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A feasibility study of an LPG DI diesel engine has been carried out to study the effectiveness of two selected cetane enhancing additives: Di-tertiary-butyl peroxide (DTBP) and 2-Ethylhexyl nitrate (EHN). When more than either 5 wt% DTBP or 3.5 wt% 2EHN was added to the base fuel (100 % butane), stable engine operation over a wide range of engine loads was possible (BMEPs of 0.03 to 0.60 MPa). The thermal efficiency of LPG fueled operation was found to be comparable to diesel fuel operation at DTBP levels over 5 wt%. Exhaust emissions measurements showed that NOx and smoke levels can be significantly reduced using the LPG+DTBP fuel blend compared to a light diesel fuel at the same experimental conditions. Correlations were derived for the measured ignition delay, BMEP, and either DTBP concentration or cetane number. When propane was added to a butane base fuel, the ignition delay became longer.

The spray characteristics of n-butane were analyzed numerically using KIVA-3V code and compared with those of diesel under the same boundary conditions. The transient behavior of hollow cone spray was calculated not only in a constant volume chamber under various ambient conditions, but also in a premixed compression ignition engine. The spray characteristics were evaluated in terms of spray tip penetration and droplet size distribution. Various atomization sub-models such as TAB, Wave breakup and Wave-KH (Kelvin-Helmholtz) model were implemented in the code and validated by comparison with experimental data. The results show that mixture formation for butane proceeds faster than diesel fuel primarily due to a higher evaporation rate caused by butane's higher diffusivity in air. Furthermore, in a premixed compression ignition engine, the mixture of butane becomes more homogeneous than diesel by the end of compression stroke.