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During gasoline direct injection (GDI) in spark ignition engines, droplets may hit piston or liner surfaces and be rebounded or deposit in the liquid phase as wallfilm. This may determine slower secondary atomization and local enrichments of the mixture, hence be the reason of increased unburned hydrocarbons and particulate matter emissions at the exhaust. Complex phenomena indeed characterize the in-cylinder turbulent multi-phase system, where heat transfer involves the gaseous mixture (made of air and gasoline vapor), the liquid phase (droplets not yet evaporated and wallfilm) and the solid walls. A reliable 3D CFD modelling of the in-cylinder processes, therefore, necessarily requires also the correct simulation of the cooling effect due to the subtraction of the latent heat of vaporization of gasoline needed for secondary evaporation in the zone where droplets hit the wall. The related conductive heat transfer within the solid is to be taken into account.

Bio-derived fuels are drawing more and more attention in the internal combustion engine (ICE) research field in recent years. Those interests in use of renewable biofuels in ICE applications derive from energy security issues and, more importantly, from environment pollutant emissions concerns. High fidelity numerical study of engine combustion requires advanced computational fluid dynamics (CFD) to be coupled with detailed chemical kinetic models. This task becomes extremely challenging if real fuels are taken into account, as they include a mixture of hundreds of different hydrocarbons, which prohibitively increases computational cost. Therefore, along with employing surrogate fuel models, reduction of detailed kinetic models for multidimensional engine applications is preferred. In the present work, a reduced mechanism was developed for primary reference fuel (PRF) using the directed relation graph (DRG) approach. The mechanism was generated from an existing detailed mechanism.

Gasoline direct injection (GDI) engines are characterized by complex phenomena involving spray dynamics and possible spray-wall interaction. Control of mixture formation is indeed fundamental to achieve the desired equivalence ratio of the mixture, especially at the spark plug location at the time of ignition. Droplet impact on the piston or liner surfaces has also to be considered, as this may lead to gasoline accumulation in the liquid form as wallfilm. Wallfilms more slowly evaporate than free droplets, thus leading to local enrichment of the charge, hence to a route to diffusive flames, increased unburned hydrocarbons formation and particulate matter emissions at the exhaust. Local heat transfer at the wall obviously changes if a wallfilm is present, and the subtraction of the latent heat of vaporization necessary for secondary phase change is also an issue deserving a special attention.