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A new hydrogen flow sensor was designed and evaluated based on the concept of hot wire anemometry. This sensor is designed to measure the mass flow rate of hydrogen gas used in (but not limited to) proton exchange fuel cell, PEFC. The conceptual evaluation was initiated by deriving an electro-thermal model of the hot wire required for sensing hydrogen velocity. The modeling is done via a mechatronics software tool, Saber™. This model was validated using air as a medium. Simulated and experimental performance results and safety issues are presented and discussed in this paper. Fail safe methods and effectiveness have been investigated along with hydrogen ignition temperatures with varying hydrogen to air ratio.

The influence of the addition of oxygenated hydrocarbons to diesel fuels has been studied, using a detailed chemical kinetic model. Resulting changes in ignition and soot precursor production have been examined. N-heptane was used as a representative diesel fuel, and methanol, ethanol, dimethyl ether, dimethoxymethane and methyl butanoate were used as oxygenated fuel additives. It was found that addition of oxygenated hydrocarbons reduced the production of soot precursors. When the overall oxygen content in the fuel reached approximately 30-40 % by mass, production of soot precursors fell effectively to zero, in agreement with experimental studies. The kinetic factors responsible for these observations are discussed.

A novel fuel tank for storing liquid dimethyl ether (DME) has been developed. This fuel tank was made of cast aluminum with a water capacity of 40 liters. It contains two fluids: liquid DME and a vapor-liquid mixture of propane. A diaphragm separates the two fluids. The propane in the tank is a pressurizing fluid that pressurizes DME into a subcooled-liquid state; and, it also functions as a driving fluid that pumps the liquid DME from the tank to the injection pump using its vapor pressure. These features characterize the tank as a thermodynamic pump. Several hundred hours of tank tests at various temperatures have been conducted. Results of tank filling-discharge cycles simulating those in vehicle applications demonstrated that the concept of the two-fluid thermodynamic pump works and that the tank design is successful.

Although there seems to be a consensus regarding the low emission potential of DME, there are still different opinions about why the low NOx emissions can be obtained without negative effects on thermal efficiency. Possible explanations are: The physical properties of DME affecting the spray and the mixture formation Different shape and duration of the heat release in combination with reduced heat losses In this paper an attempt is made to increase the knowledge of DME in relation to diesel fuel with respect to heat release and NOx formation. The emphasis has been to create injection conditions as similar as possible for both fuels. For that purpose the same injection system (CR), injection pressure (270 bar), injection timing and duration have been used for the two fuels. The only differences were the diameters of the nozzle holes, which were chosen to give the same fuel energy supply, and the physical properties of the fuels.

Transesterified fuels (biodiesel fuels; BDF) from vegetable oils are alternative fuels for diesel engines, they are renewable and offer potential reductions in carbon dioxide emissions. Many studies have reported that exhaust from BDF has equal or higher NOx concentrations while HC and PM emissions are significantly lower than with gas oil. The aim of the present investigation is to achieve drastic reductions in NOx emissions. Performance tests of a single cylinder DI diesel engine were conducted using water emulsified fuels from BDF and gas oil with varying water addition rates combined with cooled EGR. The result showed that at a rated output, the emulsified gas oil with water to base fuel volume ratio of 30% reduced NOx (from 1020ppm) to 190ppm with the 21% EGR condition maintaining the minimum BSEC value achieved with EGR free gas oil operation. However, the smoke density increased by 28%.

This research explored methods to reduce regulated emissions in a small-bore, direct-injection diesel engine. Swirl was used to influence mixing of the spray plumes, and alternative fuels were used to study the effects of oxygenated and water microemulsion diesel fuels on emissions. Air/fuel mixing enhancement was achieved in the running engine by blocking off a percentage of one of the two intake ports. The swirl was characterized at steady-state conditions with a flowbench and swirl meter. Swirl ratios of 1.85, 2.70, and 3.29 were studied in the engine tests at full load with engine speeds of 1303, 1757, and 1906 rev/min. Increased swirl was shown to have negative effects on emissions due to plume-to-plume interactions. Blends of No. 2 diesel and biodiesel were used to investigate the presence of oxygen in the fuel and its effects on regulated emissions. Pure No. 2 diesel fuel, a 15% and a 30% biodiesel blend (by weight) were used.

The transportation industry has been investigating ethanol as an alternative fuel for many years. Ethanol provides a clean alternative to gasoline, though widespread use of this fuel has been limited due to a number of technical challenges, such as poor cold-start performance and reduced vehicle range, and economic competitiveness with gasoline. To address the technical issues surrounding the use of ethanol, a group of university engineering teams were selected to participate in the Ethanol Vehicle Challenge by converting 1999 Chevrolet Silverado trucks to dedicated E85 operation (85% ethanol and 15% gasoline). The goals of the Ethanol Vehicle Challenge concentrated on significantly lowering emissions and improving the cold-start performance, fuel efficiency and overall vehicle performance of the trucks. This report examines the emissions and cold-start performance results from the competition and the approaches taken by the teams to address these issues.

The fuel called E-85 can be burned effectively in engines similar to the engines currently mass-produced for use with gasoline. Since the ethanol component of this fuel is produced from crops such as corn and sugar cane, the fuel is almost fully renewable. The different physical and chemical properties of E-85, however, do require certain modifications to the common gasoline engine. The Windsor - St. Clair team has focused their attention to modifications that will improve fuel efficiency and reduce tailpipe emissions. Other modifications were also performed to ensure that the vehicle would still operate with the same power and driveability as its gasoline counterpart.

The University of Texas 2000 Ethanol Vehicle Challenge team remains focused on cold start, cold drivability, fuel economy, and emissions reduction for our 2000 Ethanol Vehicle Challenge entry. We used the stock PCM for all control functions except control of an innovative cold-start system our team designed. The primary modifications for improved emissions control involved ceramic coating of the exhaust manifolds, use of close-coupled ethanol-specific catalysts, use of a moddified version of the California Emissions Calibrated PCM, and our cold-start system that eliminates the need to overfuel the engine at the beginning of the FTP. Additionally, we eliminated EGR at high load to improve power density. Major modifications, such as increasing the compression ratio or pressure boosting, were eliminated from consideration due to cost, complexity, reliability, or emissions penalties.

A natural gas direct injection test engine equipped with a newly developed natural gas injector was built. High total hydrocarbon (THC) emission at part-load and high NOx emission at high-load remain as problems for direct injection natural gas engines. THC reduction and combustion improvement by throttling and NOx reduction by EGR were investigated. The following results were obtained: (1) the combustion at light and medium load conditions is improved by throttling. It is possible to improve the thermal efficiency at light-load in spite of the pumping loss by throttling. THC emissions are greatly decreased in this condition; (2) a large NOx reduction can be obtained without combustion deterioration by appropriate EGR at high-load conditions; and (3) it is possible to decrease both THC and NOx emissions by both throttling and EGR at part-load conditions.

The accuracy of the injection rate meter based on W. Zeuch's method in the measurement of multiple injection rate and amount was calibrated using a small cam driven piston that is driven by an electric motor. For the pre- or early-injection, a sensor with a high sensitivity can be applied to measure the small pressure increase due to the small injection amount. In case of the multiple injection that has the post and/or late injection, a pressure sensor with a low sensitivity must cover not only the large pressure increase due to the main injection but also the small pressure increase due to the post and/or late injection because the output of the high sensitivity sensor is saturated after the main injection. So the linearity of the low sensitivity pressure sensor was calibrated with the cam driven piston prior to the experiment with the actual injection system.

This paper focuses on the impact of proper thermal integration between two major components of the indirect methanol fuel cell vehicle fuel processor (reformer and burner). The fuel processor uses the steam reformation of methanol to produce the hydrogen required by the fuel cell. Since the steam reformation is an endothermic process, the required thermal energy is supplied by a catalytic burner. The performance of the fuel processor is very strongly influenced by the extent of thermal integration between the reformer and burner. Both components are modeled as a set of CSTRs (Continuous Stirred Tank Reactors) using Matlab/Simulink. The current model assumes no time lag between the methanol sent into the reformer and the methanol sent into the burner to generate the necessary heat for the reformer reactions to occur.

This work presents a method to maximize the net power output of an indirect methanol PEM fuel cell system. This method establishes an operating strategy for the air supply based on the stack, air supply and water and thermal management (WTM) sub-system characteristics - holding anode conditions constant. It is shown that operating strategies based on individual components result in the inefficient operation of the overall system. Inclusion of the WTM modifies the optimal operating conditions for both low and high pressure systems. However the results for high pressure show an efficiency gain through reducing air pressure and increasing airflow, the opposite of what is expected. This work also outlines the components and issues not included and their importance in system operation.

This paper describes the motivation for developing hydrogen-fueled engines for use in hybrid electric vehicles of the future. The ultimate motivation for using hydrogen as an energy carrier is carbon management. However, air quality concerns also provide motivation for developing hydrogen-fueled vehicles. For this reason, we discuss the position of the hydrogen-powered hybrid vehicle within the California Air Resources Board requirement for Zero Emission Vehicles. We describe the expected performance of an electrical generation system powered by a four-stroke, spark-ignited, internal combustion engine for a hydrogen-powered hybrid vehicle. The data show that the engine-out emissions of NOx will allow the vehicle to operate below the Super Ultra-Low Emission Vehicle standard set by the California Air Resources Board. The engine can run on either hydrogen or blends of hydrogen and natural gas. The engine can be optimized for maximum efficiency with low emissions.

A detailed simulation of a load-following indirect methanol fuel cell (IMFC) system was performed by the University of California - Davis fuel cell vehicle modeling program (FCVMP) in order to determine the realistic steady-state and dynamic performance of such a system. The first part of the paper includes a basic description of the model and the control of the system. The interaction between the fuel processor and the anode side of the stack is shown to have dynamic load following limitations and a subsequent control strategy is described to solve this problem. The interaction between the air supply, the cathode side of the stack and the water recovery is shown to have several optimization opportunities. In the second part of the paper, we find that the steady state efficiency of the system peaks at approximately 52% at around 5% of full power. The 25% of full power steady-state system efficiency is approximately 45% and the full power efficiency is approximately 27%.

Laser-Rayleigh imaging has been employed to measure the relative fuel concentration in the gaseous jet region of DME sprays. The measurements were performed in an optically accessible diesel truck engine equipped with a common rail injection system. A one-hole nozzle was used to guarantee that the recorded pressure history was associated with the heat release in the imaged spray. To compensate for the low compression ratio in the modified engine the inlet air was preheated. Spray development was studied for two levels of preheating, from the start of injection to the point where all fuel was consumed. The results indicate that there is a strong correlation between the amount of unburned fuel present in the cylinder and the rate of heat release at a given time. The combustion can not be described as purely premixed or purely mixing-controlled at any time, but always has an element of both. After all fuel appears to have vanished there is still an extended period of heat release.

The injection rate modulation and the spray characteristics are determining factors for the quality of mixture formation when applying GDI. Their variation with load and speed is a basic criterion for the adaptability of a type of injection system to an engine with known requirements. The increased interest for the utilization of regenerative fuels - such as methanol obtained from biomass - as well as the success of previous utilization scenarios of variable gasoline/methanol mixture using manifold injection formed the base of the present analysis: the paper describes the results concerning injection performances and spray characteristics when using gasoline/methanol mixtures with different ratios in a direct injection system with high pressure modulation. The results are compared for different parameters of the injection systems as follows: injection volume, injector opening pressure, needle lift, pintle/seat geometry.

Engine models are a basis for better controlling combustion process and the exhaust emissions resulting from it. Currently the zero- and quasi-dimensional models are mostly used. These types of models are also addressed in this article. Zero-dimensional models are computationally efficient and show good simulation results concerning the in-cylinder pressure. However, by neglecting multi-zonal resolution they are not able to describe fuel efficiency or the generation of pollutants. It is therefore necessary to enhance combustion process models with phenomenological fuel spray and vaporization models, with a local resolution of at least two zones. The chemical model for the calculating of emissions shall be based on a two-zone model. The amount of mass, which is transferred from the unburned to the burned zone, is entered into a chemical model based on the chemical equilibrium for the OCH-system (oxygen/carbon/hydrogen).

During the last years a great deal of efforts have been made to reduce pollutant emissions from Direct Injection Diesel Engines. The use of gaseous fuel as a supplement for liquid diesel fuel seems to be one solution towards these efforts. One of the fuels used is natural gas, which has a relatively high auto - ignition temperature and moreover it is an economical and clean burning fuel. The high auto - ignition temperature of natural gas is a serious advantage against other gaseous fuels since the compression ratio of most conventional diesel engines can be maintained. The main aspiration from the usage of dual fuel (liquid and gaseous one) combustion systems, is the reduction of particulate emissions. In the present work are given results of a theoretical investigation using a model developed for the simulation of gaseous fuel combustion processes in Dual Fuel Engines.

A new gas phase kinetic model using Westbrook's gas phase n-heptane model and Frenklach's soot model was constructed. This model was then used to predict the impact on PAH formation as an indices of soot formation on ethanol/diesel fuel blends. The results were then compared to soot levels measured by various researchers. The ignition delay characteristics of ethanol were validated against experimental results in the literature. In this paper the results of the model and the comparison with experimental results will be discussed along with implications on the method of incorporation of additives and alternative fuels.