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Recent developments in diesel fuel injection equipment coupled with moves to using ULSD and biodiesel blends has seen an increase in the number of reports, from both engine manufacturers and fleet operators, regarding fuel system deposit issues. Preliminary work performed to characterise these deposits showed them to be complicated mixtures, predominantly carbon like but also containing other possible carbon precursor materials. This paper describes the application of the combination of hydropyrolysis, gas chromatography and mass spectrometry to the analysis of these deposits. It also discusses the insights that such analysis can bring to the constitution and origin of these deposits.

This work investigates the effect of a multifunctional diesel fuel additive package used with RapeSeed Oil (RSO) as a fuel in a DI heavy duty diesel engine. The effects on fuel injectors’ cleanliness were assessed. The aim was to maintain combustion performance and preventing the deterioration of exhaust emissions associated with injector deposit build up. Two scenarios were investigated: the effect of deposit clean-up by a high dose of the additive package; and the effect of deposit prevention using a moderate dose of the additive package. Engine combustion performance and emissions were compared for each case against use of RSO without any additive. The engine used was a 6 cylinder, turbocharged, intercooled Perkins Phaser Engine, fitted with an oxidation catalyst and meeting the Euro II emissions limits. The tests were conducted under steady state conditions of 23kW and 47kW power output at an engine speed of 1500 rpm.

The fuel injection equipment (FIE) has always been paramount to the performance of the Diesel engine. Increasingly stringent emissions regulations have dictated that the FIE becomes more precise and sophisticated. The latest generation FIE is therefore less tolerant to deposit formation than its less finely engineered predecessors. However, the latest emissions regulations make it increasingly difficult for engine manufacturers to comply without the use of exhaust aftertreatment. This aftertreatment often relies on catalytic processes that can be impaired by non-CHON (carbon, hydrogen, oxygen and nitrogen) components within the fuel. Fuel producers have therefore also been obliged to make major changes to try and ensure that with the latest technology engines and aftertreatment systems the fuel is still fit for purpose. However, there has recently been a significant increase in the incidence of reported problems due to deposit build-up within vehicle fuel systems.

Many diesel engines have to work at load profiles which, due to the low exhaust gas temperatures, necessitate active regeneration procedures to ensure continued engine operation and the reliability of the particulate filter. An active regeneration may be initiated via inner engine measures such as late injection. However, due to high maintenance interval and run time requirements for non-road applications the combustion of soot accumulated in the diesel particulate filter (DPF) often is realized via downstream processes. Known methods for this purpose are burner systems, systems based on downstream hydrocarbon injection (HCI) and subsequent hydrocarbon (HC)-conversion due to a catalyst or a combination of both. This paper describes an autarkic system using two-stage electro-thermal-supported hydrocarbon conversion. This system is capable to regenerate a DPF within the entire engine operating range and it is less complex than flame burner systems.

Internal deposits formed within the fuel injection system have been widely reported in the literature. Several root causes exist, with many deposits consisting of more than one material. The final chemistry depends on the availability of trace fuel contaminants and additives and to a lesser extent hydrocarbon/FAME stability and operating conditions. The present paper identifies the primary deposit morphologies, along with the typical root cause. Metal carboxylate salts, also known as metal soaps are most widely reported and are easily recreated under controlled conditions using compounds present at trace concentrations in some market fuels. The salting reaction may occur at low temperatures in the fuel supply system. It is proposed that the resulting fuel insoluble salt molecules are transported as reverse micelles, occasionally plugging filters but more commonly passing to the high pressure injection system.

Full flow particulate filters are a state of the art solution for many serial production diesel engine applications. They are very effective for removing ≻ 90% of particulate mass and ≻ 99% of the particulate number from the exhaust gas of diesel engines. Many diesel engines have to work at load profiles which necessitate active regeneration procedures to ensure continued engine operation and the reliability of the full flow particulate filter. Passive regeneration via NO₂, as a cost-effective solution, cannot be used as the sole method for all applications, due to restrictions such as, insufficient engine-out NOX/PM ratio, low exhaust gas temperature level or occasionally poor fuel quality. To meet the Tier 4 emission legislation casually partial flow particulate filters enable sufficient particulate reduction at boundary conditions where full flow DPF is not applicable.

Traditionally, diesel fuel injection equipment (FIE) has frequently relied on the diesel fuel to lubricate the moving parts. When ultra low sulphur diesel fuel was first introduced into some European markets in the early 1980's it rapidly became apparent that the process of removing the sulphur also removed other components that had bestowed the lubricating properties of the diesel fuel. Diesel fuel pump failures became prevalent. The fuel additive industry responded quickly and diesel fuel lubricity additives were introduced to the market. The fuel, additive and FIE industries expended much time and effort to develop test methods and standards to try and ensure this problem was not repeated. Despite this, there have recently been reports of fuel reaching the end user with lubricating performance below the accepted standards.

The need for improved emissions and fuel economy are placing increasingly severe performance requirements on compression ignition engines. These are satisfied in part by advanced fuel injection equipment that provide multiple injections and increased injection pressures along with higher operating temperature. Fuel composition is also changing, with increased use of non-traditional feedstocks combined with a range of additive chemistries to restore or enhance fuel quality. Within this environment, a number of worldwide automotive companies have noted a trend towards increased Internal Injector Deposits (IID). Little quantitative information to understand the root cause is available, largely due to difficulty in reproducing the issue under controlled conditions. The present study details the results of an accelerated test methodology, which is used to evaluate the interrelated effects of fuel composition and operating environment.

Current developments in fuels and emissions regulations are resulting in an increasingly severe operating environment for diesel fuel injection systems. The formation of deposits within the holes or on the outside of the injector nozzle can affect the overall system performance. The rate of deposit formation is affected by a number of parameters, including operating conditions and fuel composition. For the work reported here an accelerated test procedure was developed to evaluate the relative importance of some of these parameters in a high pressure common rail fuel injection system. The resulting methodology produced measurable deposits in a custom-made injector nozzle on a single-cylinder engine. The results indicate that fuels containing 30%v/v and 100% Fatty Acid Methyl Ester (FAME) that does not meet EN 14214 produced more deposit than an EN590 petroleum diesel fuel.

For the regeneration of diesel particulate filters with oxygen, temperatures above 550°C are normally required. The increase of the exhaust gas temperature to temperatures above 500°C demands a large amount of energy, so that strategies to reduce the regeneration temperature have to be considered. One option is the injection of a catalyst, which reduces the required regeneration temperature. Hence, a system was developed at HJS Emission Technology GmbH to inject catalyst-precursor into the exhaust gas pipe, whereby the catalysts are generated due to decomposition of the precursor in the hot exhaust gas. A technique based on the calculation of apparent activation energies was developed to characterize the soot combustion on the filter. In the first step metal oxide catalysts, like cerium(IV)oxide, manganese-oxide and iron(III)oxide were investigated after injection of their nitrate precursors dissolved in water.

With growing concern over greenhouse gases there is increasing emphasis on reducing CO2 emissions. Despite engine efficiency improvements plus increased dieselisation of the fleet, increasing vehicle numbers results in increasing CO2 emissions. To reverse this trend the fuel source must be changed to renewable fuels which are CO2 neutral. A common route towards this goal is to substitute diesel fuel with esterified seed oils, collectively known as Fatty Acid Methyl Esters. However a fundamental change to the fuel chemistry produces new challenges in ensuring compatibility between fuel and engine performance/durability. This paper discusses the global situation and shows how fuel additives can overcome the challenges presented by the use of biodiesel.

Exhaust emissions legislation for diesel engines generally limits only the mass of emitted particulate matter. This limitation reflects the concerns and measurement technology at the time the legislation was drafted. However, evolving diesel particulate filter (DPF) systems offer the potential for reductions in the mass and more importantly, the number of particles emitted from diesel exhausts. Particulate filters require frequent cleaning or regeneration of accumulated soot, if the engine is to continue to operate satisfactorily. Exothermic reactions during regeneration can lead to severe thermal gradients in the filter system resulting in damage. Fuel additives have been evaluated to show significant reductions in light off temperature which allow frequent small regeneration events to occur, under mild operating conditions.

Recent developments in diesel engines and fuel injection equipment combined with the change to ULSD and bio-blends have resulted in increased reports regarding deposits within injectors and filters. A review of known fuel degradation mechanisms and other relevant chemistries suggests the effects of high pressure and high shear environments should be examined as the most probable causes of increasing deposit formation. Existing fuel quality tests do not correlate with reported fouling propensity. Analytical studies have shown that there are only subtle chemical changes for the materials within the standard diesel boiling range. The implications for further scientific study are discussed.

The operating cycle of many vehicles fitted with diesel particulate filters is such that soot accumulates within the filter and must periodically be oxidised. Work was carried out on a passenger car engine to elucidate how fuel borne catalyst (FBC) to soot ratio, oxygen mass flow rate, temperature and soot loading influence the oxidation rate of soot accumulated in a sintered metal filter (SMF). Results show that soot loading had a major influence; increased soot loading increased the oxidation rate. The other parameter had a smaller influence with increasing oxygen flow rate and FBC/soot ratio each increasing the oxidation rate.

Current developments in fuels and emissions regulations are resulting in increasingly severe operating environment for the injection system. Formation of deposits within the holes of the injector nozzle or on the outside of the injector tip may have an adverse effect on overall system performance. This paper provides a critical review of the current understanding of the main factors affecting deposit formation. Two main types of engine test cycles, which attempt to simulate field conditions, are described in the literature. The first type involves cycling between high and low load. The second involves steady state operation at constant speed either at medium or high load. A number of influences on the creation of deposits are identified. This includes fouling through thermal condensation and cracking reactions at nozzle temperatures of around 300°C. Also the design of the injector holes is an influence, because it can influence cavitation.

An increasing range of conventional and unconventional feed stocks will be used to produce fuel of varying chemical and physical properties for use in compression ignition engines. Fischer-Tropsh (F-T) technology can be used to produce fuels of consistent quality from a wide range of feed stocks. The present study evaluates the performance of F-T fuel in advanced common rail fuel injection systems. Laboratory scale tests are combined with proprietary engine and electrically driven common rail pump hydraulic rig tests to predict long-term performance. The results obtained indicate that the performance of F-T fuel is at least comparable to conventional hydrocarbon fuels and superior in a number of areas. In particular, the lubricity of F-T fuel was improved by addition of lubricity additives or FAME, with minimal wear under a wide range of operating conditions and temperatures.

Diesel particulate filters (DPF), in conjunction with fuel borne catalysts (FBC) to facilitate regeneration, are now an accepted technology for passenger car application. Retrofitting of such systems has demonstrated the possibility of applying this technology to heavy-duty vehicles. To demonstrate the efficacy of DPF/FBC systems and to assess their affect on engine durability and economy, five heavy-duty trucks were fitted with DPF/FBC systems. After the completion of over ¼ million kms four trucks underwent a full engine strip-down and rating. This paper briefly reviews the installation of the systems and their effect on the regulated emissions, present details of the mileage accumulation and of the engine strip-downs. The conclusions drawn are that after a ¼ million km of use with the DPF/FBC systems the trucks had not suffered any abnormal deterioration and in fact there was some indication of reduced wear on the engine.

In view of increasing concern over diesel particulates and tightening legislation to control their emission, much work has been done to develop diesel particulate filters (DPFs) and systems to allow them to work reliably. Although a filter will effectively trap solid particles, any material in the vapour phase, such as unburned hydrocarbons, may pass through the filter and subsequently condense. The use of a catalytic wash coat, either on the DPF itself or on a separate substrate, has been proposed to oxidise these hydrocarbons and thus reduce the total material emitted. The use of fuel borne catalysts to aid the regeneration of trapped material within the DPF is also well documented. Such catalyst will also catalyse the oxidation of any hydrocarbons bound up within the particulate. The oxidation of such hydrocarbon occurs at a lower temperature than that of carbon itself, thus allowing lower temperature regeneration of the DPF.

Diesel particulate filter (DPF) technology is becoming increasingly established as a practical method for control of particulate emissions from diesel engines. In the year 2000, production vehicles with DPF systems, using metallic fuel additive to assist regeneration, became available in Europe. These early examples of first generation DPF technology are forerunners of more advanced systems likely to be needed by many light-duty vehicles to meet Euro IV emissions legislation scheduled for 2005. Aspects requiring attention in second generation DPF systems are a compromise between regeneration kinetics and ash accumulation. The DPF regeneration event is activated by fuel injection, either late in the combustion cycle (late injection), or after normal combustion (post injection), leading to increased fuel consumption. Therefore for optimum fuel economy, the duration of regeneration and/or the soot ignition temperature must be minimised.

In an attempt to improve ambient air quality, retrofit programmes have been encouraged; targeting reductions in PM emissions by means of diesel particulate filters (DPFs). However depending on the DPF design and operating conditions increased nitrogen dioxide (NO2) emissions have been observed, which is causing concern. Previous work showed that retrofitting a DPF system employing a fuel borne catalyst (FBC) to facilitate regeneration, reduced NO2 emissions. This paper outlines the investigation of a base metal coated DPF to enhance the reduction of NO2. Such a DPF system has been fitted to older technology buses and has demonstrated reliable field performance.