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A 1.9 liter Volkswagen TDI engine has been modified to accomodate the addition of hydrogen into the intake manifold via timed port fuel injection. Engine out particulate matter and the emissions of oxides of nitrogen were investigated. Two fuels,low sulfur diesel fuel (BP50) and soy methyl ester (SME) biodiesel (B99), were tested with supplemental hydrogen fueling. Three test conditions were selected to represent a range of engine operating modes. The tests were executed at 20, 40, and 60 % rated load with a constant engine speed o 1700 RPM. At each test condition the percentage of power from hydrogen energy was varied from 0 to 40 %. This corresponds to hydrogen flow rates ranging from 7 to 85 liters per minute. Particulate matter (PM) emissions were measured using a scaning mobility particle sizer (SMPS) and a two stage micro dilution system. Oxides of nitrogen were also monitored.

The formation of NO2 in the cylinder of a diesel engine has been investigated using a total cylinder sampling technique and a simple kinetic model. Exhaust measurements of NO2 as a function of equivalence ratio and as function of time after engine start were made. Samples obtained by total cylinder sampling from an operating direct injection diesel engine showed NO2/NO ratios of 25 to 50%. This is much higher than the 1 to 3% which was measured in the exhaust. Simulations of the sampling process indicate that conversion of NO to NO2 is at least partially responsible for the high NO2/NO measurements. However, the processes which produce the NO to NO2 conversion during the sampling also occur during normal combustion. This may lead to high NO2 concentrations during the combustion cycle which are then lowered during the expansion to the measured exhaust concentrations.

Soot is the largest component of contaminants found in the diesel engine lubricating oil. The soot enters lubricating oil mainly through thermophoretic deposition on the cylinder wall. Although the mechanism is still not fully understood, it is generally accepted that soot particles promote engine wear, reducing engine component service life, fuel efficiency and performance. This problem will be further exacerbated when more and more diesel engines use EGR to reduce NOx emissions and when lubricating oil consumption is drastically reduced to control particulate emissions. In this study, lubricating oil samples were taken from 7 different operating diesel engines. The size distribution and concentration of the diesel soot particles in the lubricants were investigated by methods of photosedimentation and quantitative spectrophotometry. The size distributions were compared to those of soot particles in the exhaust.

There is a growing body of evidence that in-cylinder surfaces play an important role in determining the nature and quantity of soot emitted by diesel engines. This paper describes recent experimental results which demonstrate the importance of both the deposition of soot on walls during the combustion process and its subsequent reentrainment during exhaust blowdown. Soot deposition was demonstrated both experimentally and theoretically. The principal mechanism of soot deposition during combustion is thermophoresis. Our results suggest that the gross rate of in-cylinder deposition in the indirect injection diesel engine is between 20 and 45 percent of the net soot emission rate. Thus, a significant fraction of the soot emitted may have been stored on combustion chamber surfaces and protected from oxidation. Further evidence of wall deposition and subsequent reentrainment has been obtained by making time-resolved measurements of soot concentrations in the exhaust.

A one-stage dilution tunnel has been developed to sample and dilute diesel exhaust. The tunnel has the capability of simulating many aspects of the atmospheric dilution process. The dilution rate and overall dilution ratio, temperature, relative humidity, and residence time in the tunnel, as well as residence time and temperature in the transfer line between the tunnel and exhaust sampling point may be varied. In this work we studied the influence of the exhaust transfer line, tunnel residence time, and dilution air temperature on the exhaust particle size distribution. The influences of fuel sulfur content on the size distribution and on the sensitivity of the size distribution to dilution and sampling conditions were also examined. We do not suggest an optimum dilution scheme, but do identify critical variables.

Carbon black particles, which morphologically and chemically simulate a diesel exhaust soot, were mixed with the intake air of a single-cylinder direct injection diesel engine to investigate the efficiency of their removal by oxidation in the combustion chamber. An aerosol generation system, which is capable of generating carbon black aerosol of a size distribution and mass flow rate comparable to those of the soot agglomerates, was developed first. The aerosol was then introduced into the engine which was operating on conventional fuel. Four methods were used to characterize the exhaust particles: an electrical aerosol analyzer, a condensation nuclei counter, a low volume filter, and a micro-orifice cascade impactor. The size distribution and concentration of the diesel soot particles in the lubricants were investigated by methods of photosedimentation and quantitative spectrophotometry, respectively.

The formation of particles in the combustion chamber of a direct injection diesel engine has been studied with the use of the Total Cylinder Sampling Method. With this method, nearly the entire contents of the cylinder of an operating diesel engine can be quickly removed at various times during the combustion process. The particle mass and size distributions present in the sample can then be analyzed. If quenching of the combustion process is quick and complete, the resulting samples are representative of the particle mass and size distributions present in the cylinder near the time sampling begins. This paper discusses the effect of injection timing and piston bowl shape on the particle formation and oxidation. Example size distribution measurements are also shown. The particle concentrations in the cylinder were measured for three different injection timings with the standard piston installed in the engine.

A study of factors affecting hydrocarbon oxidation in a diesel oxidation catalyst was undertaken. The objective was to determine whether interactions between particulate-adsorbed hydrocarbons and the catalyst significantly influenced hydrocarbon oxidation. Theoretical modeling supported by experimental data obtained at the U.S. Bureau of Mines' Diesel Emissions Research Laboratory indicated that the mass of particles interacting with the ceramic support was negligible. Additionally, a model of hydrocarbon adsorption onto diesel particulate predicted that over 98% by mass of exhaust hydrocarbons would be gas-phase, rather than particulate-adsorbed, at converter operating temperatures. A second physical process, the diffusion of gas phase hydrocarbons to the catalytic surface, was subsequently investigated. Theoretical and experimental results for the unburnt fuel hydrocarbons indicated that hydrocarbon oxidation was diffusion limited under high temperature operating conditions.

A system has been developed that allows near real time measurements of total, volatile, and nonvolatile particle concentrations in engine exhaust. It consists of a short section of heated catalyst, a cooling coil, and an electrical aerosol analyzer. The performance of this catalytic stripper system has been characterized with nonvolatile (NaCl), volatile sulfate ((NH4)2 SO4), and volatile hydrocarbon (engine oil) particles with diameters ranging from 0.05-0.5 μm. The operating temperature of 300°C gives essentially complete removal of volatile sulfate and hydrocarbon particles, but also leads to removal of 15-25% of solid particles. This system has been used to determine total, volatile, and nonvolatile particle concentrations in the exhaust of a Diesel engine and a spark ignition engine. Volatile volume fractions measured in Diesel exhaust with the catalytic stripper system increased from 19-65% as the equivalence ratio (load) decreased from 0.64-0.13.

A test reactor was designed for a 6.7 kW, 303 cc, single cylinder, air cooled, gasoline fueled engine. The reactor was very efficient at hydrocarbon (HC) and carbon monoxide (CO) reductions - with up to 99.9 and 98.6% removed, respectively. It had no effect on oxides of nitrogen (NOx) emissions. With the reactor, the engine met the California Air Resources Board (ARB) proposed Tier II emission standards. A factorial test was used to determine that A/F ratio and air injection rate significantly affected CO reduction efficiency whereas air injection location, ignition timing, and engine load did not. Relationships were established between CO reduction, air injection rate, and reactor core temperature.

Low emission heavy-duty diesel engines are increasingly utilizing four-valve designs with vertical central injectors. However, two-valve DI diesel engines with inclined injectors offset from the centerline of the piston bowl are likely to continue to be used in medium and light duty applications for some time. In such situations, designing of the hole-type nozzle is very difficult and may cause unavoidable back-drilling problems. The purpose of this paper is to solve back-drilling problems connected with hole-type nozzles and improve fuel-air mixing which leads to more efficient combustion. Based on geometric considerations, this paper introduces single-cone hole-type nozzles, double-cone hole-type nozzles, and the critical principal angles for hole-type nozzles. The single-cone hole-type nozzles and double-cone hole-type nozzles can meet requirements for height of the spray impingement points and spray orifice distribution angle at the same time.

Two types of in-cylinder optical probes were applied to a single cylinder CFR engine to detect knocking combustion. The first probe was integrated directly into the engine spark plug to monitor the radiation from burned gas in the combustion process. The second was built into a steel body and installed near the end gas region of the combustion chamber. It measured the radiant emission from the end gas in which knock originates. The measurements were centered in the near infrared region because thermal radiation from the combustion products was believed to be the main source of radiation from a spark ignition engine. As a result, ordinary photo detectors can be applied to the system to reduce its cost and complexity. It was found that the measured luminous intensity was strongly dependent upon the location of the optical sensor.

The U.S. Bureau of Mines has sponsored research Co determine the particle size distribution and concentration of submicron particles upstream and downstream of a ceramic particle trap mounted in the exhaust stream of a Caterpillar 3304 diesel engine. Particle size distribution and mass were measured with an electrical aerosol analyzer, a diffusion battery-condensation nuclei counter combination, and filters. The engine was operated at 1400 and 1800 RPM and 3 load conditions at each speed-In general, the collection efficiency of the trap was high, ranging between 89 to 96%. Size distribution analysis revealed that the trap was generally more efficient at removing particles smaller than 0.1 µm diameter than larger particles. However, under certain conditions formation of nuclei (less than 0.056 µm diameter) downstream of the trap took place.

This paper describes the performance and emissions of a hydrogen-fueled, spark-ignited engine. An electronic control device, designed to provide the engine with a timed injection of the fuel, is shown to give high mean effective pressures and high efficiencies. The oxides of nitrogen from the exhaust gases have been analyzed and the mechanism for their formation is reviewed. The paper further describes an experiment with traces of hydrocarbons added to the hydrogen in an attempt to explain any additional phenomena that may be taking place during the combustion, such as “prompt NO” which is known to occur in hydrocarbon flames only. As it turns out, such additions have a negligible effect on the NOx formation in the region investigated.

Vibration signals from diesel engines were analyzed for the purpose of isolating signals relating to injection or combustion which could be used to time the engines. Nonintrusive sensors, magnetically attached to the engine, were used to obtain these vibration signals. Components believed to be associated with combustion or fuel injection were electronically isolated from the remaining engine noise, and subsequently processed to produce specific timing signals. Digital data acquisition and averaging methods were used, coupled with computerized frequency analysis. The signals were experimentally correlated with the combustion process over a wide range of injection timing. The electronic processing system developed provides a real time digital measure of the timing. Data on the accuracy and correlation of experimental measurements will be presented.

Particle formation, growth, coagulation and combustion in the cylinder of an indirect injection passenger car type diesel engine have been studied using a system which allows the cylinder contents to be rapidly expelled through a blowdown port, diluted, and collected in a sample bag for subsequent analysis. Characteristic blowdown times were about 0.5 ms. Samples were analyzed using a condensation nuclei counter to determine particle number concentrations and an electrical aerosol analyzer to determine particle volume concentrations in the 0.01 to 1.0 μm diameter range. Measurements were made with the engine operating at 1000 rpm and an equivalence ratio of 0.32. Peak particle number concentration in the cylinder 13 times the exhaust level, and peak particle volume (or mass) concentration in the cylinder 3 times the exhaust level were observed. These results suggest that significant particle coagulation and oxidation occur during the expansion stroke.

The performance of a closed-loop electronic fuel injection timing control system for diesel engines has been investigated, both experimentally and analytically. The Electronic Control System (ECS) studied is a version of the “Optimizer,” a peak seeking control which can find the maximum of one variable with respect to another. In this case, it was used to find the timing for maximum brake torque (MBT). The ECS can also be operated in a “biased” mode in which it will hold the timing either advanced or retarded of MBT, but in a fixed relationship to it. Performance and emissions of a medium duty engine equipped with the ECS were measured on an engine dynamometer. The results clearly demonstrate that, for a variety of operating conditions and for two fuels, the ECS can find and hold the timing at MBT or in fixed relationship to it.

A unique system which allows sampling of the entire contents of one of the cylinders of a 5.7-liter V-8 indirect-injection diesel engine has been developed. An explosively actuated cutter ruptures a diaphragm in the combustion chamber and allows the contents of the cylinder to rush out and be subsequently diluted and quenched with cool nitrogen. Particles are collected with a high-volume impactor/filter system. This system has been used to collect a series of particle samples at crankangles ranging from 5 to 40 degrees after top dead center. Particle samples from the exhaust were also obtained. The samples have been extracted to determine the soluble organic fraction. These extracts have been analyzed for five polycyclic aromatic compounds: pyrene, fluoranthene, benz(a)pyrene, benz(k)fluoranthene, and 1-nitropyrene. The results indicate significant removal of the first four between the combustion chamber and the exhaust manifold.

Combustion characteristics of an L-head engine combustion chamber have been examined using ionization probes and piezioelectric pressure transducers. The method describes how pressure rise rates, peak pressures, mean effective pressures, and flame arrival times were recorded. The flame arrival times were then used to find the position and shape of the flame front as a function of time. The influence of spark plug location on the above parameters was then examined for two different combustion chamber shapes.

Because of the more hostile environment in the compression ignition engine compared to the spark ignition engine, development and application of CI engine in-cylinder diagnostic methods have lagged those for SI engines. However, with more stringent federally mandated particulate and NOx standards which will go into effect in 1991 and 1994, the need for detailed information on the combustion processes in the cylinder is vital to controlling tailpipe emissions. The present paper contains a summary of the state-of-the-art techniques for determining in-situ species concentrations and profiles; particle concentrations, profiles, and size distributions; and temperature fields. Optical and physical probing methods, total cylinder dumping methods, and optical diagnostics applied for use in CI engine combustion chambers are discussed.