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The engine and its exhaust flow behaviors are investigated in a turbo-charged gasoline direct injection engine under simulated cold-fast-idle condition. The metrics of interest are the exhaust sensible and chemical enthalpy flows, and the exhaust temperature, all of which affect catalyst light off time. The exhaust sensible enthalpy flow is mainly a function of combustion phasing; the exhaust chemical enthalpy flow is mainly a function of equivalence ratio. High sensible and chemical enthalpy flow with acceptable engine stability could be obtained with retarded combustion and enrichment. When split injection is employed with one early and one later and smaller fuel pulse, combustion retards with early secondary injection in the compression stroke but advances with late secondary injection. Comparing gasoline to E85, the latter produces a lower exhaust temperature because of charge cooling effect and because of a faster combustion.

The effects of secondary air on the exhaust oxidation of particulate matters (PM) have been assessed in a direct-injection-spark-ignition engine under fuel rich fast idle condition (1200 rpm; 2 bar NIMEP). Substantial oxidation of the unburned feed gas species (CO and HC) and significant reduction of both the particulate number (up to ∼80%) and volume (up to ∼90%) have been observed. The PM oxidation is attributed to the reactions between the PM and the radicals generated in the oxidation of the feed gas unburned species. This hypothesis is supported by the observation that the reduction in PM volume is proportional to the amount of heat release in the secondary oxidation.

This work examines the effect of valve timing during cold crank-start and cold fast-idle (1200 rpm, 2 bar NIMEP) on the emissions of hydrocarbons (HC) and particulate mass and number (PM/PN). Four different cam-phaser configurations are studied in detail: 1. Baseline stock valve timing. 2. Late intake opening/closing. 3. Early exhaust opening/closing. 4. Late intake phasing combined with early exhaust phasing. Delaying the intake valve opening improves the mixture formation process and results in more than 25% reduction of the HC and of the PM/PN emissions during cold crank-start. Early exhaust valve phasing results in a deterioration of the HC and PM/PN emissions performance during cold crank-start. Nevertheless, early exhaust valve phasing slightly improves the HC emissions and substantially reduces the particulate emissions at cold fast-idle.

The windage tray effect on aeration in the engine sump was assessed by replacing much of the windage tray materials with wire meshes of various blockages. The mesh was to prevent direct impact of the oil drops spinning off the crank shaft onto the sump oil, and simultaneously, to provide sufficient drainage so that there was no significant build up of windage tray oil film that would interact with these droplets. Aeration at the oil pump inlet was measured by X-ray absorption in a production V-6 SI engine motoring at 2000 to 6000 rpm. Within experimental uncertainty, these windage tray changes had no effect on aeration. Thus activities in the sump such as the interaction of the oil drops spun from the crank shaft with the sump oil or with the windage tray, and the agitation of the sump oil by the crank case gas, were not major contributors to aeration at the pump inlet.

The effects of the directed port flow produced by a Charge-Motion-Control-Valve (CMCV) on mixture preparation in a Port-Fuel-Injection engine were assessed under conditions typical of fast idle in a cold start process. The port fuel was found to comprise two components: a “valve” puddle (at the vicinity of the valve) that built up quickly, and that was mainly responsible for the delivery of the fuel to the cylinder charge; a “port” puddle located significantly upstream. The latter was mainly created by the reverse back flow process and built up slowly. Although the fuel amounts in these two components were roughly the same, the latter did not significantly interact with the fuel transport to the cylinder charge. The CMCV only weakly affected the purging or filling time of the valve puddle, hence the dynamics of the fuel delivery process was not materially affected.

A flame sheet model for NO production in multi-dimensional diesel simulation has been developed. It explicitly addresses that because of the finite computational cell resolution, the local temperature within the diffusion flame is substantially higher than the cell averaged temperatures. Thus using the latter values will under-predict NO production. The methodology uses a flame sheet library for the NO production. Computations using this model are compared to experimental data for a Cummins N14 engine. The results show that the NO production is predominantly from within the flame sheets; the bulk production accounts for less than 5% of the total production.

The catalyst oxygen storage capacities were measured over a test matrix consisted of fuels with 7, 33, 266 and 500 ppm sulfur, and of dynamometer-aged catalysts simulating 4K, 50K and 150K vehicle miles. A methodology was developed to relate the post-catalyst λ sensor response following an engine lean-step-transient to the total oxygen storage sites available. The time resolved NOx concentration profiles (which were most sensitive to the oxygen storage) in the catalyst were measured with the engine operating at λ modulations of various amplitudes and frequencies. The oxygen storage capacity deterioration comprised two multiplicative factors - an age factor which decreased quickly initially (by a factor of 2 from 4K to 50K miles), and then more modestly (by 30% from 50 to 150K miles), and a fuel sulfur factor which decreased by 10% for every 150 ppm increase in sulfur level.

The combustion process after auto-ignition is investigated. Depending on the non-uniformity of the end gas, auto-ignition could initiate a flame, produce pressure waves that excite the engine structure (acoustic knock), or result in detonation (normal or developing). For the “acoustic knock” mode, a knock intensity (KI) is defined as the pressure oscillation amplitude. The KI values over different cycles under a fixed operating condition are observed to have a log-normal distribution. When the operating condition is changed (over different values of λ, EGR, and spark timing), the mean (μ) of log (KI/GIMEP) decreases linearly with the correlation-based ignition delay calculated using the knock-point end gas condition of the mean cycle. The standard deviation σ of log(KI/GIMEP) is approximately a constant, at 0.63. The values of μ and σ thus allow a statistical description of knock from the deterministic calculation of the ignition delay using the mean cycle properties

An ignition delay correlation encompassing the effects of temperature, pressure, residual gas, EGR, and lambda (on both the rich and lean sides) has been developed. The procedure uses the individual knocking cycle data from a boosted direct injection SI engine (GM LNF) operating at 1250 to 2000 rpm, 8-14 bar GIMEP, EGR of 0 to 12.5%, and lambda of 0.8 to 1.3 with a certification fuel (Haltermann 437, with RON=96.6 and MON=88.5). An algorithm has been devised to identify the knock point on individual pressure traces so that the large data set (of some thirty three thousand cycles) could be processed automatically. For lean and for rich operations, the role of the excess fuel, air, and recycled gas (which has excess air in the lean case, and hydrogen and carbon monoxide in the rich case) may be treated effectively as diluents in the ignition delay expression.

The loss mechanisms associated with engine downsizing, boosting and compression ratio change are assessed. Of interest are the extents of friction loss, pumping loss, and crevice loss. The latter does not scale proportionally with engine size. These losses are deconstructed via a cycle simulation model which encompasses a friction model and a crevice loss model for engine displacement of 300 to 500 cc per cylinder. Boost pressure is adjusted to yield constant torque. The compression ratio is varied from 8 to 20. Under part load, moderate speed condition (1600 rpm; 13.4 Nm/cylinder brake torque), the pumping work reduces significantly with downsizing while the work loss associated with the crevice volume increases. At full load (1600 rpm; 43.6 Nm/cylinder brake torque), the pumping work is less significant. The crevice loss (normalized to the fuel energy) is essentially the same as in the part load case. The sensitivities of the respective loss terms to downsizing are reported.

To understand the effects of crevices on the engine-out hydrocarbon emissions, a series of engine experiments was carried out with different piston crevice volumes and with simulated head gasket crevices. The engine-out HC level was found to be modestly sensitive to the piston crevice size in both the warmed-up and the cold engines, but more sensitive to the crevice volume in the head gasket region. A substantial decrease in HC in the cold-to-warm-up engine transition was observed and is attributed mostly to the change in port oxidation.

The oxidation chemistry of paraffins, aromatics, olefins and MTBE were examined. Detailed chemical kinetics calculations were carried out for oxidation of these compounds in the engine cycle. The oxidation rates are very sensitive to temperature. At temperatures of over 1400 K (depending on the fuel), all the hydrocarbons are essentially oxidized for typical residence time in the engine. Based on the kinetics calculations, a threshold temperature is defined for the conversion of the fuel species to CO, CO2, H2O and partially oxidized products. The difference in the survival fraction between aromatics and non-aromatics is attributed to the higher threshold temperature of the aromatics.

A method for determining the flame contour based on the flame arrival time at the fiber optic (FO) spark plug and at the head gasket ionization probe (IP) locations has been developed. The experimental data were generated in a single-cylinder Ricardo Hydra spark-ignition engine. The head gasket IP, constructed from a double-sided copper-clad circuit board, detects the flame arrival time at eight equally spaced locations at the top of the cylinder liner. Three other IP's were also installed in the cylinder head to provide additional intermediate data on flame location and arrival time. The FO spark plug consists of a standard spark plug with eight symmetrically spaced optical fibers located in the ground casing of the plug. The cylinder pressure was recorded simultaneously with the eleven IP signals and the eight optical signals using a high-speed PC-based data acquisition system.

The effect of engine operating parameters (speed, spark timing, and fuel-air equivalence ratio [Φ]) on hydrocarbon (HC) oxidation within the cylinder and exhaust system is examined using propane or isooctane fuel. Quench gas (CO2) is introduced at two locations in the exhaust system (exhaust valve or port exit) to stop the oxidation process. Increasing the speed from 1500 to 2500 RPM at MBT spark timing decreases the total, cylinder-exit HC emissions by ∼50% while oxidation in the exhaust system remains at 40% for both fuels. For propane fuel at 1500 rpm, increasing Φ from 0.9 (fuel lean) to 1.1 (fuel rich) reduces oxidation in the exhaust system from 42% to 26%; at 2500 RPM, exhaust system oxidation decreases from 40% to approximately 0% for Φ = 0.9 and 1.1, respectively. Retarded spark increases oxidation in the cylinder and exhaust system for both fuels. Decreases in total HC emissions are accompanied by increased olefinic content and atmospheric reactivity.

The fuel injection process in the port of a firing 4-valve SI engine at part load and 25°C head temperature was observed by a high speed video camera. Fuel was injected when the valve was closed. The reverse blow-down flow when the intake valve opens has been identified as an important factor in the mixture preparation process because it not only alters the thermal environment of the intake port, but also strip-atomizes the liquid film at the vicinity of the intake valve and carries the droplets away from the engine. In a series of “fuel-on” experiments, the fuel injected in the current cycle was observed to influence the fuel delivery to the engine in the subsequent cycles.

A sampling system was developed to measure the evolution of the speciated hydrocarbon emissions from a single-cylinder SI engine in a simulated starting and warm-up procedure. A sequence of exhaust samples was drawn and stored for gas chromatograph analysis. The individual sampling aperture was set at 0.13 s which corresponds to ∼ 1 cycle at 900 rpm. The positions of the apertures (in time) were controlled by a computer and were spaced appropriately to capture the warm-up process. The time resolution was of the order of 1 to 2 cycles (at 900 rpm). Results for four different fuels are reported: n-pentane/iso-octane mixture at volume ratio of 20/80 to study the effect of a light fuel component in the mixture; n-decane/iso-octane mixture at 10/90 to study the effect of a heavy fuel component in the mixture; m-xylene and iso-octane at 25/75 to study the effect of an aromatics in the mixture; and a calibration gasoline.

A strategy to facilitate the mixture preparation process in PFI engines is to delay the Intake Valve Opening (IVO) by shifting the cam phasing so that the cylinder pressure is sub-atmospheric when the valve opens. The physics of the effect are discussed in terms of the pressure differential between the manifold and the cylinder, and the resulting flow and charge temperature history. The effect was evaluated by measuring the equivalence ratio of the trapped charge and the exhaust HC emissions in the first cycle of cranking in a 2.4L engine. When the IVO timing was changed from 18° BTDC to 21° ATDC, the in-cylinder fuel equivalence ratio increased by approximately 10%. This increase was attributed mainly to the enrichment of the charge by displacing the leaner mixture at the top of the cylinder in the period between BDC and IVC. The exhaust HC, however, increased by 40%. No conclusive explanation was established for this increase in HC emissions.

When gas sample is continuously drawn from the cylinder of an internal combustion engine, the sample that appears at the end of the sampling system corresponds to the in-cylinder content sometime ago because of the finite transit time which is a function of the cylinder pressure history. This variable delay causes a dispersion of the sample signal and makes the interpretation of the signal difficult An unsteady flow analysis of a typical sampling system was carried out for selected engine loads and speeds. For typical engine operation, a window in which the delay is approximately constant may be found. This window gets smaller with increase in engine speed, with decrease in load, and with the increase in exit pressure of the sampling system.

The interaction of intake port gas flow with the fuel spray in a port-fuel-injection engine is studied to see whether there are opportunities to facilitate the mixture preparation process and to improve the HC emissions through this interaction. The operating regime of interest is the fast idle period in a cold start. For single pulse injection, the HC emissions were not sensitive to injection details for closed-valve injection; emissions increased with open-valve injection. Then a split injection strategy was used in which the fuel was divided into two pulses. The first pulse was delivered during valve-closed; the second pulse was injected in the back flow period. Under cold-valve conditions, a small benefit (compared to close valve injection) was obtained with a second pulse fuel of 25%: 6% decrease in Specific HC emissions and 4.5% increase in the fuel delivery fraction.

The liquid fuel entry into the cylinder and its subsequent behavior through the combustion cycle were observed by a high speed CCD camera in a transparent engine. The videos were taken with the engine firing under cold conditions in a simulated start-up process, at 1,000 RPM and intake manifold pressure of 0.5 bar. The variables examined were the injector geometry, injector type (normal and air-assisted), injection timing (open- and closed-valve injection), and injected air-to-fuel ratios. The visualization results show several important and unexpected features of the in-cylinder fuel behavior: 1) strip-atomization of the fuel film by the intake flow; 2) squeezing of fuel film between the intake valve and valve seat at valve closing to form large droplets; 3)deposition of liquid fuel as films distributed on the intake valve and head region. Some of the liquid fuel survives combustion into the next cycle.