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A step in the development of advanced regenerative life support systems is to produce simulation models to guide experimentation and hardware development. This paper discuses the development of detailed simulation models of water reclamation processors using the ASPEN PLUS™ simulation program. Individual models have been developed for Vapor Compression Distillation (VCD), Vapor Phase Catalytic Ammonia Removal (VPCAR) and Supercritical Water Oxidation (SCWO). This paper outlines the methodology which is used to complete this work and discusses the insights which are gained by this type of model development. A discussion of how modeling predictions are used to direct future work in modeling and experimentation is also presented. The initial set of modeled processors were VCD, VPCAR, and SCWO. Future work will cover the modeling of other processors. These models will be linked to form subsystem level models, and evaluations will be performed on various configurations.

The sorption and ion exchange water reclamation technologies used to treat the waste streams in the Environmental Control and Life Support System (ECLSS) and Process Materials Management System (PMMS) are ineffective for removal of low molecular weight, polar organic contaminants which do not have ionized forms. These include likely waste stream constituents such as methanol, ethanol, isopropanol, and acetone. Catalytic oxidation of these compounds in oxygen saturated water at moderate temperatures (125 to 160 C) provides a reliable, simple, and inexpensive way to eliminate these contaminants. By the suitable choice of catalysts, these species can be converted to carbon dioxide and water or to species which can be removed effectively by sorbents and ion exchange resins. The operation requirements of the baseline system are oxygen and heat. Since much of the heat is recovered, the energy use of the technology is very low.

Waste management is a vital function of spacecraft life support systems as it is necessary to meet crew health and safety and quality of life requirements. Depending on the specific mission requirements, waste management operations can include waste collection, segregation, containment, processing, storage and disposal. For the Crew Exploration Vehicle (CEV), addressing volume and mass constraints is paramount. Reducing the volume of trash prior to storage is a viable means to recover habitable volume, and is therefore a particularly desirable waste management function to implement in the CEV, and potentially in other spacecraft as well. Research is currently being performed at NASA Ames Research Center to develop waste compaction systems that can provide both volume and mass savings for the CEV and other missions.

A Microwave Enhanced Solid Waste Freeze Drying Prototype system has been developed for the treatment of solid waste materials generated during extended manned space missions. The system recovers water initially contained within wastes and stabilizes the residue with respect to microbial growth. Dry waste may then be safely stored or passed on to the next waste treatment process. Operating under vacuum, microwave power provides the energy necessary for sublimation of ice contained within the waste. This water vapor is subsequently collected as relatively pure ice on a Peltier thermoelectric condenser as it travels en route to the vacuum pump. In addition to stabilization via dehydration, microwave enhanced Freeze Drying reduces the microbial population (∼90%) in the waste.

The on-demand production of Medical Grade Water (MGW) is a critical biomedical requirement for future long-duration exploration missions. Potentially, large volumes of MGW may be needed to treat burn victims, with lesser amounts required to reconstitute pharmacological agents for medical preparations and biological experiments, and to formulate parenteral fluids during medical treatment. Storage of MGW is an untenable means to meet this requirement, as are nominal MGW production methods, which use a complex set of processes to remove chemical contaminants, inactivate all microorganisms, and eliminate endotoxins, a toxin originating from gram-negative bacteria cell walls. An innovative microgravity compatible alternative, using a microwave-based MGW generator, is described in this paper. The MGW generator efficiently couples microwaves to a single-phase flowing stream, resulting in super-autoclave temperatures.

The inedible portion of plant biomass in closed regenerative life support systems must be reprocessed producing recyclable by-products such as carbon dioxide, sugars, and other useful organic species. High solids biomass slurries containing up to 27 wt% were successfully prepared in a stirred batch reactor and then pumped using a single piston valveless pump. Wheat straw, potato, and tomato crop residues were acid hydrolyzed using 1.2 wt% sulfuric acid at 180°C and 1.2 MPa for 0.75-1.5 hours. Viscosity for a 25 wt% acid hydrolyzed wheat straw emulsion (Bingham-plastic) was 6.5 centipoise at 3 cm/sec and 25°C.

Over the last three years, the University of Utah (UofU), NASA Ames Research Center (ARC), and Reaction Engineering International (REI) have been developing an incineration system for the regeneration of components in waste materials for long-term life support systems. The system includes a fluidized bed combustor and a catalytic flue gas clean up system. An experimental version of the incinerator was built at the UofU. The incinerator was tested and modified at ARC and then operated during the Phase III human testing at NASA Johnson Space Center (JSC) during 1997. This paper presents the results of the work at the three locations: the design and testing at UofU, the testing and modification at ARC, and the integration and operation during the Phase III tests at JSC.

Water is of critical importance to space missions due to crew needs and the cost of supply. To control mission costs, it is essential to recycle water from all available wastes - both solids and liquids. Water recovery from liquid water wastes has already been accomplished on space missions. For instance, a Water Recycling System (WRS) is currently operational on the International Space Station (ISS). It recovers water from urine and humidity condensate and processes it to potable water specifications. However, there is more recoverable water in solid wastes such as uneaten food, wet trash, feces, paper and packaging material, and brine. Previous studies have established the feasibility of obtaining a considerable amount of water and oxygen from these wastes (Pisharody et al, 2002; Fisher et al, 2008; Wignarajah et al, 2008).

The elemental composition of food consumed by astronauts is well defined. The major elements carbon, hydrogen, oxygen, nitrogen and sulfur are taken up in large amounts and these are often associated with the organic fraction (carbohydrates, proteins, fats etc) of human tissue. On the other hand, a number of the elements are located in the extracellular fluids and can be accounted for in the liquid and solid waste fraction of humans. These elements fall into three major categories - cationic macroelements (e.g. Ca, K, Na, Mg and Si), anionic macroelements (e.g. P, S and Cl and17 essential microelements, (e.g. Fe, Mn, Cr, Co, Cu, Zn, Se and Sr). When provided in the recommended concentrations to an adult healthy human, these elements should not normally accumulate in humans and will eventually be excreted in the different human wastes.

The active control of problematic microbial populations aboard spacecraft, and within future lunar and planetary habitats is a fundamental Advanced Life Support (ALS) requirement to ensure the long-term protection of crewmembers from infectious disease, and to shield materials and equipment from biofouling and biodegradation. The development of effective antimicrobial coatings and materials is an important first step towards achieving this goal and was the focus of our research. A variety of materials were coated with antibacterial and antifungal agents using covalent linkages. Substrates included both granular media and materials of construction. Granular media may be employed to reduce the number of viable microorganisms within flowing aqueous streams, to inhibit the colonization and formation of biofilms within piping, tubing and instrumentation, and to amplify the biocidal activity of low aqueous iodine concentrations.

Solid Waste Management (SWM) systems of current and previous space flight missions have employed relatively uncomplicated methods of waste collection, storage and return to Earth. NASA's long-term objectives, however, will likely include human-rated missions that are longer in both duration and distance, with little to no opportunity for re-supply. Such missions will likely exert increased demands upon all sub-systems, particularly the SWM system. In order to provide guidance to SWM Research and Technology Development (R&TD) efforts and overall system development, the establishment of appropriate SWM system requirements is necessary. Because future long duration missions are not yet fully defined, thorough mission-specific requirements have not yet been drafted.

Long duration missions pose substantial new challenges for solid waste management in Advanced Life Support (ALS) systems. These possibly include storing large volumes of waste material in a safe manner, rendering wastes stable or sterilized for extended periods of time, and/or processing wastes for recovery of vital resources. This is further complicated because future missions remain ill-defined with respect to waste stream quantity, composition and generation schedule. Without definitive knowledge of this information, development of mission requirements is hampered. Additionally, even if waste streams were well characterized, other operational and processing needs require clarification (e.g. resource recovery requirements and planetary protection constraints). Therefore, the development of solid waste management (SWM) subsystem requirements for long duration space missions is an inherently uncertain, complex and iterative process.

In order to meet NASA potable water standards using biological processing, additional purification is needed. Elimination of ammonia species is a significant post-treatment step to achieve this goal. New technology, combining membrane transport and electro-oxidation of ammonia, was developed to solve this problem without the use of expendables. The Aqueous Phase Ammonia Removal and Destruction System (APARDS) Phase I Program rigorously demonstrated the feasibility of each sub-process, and an integrated system was developed that removed and destroyed ammonia from a simulated bioreactor effluent. Membranes and process conditions suitable for ammonia removal have been determined. An Ammonia Removal Module (ARM) was designed for the efficient transfer of ammonia to a secondary electro-oxidation stream where the ammonia was destroyed. The electrolysis cell's electrodes, operational voltage, and flow characteristics were optimized to rapidly destroy ammonia.

A workshop entitled the “Life Support & Habitation and Planetary Protection Workshop” was held in Houston, TX in April, 2005. The main objective of the workshop was to initiate communication, understanding, and a working relationship between the Life Support and Habitation1 (LSH) and Planetary Protection (PP) communities regarding the effect of the implementation of Mars human exploration PP policies on the Advanced Life Support2 (ALS), Advanced Extravehicular Activity (AEVA), and Advanced Environmental Monitoring and Control (AEMC) programs. This paper presents an overall summary of the workshop that includes workshop organization, objectives, starting assumptions, findings and recommendations. Specific result topics include the identification of knowledge and technology gaps, research and technology development (R&TD) needs, potential forward and back contaminants and pathways, mitigation alternatives, and PP requirements definition needs.

A Microwave Powered Solid Waste Stabilization and Water Recovery Prototype system has been developed for the treatment of solid waste materials generated during extended manned space missions. The system recovers water initially contained within wastes and stabilizes the residue with respect to microbial growth. Dry waste may then be safely stored or passed on to the next waste treatment process. Using microwave power, water present in the solid waste is selectively and rapidly heated. Liquid phase water flashes to steam and superheats. Hot water and steam formed in the interior of waste particles create an environment that is lethal to bacteria, yeasts, molds, and viruses. Steam contacts exposed surfaces and provides an effective thermal kill of microbes, in a manner similar to that of an autoclave. Volatilized water vapor is recovered by condensation.

Handling and processing human feces in space habitats is a major concern and needs to be addressed for the Crew Exploration Vehicle (CEV) as well as for future exploration activities. In order to ensure crew health and safety, feces should either be isolated in a dried form to prevent microbial activity, or be processed to yield a non-biohazardous product using a reliable technology. During laboratory testing of new feces processing technologies, use of “real” feces can impede progress due to practical issues such as safety and handling thereby limiting experimental investigations. The availability of a non-hazardous simulant or analogue of feces can overcome this limitation. Use of a simulant can speed up research and ensure a safe laboratory environment. At Ames Research Center, we have undertaken the task of developing human fecal simulants. In field investigations, human feces show wide variations in their chemical/physical composition.

A breadboard Electrochemical Water Recovery System (EWRS) that is designed to produce potable water from a composite waste stream without the use of expendables is described in this paper. Umpqua Research Company working together with NASA/JSC developed a sequential three-step process to accomplish this task. Electrolysis removes approximately 60% of the organic contaminants from ersatz composite waste water containing a total organic carbon (TOC) concentration of 707 mg/L. The contaminants in this solution consist of organic and inorganic impurities common to laundry, shower, handwash, and urine waste water. Useful gases and organic acids are the chief by-products of the first step. The partially oxidized electrolysis solution is then transferred to the electrodialysis process where ionized organic and inorganic species are concentrated into a brine. The deionized solution of recovered water contains ∼6% of the original organic contaminants and >90% of the original water.

Catalytic oxidation has proven to be an effective addition to the baseline multifiltration (MF) water reclamation technology which will be used on Space Station Freedom (SSF). Low molecular weight, polar organics such as alcohols, aldehydes, ketones, amides, and thiocarbamides which are poorly removed by the baseline MF technology can be oxidized to carbon dioxide at low temperature (121 C). The catalytic oxidation process by itself can reduce the Total Organic Carbon (TOC) to below 500 ppb for solutions designed to model these waste waters. Individual challenges by selected contaminants have shown only moderate selectivity towards particular organic species. The combined technology is applicable to more complex waste water generated in the Environmental Control and Life Support System (ECLSS) aboard SSF.

Advanced space life support systems, especially systems that include growing plants to produce food, require the recovery of resources - primarily carbon dioxide and water - from various hydrocarbon wastes. Supercritical water oxidation (SCWO) of wastes is one of several possible techniques for oxidizing waste organics to recover the carbon dioxide and water. Supercritical water oxidation has the advantages of fast kinetics, complete oxidation, and the minimization of undesirable side products. However, the SCWO process requires further development before the process can be implemented in space life systems. One of the SCWO development needs is in the area of destruction of insoluble solids - such as inedible biomass or human wastes. Insoluble solids have to be introduced into a SCWO reactor as particles, and it can be expected that the particle size of the solids will affect the rate of reaction.

The investigation and development of a chemiluminescence based ethanol detection concept into a biosensor system is described. The biosensor uses alcohol oxidase to catalyze the reaction of short chain primary alcohols with elemental oxygen to produce hydrogen peroxide and the corresponding aldehyde. The reaction of hydrogen peroxide with an organic luminophore in the presence of a sufficient electric field results in emission of blue light with peak intensity at 425nm. The chemiluminescent light intensity is directly proportional to the alcohol concentration of the sample. The aqueous phase chemistry required for sensor operation is implemented using solid phase modules which adjust the pH of the influent stream, catalyze the oxidation of alcohol, provide the controlled addition of the luminophore to the flowing aqueous stream, and minimize the requirement for expendables. Precise control of the pH has proven essential for the long-term sustained release of the luminophore.