/zeolite SCR samples were evaluated. Limited validations are presented that show the model agrees well with vehicle data from Environmental Protection Agency Federal Test Procedure (EPA FTP) emission assessments. The model includes energy and mass balances, several different NH3 reactions with NOx, NH3 adsorption and desorption algorithms, and NH3 oxidation.

The use of urea-based selective catalytic reduction (SCR) is a promising method for achieving U.S. Tier 2 diesel emission standards for NOx. To meet the Tier 2 standards for Particulate Matter (PM), a catalyzed diesel particulate filter (CDPF) will likely be present and any ammonia (NH3) that is not consumed over an SCR catalyst would pass over the CDPF to make nitrous oxide (N2O) emissions and/or oxides of nitrogen (NOx), or exit the exhaust system as NH3. N2O is undesirable due to its high greenhouse gas potential, while NOx production from the slipped NH3 would reduce overall system NOx conversion efficiency. This paper reviews certain conditions where NH3 slip past an SCR system may be a concern, looks at what would happen to this slipped NH3 over a CDPF, and evaluates the performance of various supplier NH3 slip catalysts under varied space velocities, temperatures and concentrations of NH3 and NOx.

This paper presents a study of urea SCR catalyst aging characteristics and implementation into an analytical model that complements laboratory based experiments for a dynamometer-aged SCR brick. The model calibration is based on measured data taken from a 120k-mile simulated dynamometer-aged base metal/zeolite SCR. Dynamometer aging led to non-uniform axial deterioration with more severe deactivation toward the front of the SCR brick compared to the rear. Data from a 120k-mile simulated hydrothermally oven-aged SCR (uniform axial aging) is used to establish baseline aged NOx performance and NH3 adsorption/desorption behavior. An axial deterioration factor is applied to the baseline model to account for differences between oven and dynamometer aging. The model is exercised using engine out vehicle data to examine how different aging processes (oven vs. dynamometer) affect overall NOx performance during the EPA FTP (Environmental Protection Agency Federal Test Procedure).

Urea-based Selective Catalytic Reduction (SCR) has the potential to meet U.S. Diesel Tier 2 Bin 5 emission standards for NOx in 2010. The operating and driving conditions of light-duty and heavy-duty vehicles make it necessary to customize catalyst features to the application. This paper reviews the selection of SCR catalyst technology for the U.S. and the appropriate aging and poisoning protocols for current supplier SCR catalysts. Generally, light-duty applications require SCR catalysts to function well at low temperature whereas heavy-duty applications require functionality at high temperature and high space velocity. One main durability requirement of SCR formulations involves withstanding the high temperature process of regenerating particulate filters from accumulated soot. Unrefined engine exhaust temperature control coupled with the inexact temperature measurement may also expose SCR catalysts to additional over-temperature conditions.