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Significant progress has been made at NASA Ames Research Center in the development of a heat melt compaction device called the Plastic Melt Waste Compactor (PMWC). The PMWC was designed to process wet and dry wastes generated on human space exploration missions. The wastes have a plastic content typically greater than twenty percent. The PMWC removes the water from the waste, reduces the volume, and encapsulates it by melting the plastic constituent of the waste. The PMWC is capable of large volume reductions. The final product is compacted waste disk that is easy to manage and requires minimal crew handling. This paper describes the results of tests conducted using the PMWC with a wet and dry waste composite that was representative of the waste types expected to be encountered on long duration human space exploration missions.

{ Natural fibre-reinforced composite has the potential to replace current materials used for automotive industrial applications. Oilseed flax fibre could be used as reinforcement for composites because it is readily available, environmentally friendly and possesses good mechanical properties. In this research, oilseed flax fibre reinforced-LLDPE and -HDPE biocomposites were developed through extrusion and injection molding. The flax fibre was chemically treated to improve the bond between the fibre and polymer. Flax fibre was mixed with low linear density polyethylene (LLDPE) and high density polyethylene (HDPE) with fibre content varying from 10 to 30% by mass and processed by extrusion and injection molding to biocomposites. The mechanical properties, surface properties, and thermal properties of biocomposites were measured to analyze the treatment and processing effect and to compare the effect of different flax fibre concentrations on the biocomposites.

Flax oil is the main goal of growing flaxseed. Flax oil has been used for nutrition, food, paint binder, putty, and wood finish. However, synthetic resin from flax oil has not been developed. In this paper we will develop a biopolymer derived from flax oil and the goal is to use it as a resin to produce a viable, biodegradable composite using natural fiber as reinforcement. First, the functionalization of the triglyceride group of the flax oil fatty acids with polymerizable chemical groups was studied. The triglyceride molecule of flax oil was epoxidized by the reaction of double bonds in the fatty acid with a peroxy acid (formic acid) to get epoxidized oil; the epoxidized oil was then reacted with ethylenically substituted carboxylic acid (acrylic acid) to form acrylated epoxidized flax oil. Polymer resins were prepared from flax oil by blending acrylated epoxidized flax oil with styrene and a free radical initiator.

During braking, third-body flows and layers govern friction mechanisms, which are fully responsible of the friction coefficient and wear. In the context of development of brake friction pairs, the involved tribological circuit has to be well understood and mastered. This paper concerns a sintered metal matrix composite used for TGV very high speed train. A series of low-energy stop brakings allows a detailed study of the third-body formation at the pad-disc contact. The pin surface is observed after each test. The evolution of the rubbing-area expansion all along the series is explained, and the friction behaviour, typical of the studied friction material, is related to the formation of a well-established third body at the pad-disc interface.

Due to the conventional autoclaving of pre-impregnated materials causes high costs in the production of carbon fibre structures, new injection methods have become more and more relevant. The research project “CFK-Tex” focuses on the automated handling and processing of preforms out of dry carbon fibre textiles. Regarding the advantages in quality improvement and process time, an automation of all process steps is getting enforced. The major challenge, in addition to the difficult handling-properties of the materials and high quality demands, is the enormous variety of outline variants caused by small production quantities but many different textile cuts per part. In the first step the requirements of an automated system are exactly analyzed considering the specific material properties as well as process and product based characteristics.

Drilling fastener holes in composite is much more difficult than in aluminum or other metallic materials since individual carbon fibers fracture at irregular angles resulting in numerous microscopic voids. These voids can trap excess sealant inhibiting the intimate electrical contact between the fastener and the composite structure. As the cutting tool wears there is an increase of surface chipping and an increase in the amount of uncut fibers or resin. This condition is referred to as machining–induced micro texture. Machining–induced micro texture has been shown to be associated with the presence of arcing between the fastener and the composite structure during lightning strike tests. Lightning protection of composite structure is more complex due to the intrinsic high resistance of carbon fibers and epoxy, the multi-layer construction and the anisotropic nature of the structure.

This paper studies the feasibility and potential benefits of aligning recycled carbon fibres, in the form of short individual filaments, to manufacture fibre reinforced polymer composites. A review of fibre alignment processes is presented to provide insight into the different alignment technologies. The main focus is on wet hydrodynamic processes, which offer a high degree of alignment for discontinuous fibres. The process parameters that govern the alignment efficiency are also reported. The effect of alignment on fibre packing efficiency in the manufacture of composites is included, together with a report of preliminary fibre alignment results obtained from three different alignment processes.

In several industrial fields, the integration of functions is a key technology to enhance the efficiency of components in terms of performance to mass/volume/cost ratio. Concerning the space industry, in the last few years the trend in spacecraft design has been towards smaller, light-weight and higher performance satellites with sophisticated payloads and instrumentation. Increasing power density figures are the common feature of such systems, constituting a challenging task for the Thermal Control System. The traditional mechanical and thermal design concepts are evidencing their limits with reference to such an emerging scenario.

The photocatalytic oxidation of VOCs was investigated using a novel countercurrent flow reactor designed to enable the treatment of toluene present in the gas and the aqueous phases simultaneously. The reactor was packed with silica-titania composites commingled with plastic pall rings. Using this mixed packing style was advantageous as it resulted in a higher UV penetration throughout the reactor. The average UV intensity in the reactor was determined to be 220 μW/g irradiated TiO2. It was found that under dry conditions, the STCs had a high adsorption capacity for toluene; however, this adsorption was completely hindered by the wetting of the STCs when the two phases were flowing simultaneously. The destruction of toluene in the aqueous phase was determined to follow a linear trend as a function of the contaminant concentration.

The physical and optical properties viz., water absorption pattern, density, color and opacity of oil palm fiber-LLDPE composites were studied. The effect of fiber size, fiber loading and fiber treatment on the above parameters was also studied. Alkali treatment on fibers was done to reduce the hydrophilic nature of composites. It was found that the water absorption in most of the combinations followed typical fickian behavior. The rate of water absorption and swelling increased with fiber loading. However alkali treatment on fibers resulted in reduction of water absorption at higher fiber loading only and composites with higher fiber size exhibited higher water absorption. True density of oil palm fiber-LLDPE composites were in the range of 967-1177 kg m-₃, whereas the bulk density ranged from 942-1122 kg m-₃. The dielectric constant of the composite was in the range of 3.22 to 6.73.

The research on using natural fibres as the reinforcement in plastic composites has increased dramatically in the last few years. Flax fibres are renewable resources with low specific mass, reduced energy consumption, and relatively low in cost. These advantages make flax fibres recognized as a potential replacement for glass fibres in composites. Among plastic, polyethylene was concluded to be a suitable material used as matrix in natural fibre reinforced biocomposites. However there are few studies on this area so far. In this paper, the processing method of flax fibre-reinforced polyethylene biocomposites is introduced. Flax fibre polyethylene biocomposite consists of flax fibre as the reinforcing component and high density polyethylene as the matrix. Acrylic acid pre-treatment was applied to flax fibre to improve the bonding between fibre and polyethylene.

The properties of oil palm fiber were estimated and compared with oil seed flax and industrial hemp fibers. Biocomposite of oil palm fiber and linear low density polyethylene (LLDPE) was manufactured. The effect of fiber size, fiber content and fiber treatment on dimensional stability of the biocomposite was studied. The true density of oil palm fiber is found to be 1503 kg m-₃. The oil palm fibers obtained from field contained nearly one-fourth impurities, and the equilibrium moisture contents (EMC) values of fibers nearly doubled with 25% increase in relative humidity. The dielectric constant of oil palm fiber was in the range of 7.76-8.31. The oil palm fiber resulted in thermograms with two endothermic peaks and three exothermic peaks with the first degradation temperature at 301.71°C. Alkali treatment reduced first degradation temperature to 297.1°C.

Magnesium and aluminum alloys offer lightweighting opportunities in automotive applications. Joining of dissimilar materials, however, generally requires methods that do not involve fusion. This paper explores the use of self-pierce riveting (SPR) to join magnesium to aluminum alloys for structural and closure applications. The preliminary results indicate that SPR is a viable option for joining aluminum extrusions to magnesium die castings, as well as stamped sheet aluminum to quick-plastic-formed (QPF) sheet magnesium.

This paper will present the results of 3-D finite element analyses of single lap adhesive joints between magnesium and three other automotive materials, namely steel, aluminum and SRIM composites. The modulus of magnesium is lower than that of either steel or aluminum, but is higher than that of SRIM. Thus, this study aims at determining the effect of the difference in substrate modulus on the deformation, stress and strain distributions and maximum stresses in adhesive joints of magnesium with the other three materials. In addition, the effect of adhesive modulus is also explored.

Experimental decklids for the Cadillac STS sedan were made with Al AA5083 sheet outer panels and Mg AZ31B sheet inner panels using regular-production forming processes and hardware. Joining and coating processes were developed to accommodate the unique properties of Mg. Assembled decklids were evaluated for dimensional accuracy, slam durability, and impact response. The assemblies performed very well in these tests. Explicit and implicit finite element simulations of decklids were conducted, and showed that the Al/Mg decklids have good stiffness and strength characteristics. These results suggest the feasibility of using Mg sheet closure panels from a structural perspective.

Al383/SiO₂ metal matrix composites (MMC) were designed to increase the wear properties of the Al alloy. However, the soft Al matrix was subject to large plastic deformation under high normal load during lubricated sliding wear tests, causing detachment of the reinforced particles. To further increase the wear resistance of the MMC, in this research, Plasma Electrolytic Oxidation (PEO) process was used to form oxide coatings on the MMC. The hard and wear-resistant oxide coatings protected the metal matrix during the wear tests, reducing the wear rate of MMC. The effect of both oxide coating thickness and volume content of SiO₂ particles on the wear behavior of MMC was investigated. It was found that with a proper combination of the volume content of SiO₂ and coating thickness, the MMC exhibited high wear resistance and low friction coefficient.

Polymer composites have been increasingly used for high temperature applications such as engine components. Exposed at elevated temperature for prolonged time, the polymer composites will undergo thermo-oxidative degradation, which is distinctive from the conventional physical degradation. The present paper reviews recent progress on studying the thermo-oxidative degradation and resultant mechanical properties of polymer composites.

There are numerous component applications that would benefit from localized austempering (heat treating only a portion of the component) for either improved wear properties or fatigue strength. Currently available methods for “surface austempering” of ductile iron are often expensive and not as well controlled as would be desired. This study was undertaken to find a better process. Locally Austempered Ductile Iron (LADI) is the result of those efforts. LADI is a surface hardening heat treatment process that will produce a localized case depth of an ausferrite microstructure (ADI) in a desired area of a component. This process has been jointly developed by Ajax Tocco Magnethermic Corporation (ATM) and Applied Process, Inc.- Technologies Division (AP) with support and collaboration from ThyssenKrupp Waupaca, Inc. (TKW). This paper describes the outcome of using this patent pending process (US #65/195,131).

There is a wide spectrum of cast ferrous heat resistant alloys available for exhaust component applications such as exhaust manifolds and turbocharger housings. Generally speaking, the ferrous alloys can be divided into four groups including: ferritic cast irons, austenitic cast irons, ferritic stainless steels, and austenitic stainless steels. Selection of a suitable alloy usually depends on a number of material properties meeting the requirements of a specific application. Ferritic cast irons continue to be an important alloy for exhaust manifolds and turbocharger housings due to their relatively low cost. A better understanding of the alloying effects and graphite morphologies of ferritic cast irons are discussed and their effect on material behavior such as the brittleness at medium temperatures is provided. The nickel-alloyed austenitic cast irons, also known as Ni-resist, exhibit stable structure and improved high-temperature strength compared to the ferritic cast irons.

Exhaust manifolds and turbocharger housings require good elevated temperature strength, good resistance to thermal fatigue and a stable microstructure. High silicon ductile iron, high silicon-molybdenum ductile iron and Ni-resist (a high nickel ductile iron) are the cast materials of choice. Unfortunately, molybdenum and nickel are expensive. In this study, a lower cost, high silicon-titanium, compacted graphite iron was developed and compared to high silicon ductile iron and higher cost, high silicon-molybdenum ductile iron. Room and elevated temperature strength data is presented.