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Journal Article

On-Site Checks of the Particle Number Measurement Systems with Polydisperse Aerosol

2012-04-16
2012-01-0873
Since 2011 a particle number (PN) limit was introduced in the European light-duty diesel vehicles legislation. The PN measurement systems consist of i) a hot diluter and an evaporation tube at 300-400°C for the removal of the volatiles (Volatile Particle Remover, VPR) and ii) a particle number counter (PNC) with a 50% cut-point (cut-off) at 23 nm. The PN measurement systems are calibrated and validated annually with monodisperse aerosol: The VPR for the particle concentration reduction factor (PCRF) and the PNC for the linearity and the cut-off size. However, there are concerns that the PN measurement systems can drift significantly over this period of time, raising concerns regarding the validity of the previous measurements, especially if the yearly validation fails.
Journal Article

Sampling of Non-Volatile Vehicle Exhaust Particles: A Simplified Guide

2012-04-16
2012-01-0443
Recently, a particle number (PN) limit was introduced in the European light-duty vehicles legislation. The legislation requires measurement of PN, and particulate mass (PM), from the full dilution tunnel with constant volume sampling (CVS). Furthermore, PN measurements will be introduced in the next stage of the European Heavy-Duty regulation. Heavy-duty engine certification can be done either from the CVS or from a partial flow dilution system (PFDS). For research and development purposes, though, measurements are often conducted from the raw exhaust, thereby avoiding the high installation costs of CVS and PFDS. Although for legislative measurements requirements exist regarding sampling and transport of the aerosol sample, such requirements do not necessarily apply for raw exhaust measurements. Thus, measurement differences are often observed depending on where in the experimental set up sampling occurs.
Journal Article

A Miniature Catalytic Stripper for Particles Less Than 23 Nanometers

2013-04-08
2013-01-1570
The European Emissions Stage 5b standard for diesel passenger cars regulates particulate matter to 0.0045 g/km and non-volatile part/km greater than 23 nm size to 6.0x10₁₁ as determined by the PMP procedure that uses a heated evaporation tube to remove semi-volatile material. Measurement artifacts associated with the evaporation tube technique prevents reliable extension of the method to a lower size range. Catalytic stripper (CS) technology removes possible sources of these artifacts by effectively removing all hydrocarbons and sulfuric acid in the gas phase in order to avoid any chemical reactions or re-nucleation that may cause measurement complications. The performance of a miniature CS was evaluated and experimental results showed solid particle penetration was 50% at 10.5 nm. The sulfate storage capacity integrated into the CS enabled it to chemically remove sulfuric acid vapor rather than rely on dilution to prevent nucleation.
Technical Paper

Measurement of Dry Soot and Particulate Matter from Two-Stroke and Four-Stroke Snowmobiles

2010-09-28
2010-32-0042
Recent increases in emissions regulations within the snowmobile industry have led to significant advancements in fuel, exhaust, and control systems on snowmobiles. However, particulate matter is currently an unregulated exhaust component of snowmobile engines. The measurement of dry soot as well as particulate matter from snowmobiles is the focus of this paper. Two industry-representative snowmobiles were chosen for this research which included a 2006 Yamaha Nytro carbureted four-stroke and a 2009 Ski-Doo MX-Z direct-injected two-stroke. Measurements for each snowmobile included gaseous emissions (CO₂, CO, NOx, O₂, and THC), particulate matter collected on quartz filters, and dry soot measured using an AVL Micro Soot Sensor. Each snowmobile was tested over the industry-standard five-mode emissions certification test cycle to determine the emissions, dry soot, and particulate matter levels from idle to wide open throttle (full-load).
Technical Paper

Accuracy of Particle Number Measurements from Partial Flow Dilution Systems

2011-09-11
2011-24-0207
The measurement of the particle number (PN) concentration of non-volatile particles ≻23 nm was introduced in the light-duty vehicles regulation; the heavy-duty regulation followed. Based on the findings of the Particle Measurement Program (PMP), heavy-duty inter-laboratory exercise, the PN concentration measurement can be conducted either from the full dilution tunnel with constant volume sampling (CVS) or from the partial flow dilution system (PFDS). However, there are no other studies that investigate whether the PN results from the two systems are equivalent. In addition, even the PMP study never investigated the uncertainty that is introduced at the final result from the extraction of a flow by a PN system from the PFDS. In this work we investigate the uncertainty for the three possible cases, i.e., considering a constant extracted flow from the PFDS, sending a signal with 1 Hz frequency to the PFDS, or feeding back the extracted flow to the PFDS.
Technical Paper

CMS - An Evolution of the CVS - A Full Flow, Constant Mass Flow, Sampling System

2006-04-03
2006-01-1514
The CMS system commissioned by EPA and built by AVL, is a “start from a clean sheet of paper” approach to a full flow sampling system for aerosol matter from engine exhaust. The challenge of measuring 2007 level post DPF type particulate matter and polyaromatic hydrocarbons led to this re-thinking of sampler design. Previously used CVS designs had evolved to include elements that were not ideally suited for scaling up to large flow rates, and had mixing tunnels that were less than ideal for the sampling of complicated aerosols. The solution presented in this paper used ultrasonic time-of-flight flowmeters in place of the usual Venturi flow tubes, reducing the size and cost of air handling components. Acoustically designed dampeners were used to reduce pulsation disturbances to the flow measurement.
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