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Fuel atomization and combustion at engine-like conditions are complicated and sensitive processes which make it hard to perform quantitative experiments with high precision and reproducibility. A better understanding of the processes can be obtained by controlling the boundary conditions. Variable parameters with an important influence on the sprays include fuel temperature, chamber temperature, injection pressure, gas velocity. Controlling all these parameters in an experimental setup is not evident since a lot of them fluctuate with time or interact with each other. Constant volume combustion chambers, using the pre-combustion method, have already shown to be a useful experimental tool for this kind of research purposes. The obtained quantitative results can in a next step be used to evaluate either multi-dimensional or simplified lower dimensional models.

Knock is one of the main factors limiting the efficiency of spark-ignition engines. The introduction of alternative fuels with elevated knock resistance could help to mitigate knock concerns. Alcohols are prime candidate fuels and a model that can accurately predict their autoignition behavior under varying engine operating conditions would be of great value to engine designers. The current work aims to develop such a model for neat methanol. First, an autoignition delay time correlation is developed based on chemical kinetics calculations. Subsequently, this correlation is used in a knock integral model that is implemented in a two-zone engine code. The predictive performance of the resulting model is validated through comparison against experimental measurements on a CFR engine for a range of compression ratios, loads, ignition timings and equivalence ratios.