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A step in the development of advanced regenerative life support systems is to produce simulation models to guide experimentation and hardware development. This paper discuses the development of detailed simulation models of water reclamation processors using the ASPEN PLUS™ simulation program. Individual models have been developed for Vapor Compression Distillation (VCD), Vapor Phase Catalytic Ammonia Removal (VPCAR) and Supercritical Water Oxidation (SCWO). This paper outlines the methodology which is used to complete this work and discusses the insights which are gained by this type of model development. A discussion of how modeling predictions are used to direct future work in modeling and experimentation is also presented. The initial set of modeled processors were VCD, VPCAR, and SCWO. Future work will cover the modeling of other processors. These models will be linked to form subsystem level models, and evaluations will be performed on various configurations.

The Vapor Phase Catalytic Ammonia Removal (VPCAR) system is being developed to recycle water for future NASA Exploration Missions [1,2,3,4,5]. Reduced gravity testing of the VPCAR System has been initiated to identify any potential problems with microgravity operation. Two microgravity testing campaigns have been conducted on NASA's C-9B Reduced Gravity Aircraft. These tests focused on the fluid dynamics of the unit's Wiped-Film Rotating Disk (WFRD) evaporator. The experiments used a simplified system to study the process of forming a thin film on a rotating disk. The configuration simulates the application of feed in the VPCAR's WFRD evaporator. The first round of aircraft testing, which was completed in early 2006, indicated that a problem with microgravity operation of the WFRD existed. It was shown that in reduced gravity the VPCAR wiper did not produce a uniform thin film [6]. The film was thicker near the axis of rotation where centrifugal forces are small.

Management of human feces and wastes is a major challenge in space vehicles due to the potential biohazards and malodorous compounds emanating during collection and storage of feces and wastes. To facilitate safe, yet realistic human waste management research, we have previously developed human fecal simulants for research activities. The odoriferous compounds in feces and wastes reduce the quality of life for astronauts, can reduce performance, and can even cause health problems. The major odoriferous compounds of concern belong to four groups of chemicals, volatile fatty acids, volatile sulfurous compounds, nitrogenous compounds and phenols. This paper attempts to review the problem of odor detection and odor control with advanced technology. There has been considerable progress in odor detection and control in the animal industry and in the dental profession.

Waste management is a vital function of spacecraft life support systems as it is necessary to meet crew health and safety and quality of life requirements. Depending on the specific mission requirements, waste management operations can include waste collection, segregation, containment, processing, storage and disposal. For the Crew Exploration Vehicle (CEV), addressing volume and mass constraints is paramount. Reducing the volume of trash prior to storage is a viable means to recover habitable volume, and is therefore a particularly desirable waste management function to implement in the CEV, and potentially in other spacecraft as well. Research is currently being performed at NASA Ames Research Center to develop waste compaction systems that can provide both volume and mass savings for the CEV and other missions.

A Microwave Enhanced Solid Waste Freeze Drying Prototype system has been developed for the treatment of solid waste materials generated during extended manned space missions. The system recovers water initially contained within wastes and stabilizes the residue with respect to microbial growth. Dry waste may then be safely stored or passed on to the next waste treatment process. Operating under vacuum, microwave power provides the energy necessary for sublimation of ice contained within the waste. This water vapor is subsequently collected as relatively pure ice on a Peltier thermoelectric condenser as it travels en route to the vacuum pump. In addition to stabilization via dehydration, microwave enhanced Freeze Drying reduces the microbial population (∼90%) in the waste.

Waste management is a critical component of life support systems for manned space exploration. Human occupied spacecraft and extraterrestrial habitats must be able to effectively manage the waste generated throughout the entire mission duration. The requirements for waste systems may vary according to specific mission scenarios but all waste management operations must allow for the effective collection, containment, processing, and storage of unwanted materials. NASA's Crew Exploration Vehicle usually referred to as the CEV, will have limited volume for equipment and crew. Technologies that reduce waste storage volume free up valuable space for other equipment. Waste storage volume is a major driver for the Orion waste compactor design. Current efforts at NASA Ames Research Center involve the development of two different prototype compactors designed to minimize trash storage space.

We present a device for collecting and storing feces in microgravity that is user-friendly yet suitable for spacecraft in which cabin volume and mass are constrained. On Apollo missions, the commode function was served using disposable plastic bags, which proved time-consuming and caused odor problems. On Skylab, the space shuttle, and the International Space Station, toilets have used airflow beneath a seat to control odors and collect feces. We propose to incorporate airflow into a system of self-compacting, self-drying collection and stowage bags, providing the benefits of previous commodes while minimizing mass and volume. Each collection bag consists of an inner layer of hydrophobic membrane that is permeable to air but not liquid or solid waste, an outer layer of impermeable plastic, and a collapsible spacer separating the inner and outer layers. Filled bags are connected to space vacuum, compacting and drying their contents.

The initial concepts and construction of a three layered, water-absorbent, zero-G, compactor trash bag will be described. This bag is composed of an inner wicking layer, a middle absorbent layer, and an outer containment layer. The primary properties of the wicking layer are the fast adsorption of any free liquid released within the trash bag and the lateral spreading of this liquid around the interior of the bag. The absorbent layer sequesters and stores the liquid captured by the wicking layer. It need not be as fast acting as the wicking layer, but has to have a much larger capacity. The containment layer allows for handling of the bag without worry of releasing the contents. The combined strength of the three layers needs to be sufficient to withstand the forces exerted by the compactor.

The inedible portion of plant biomass in closed regenerative life support systems must be reprocessed producing recyclable by-products such as carbon dioxide, sugars, and other useful organic species. High solids biomass slurries containing up to 27 wt% were successfully prepared in a stirred batch reactor and then pumped using a single piston valveless pump. Wheat straw, potato, and tomato crop residues were acid hydrolyzed using 1.2 wt% sulfuric acid at 180°C and 1.2 MPa for 0.75-1.5 hours. Viscosity for a 25 wt% acid hydrolyzed wheat straw emulsion (Bingham-plastic) was 6.5 centipoise at 3 cm/sec and 25°C.

Over the last three years, the University of Utah (UofU), NASA Ames Research Center (ARC), and Reaction Engineering International (REI) have been developing an incineration system for the regeneration of components in waste materials for long-term life support systems. The system includes a fluidized bed combustor and a catalytic flue gas clean up system. An experimental version of the incinerator was built at the UofU. The incinerator was tested and modified at ARC and then operated during the Phase III human testing at NASA Johnson Space Center (JSC) during 1997. This paper presents the results of the work at the three locations: the design and testing at UofU, the testing and modification at ARC, and the integration and operation during the Phase III tests at JSC.

Pyrolysis is a very versatile waste processing technology which can be tailored to produce a variety of solid, liquid and/or gaseous products. The pyrolysis processing of pure and mixed solid waste streams has been under investigation for several decades for terrestrial use and a few commercial units have been built for niche applications. Pyrolysis has more recently been considered for the processing of mixed solid wastes in space. While pyrolysis units can easily handle mixed solid waste streams, the dependence of the pyrolysis product distribution on the component composition is not well known. It is often assumed that the waste components (e.g., food, paper, plastic) behave independently, but this is a generalization that can usually only be applied to the overall weight loss and not always to the yields of individual gas species.

Waste Management Systems (WMSs) designed for use aboard long-term spacecraft missions and within Lunar and planetary habitations must reduce volume and recover useful resources from solid wastes, as well as impart chemical and microbial stability to stored wastes. Many WMS processes produce high concentrations of toxic emissions that can periodically overwhelm Trace Contaminant Control Systems (TCCSs) designed to handle nominal atmospheric contaminants. A prototype Catalytic Oxidation System (COS) has been developed for this contingency, and when mated to different WMS processes, will treat these toxic emissions on an as-needed basis. The COS reactor utilizes a platinum and ruthenium bimetallic catalyst supported on mesoporous zirconia that is highly active and oxidizes at relatively low temperature a wide variety of volatile organic compounds (VOCs) and inorganic toxic emissions produced by WMS processes.

A Microwave Enhanced Freeze Drying Solid Waste (MEFDSW) processor was delivered to NASA-Ames Research Center by Umpqua Company having been funded through a Small Business Innovative Research Phase II program. The prototype hardware was tested for its performance characteristics and for its functionality with the primary focus being the removal of water from solid wastes. Water removal from wastes enables safe storage of wastes, prevents microbes from growing and propagating using the waste as a substrate and has potential for recovery and reuse of the water. Other objectives included measurements of the power usage and a preliminary estimate of the Equivalent System Mass (ESM) value. These values will be used for comparison with other candidate water removal technologies currently in development.

The “low power-CO2 removal (LPCOR) system” is an advanced air revitalization system that is under development at NASA Ames Research Center. The LPCOR utilizes the fundamental design features of the ‘four bed molecular sieve’ (4BMS) CO2 removal technology of the International Space Station (ISS). LPCOR improves power efficiency by replacing the desiccant beds of the 4BMS with a membrane dryer and a state-of-the-art, structured adsorbent device that collectively require 25% of the thermal energy required by the 4BMS desiccant beds for regeneration. Compared to the 4BMS technology, it has the added functionality to deliver pure, compressed CO2 for oxygen recovery. The CO2 removal and recovery functions are performed in a two-stage adsorption compressor. CO2 is removed from the cabin air and partially compressed in the first stage. The second stage performs further compression and delivers the compressed CO2 to a reduction unit such as a Sabatier reactor for oxygen recovery.

A microwave powered solid waste stabilization and water recovery prototype was delivered to Ames Research Center through an SBIR Phase II contract awarded to Umpqua Research Company. The system uses a container capable of holding 5.7 dm3 volume of waste. The microwave power can be varied to operate either at full power (130 W) or in a variable mode from 0% and 100%. Experiments were conducted with different types of wastes (wet cloth, simulated feces/diarrheal wastes, wet trash and brine) at different levels of moisture content and dried under varying microwave power supply. This paper presents the experimental data. The results provide valuable insight into the different operation modes under which the prototype can be used to recover water from the wastes in a space environment. Further investigations and testing of the prototype are recommended.

Water is of critical importance to space missions due to crew needs and the cost of supply. To control mission costs, it is essential to recycle water from all available wastes - both solids and liquids. Water recovery from liquid water wastes has already been accomplished on space missions. For instance, a Water Recycling System (WRS) is currently operational on the International Space Station (ISS). It recovers water from urine and humidity condensate and processes it to potable water specifications. However, there is more recoverable water in solid wastes such as uneaten food, wet trash, feces, paper and packaging material, and brine. Previous studies have established the feasibility of obtaining a considerable amount of water and oxygen from these wastes (Pisharody et al, 2002; Fisher et al, 2008; Wignarajah et al, 2008).

In February 2004 NASA released “The Vision for Space Exploration.” The goals outlined in this document include extending the human presence in the solar system, culminating in the exploration of Mars. A key requirement for this effort is to identify a safe and effective method to process waste. Methods currently under consideration include incineration, microbial oxidation, pyrolysis, drying, and compaction. Although each has advantages, no single method has yet been developed that is safe, recovers valuable resources including oxygen and water, and has low energy and space requirements. Thus, the objective of this work was to develop a low temperature oxidation process to convert waste cleanly and rapidly to carbon dioxide and water. TDA and NASA Ames Research Center have developed a pilot scale low temperature ozone oxidation system to convert organic waste to CO2 and H2O.

Magnetically Assisted Gasification (MAG) is a relatively new concept for the destruction of solid wastes aboard spacecraft, lunar and planetary habitations. Three sequential steps are used to convert the organic constituents of waste materials into useful gases: filtration, gasification, and ash removal. In the filtration step, an aqueous suspension of comminuted waste is separated and concentrated using a magnetically consolidated depth filter composed of granular ferromagnetic media. Once the filter is fully loaded, the entrapped solids are thermochemically gasified via a variety of mechanisms including pyrolysis, isomerization, and oxidation reactions. Finally, the inorganic ash residue is removed from the magnetic media by fluidization and trapped downstream by filtration. Importantly, for each of these steps, the degree of consolidation or fluidization of the granular ferromagnetic media is controlled using magnetic forces.

The elemental composition of food consumed by astronauts is well defined. The major elements carbon, hydrogen, oxygen, nitrogen and sulfur are taken up in large amounts and these are often associated with the organic fraction (carbohydrates, proteins, fats etc) of human tissue. On the other hand, a number of the elements are located in the extracellular fluids and can be accounted for in the liquid and solid waste fraction of humans. These elements fall into three major categories - cationic macroelements (e.g. Ca, K, Na, Mg and Si), anionic macroelements (e.g. P, S and Cl and17 essential microelements, (e.g. Fe, Mn, Cr, Co, Cu, Zn, Se and Sr). When provided in the recommended concentrations to an adult healthy human, these elements should not normally accumulate in humans and will eventually be excreted in the different human wastes.

Equivalent System Mass (ESM) is used by the Advanced Life Support (ALS) community to quantify mission costs of technologies for space applications (Drysdale et al, 1999, Levri et al, 2000). Mass is used as a cost measure because the mass of an object determines propulsion (acceleration) cost (i.e. amount of fuel needed), and costs relating to propulsion dominate mission cost. Mission location drives mission cost because acceleration is typically required to initiate and complete a change in location. Total mission costs may be reduced by minimizing the mass of materials that must be propelled to each distinct location. In order to minimize fuel requirements for missions beyond low-Earth orbit (LEO), the hardware and astronauts may not all go to the same location. For example, on a Lunar or Mars mission, some of the hardware or astronauts may stay in orbit while the rest of the hardware and astronauts descend to the planetary surface.