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Technical Paper

Comparison of the Particulate Matter Index and Particulate Evaluation Index Numbers Calculated by Detailed Hydrocarbon Analysis by Gas Chromatography (Enhanced ASTM D6730) and Vacuum Ultraviolet Paraffin, Isoparaffin, Olefin, Naphthene, and Aromatic Analysis (ASTM D8071)

2021-08-16
2021-01-5070
The Particulate Matter Index (PMI) is a tool that provides an indication of a fuel’s tendency to produce Particulate Matter (PM) emissions. Currently, the index is being used by various fuel laboratories and the Automotive OEMs as a tool to understand the gasoline fuel’s impact on both PM from engine hardware and vehicle-out emissions. In addition, a newer index that could be used to give an indication of the PM tendency of the gasoline range fuels, called the Particulate Evaluation Index (PEI), is shown to have a good correlation to PMI. The data used in those indices are collected from chemical analytical methods. This paper will compare gas chromatography (GC) methods used by three laboratories and discuss how the different techniques may affect the PMI and PEI calculation.
Journal Article

Analysis of Particle Mass and Size Emissions from a Catalyzed Diesel Particulate Filter during Regeneration by Means of Actual Injection Strategies in Light Duty Engines

2011-09-11
2011-24-0210
The diesel particulate filters (DPF) are considered the most robust technologies for particle emission reduction both in terms of mass and number. On the other hand, the increase of the backpressure in the exhaust system due to the accumulation of the particles in the filter walls leads to an increase of the engine fuel consumption and engine power reduction. To limit the filter loading, and the backpressure, a periodical regeneration is needed. Because of the growing interest about particle emission both in terms of mass, number and size, it appears important to monitor the evolution of the particle mass and number concentrations and size distribution during the regeneration of the DPFs. For this matter, in the presented work the regeneration of a catalyzed filter was fully analyzed. Particular attention was dedicated to the dynamic evolution both of the thermodynamic parameters and particle emissions.
Journal Article

Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Emissions

2011-08-30
2011-01-2100
More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion engines. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number-based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs). One method is a thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample-handling methods have been implemented in an engine test cell with a spark-ignited direct injection (SIDI) engine. The engine was designed for stoichiometric, homogeneous combustion.
Technical Paper

Comparison of Stochastic Pre-Ignition Behaviors on a Turbocharged Gasoline Engine with Various Fuels and Lubricants

2016-10-17
2016-01-2291
Stochastic pre-ignition (SPI) has been commonly observed in turbocharged spark-ignition direct-injection (SIDI) engines at low-speed and high-load conditions, which causes extremely high cylinder pressures that can damage an engine immediately or degrade the engine life. The compositions and properties of fuels and lubricants have shown a strong impact on SPI frequency. This study experimentally evaluated SPI behaviors on a 2.0-liter 4-cylinder turbocharged SIDI engine with China V market fuel and China fuel blended to US Tier II fuel specifications. China V market fuel showed significantly higher SPI frequency and severity than China blended US Tier II fuel, which was attributed to its lower volatility between 100 °C to 150 °C (or lower T60 to T90 in the distillation curve). Two different formulations of lubricant oils were also tested and their impact on SPI were compared.
Technical Paper

An Investigative Study of Sudden Pressure Increase Phenomenon Across the SCR on Filter Catalyst

2016-10-17
2016-01-2319
In the previous research1), the authors discovered that the sudden pressure increase phenomenon in diesel particulate filter (DPF) was a result of soot collapse inside DPF channels. The proposed hypothesis for soot collapse was a combination of factors such as passive regeneration, high humidity, extended soak period, high soot loading and high exhaust flow rate. The passive regeneration due to in-situ NO2 and high humidity caused the straw like soot deposited inside DPF channels to take a concave shape making the collapse easier during high vehicle acceleration. It was shown that even if one of these factor was missing, the undesirable soot collapse and subsequent back pressure increase did not occur. Currently, one of the very popular NOx reduction technologies is the Selective Catalytic Reduction (SCR) on Filter which does not have any platinum group metal (PGM) in the washcoat.
Technical Paper

China Market Gasoline Review Using Fuel Particulate Emission Correlation Indices

2017-10-08
2017-01-2401
The impact of gasoline composition on vehicle particulate emissions response has been widely investigated and documented. Correlation equations between fuel composition and particulate emissions have also been documented, e.g. Particulate Matter Index (PMI) and Particulate Evaluation Index (PEI). Vehicle PM/PN emissions correlate very well with these indices. In a previous paper, global assessment with PEI on fuel sooting tendency was presented [1]. This paper will continue the previous theme by the authors, and cover China gasoline in more detail. With air pollution an increasing concern, along with more stringent emission requirements in China, both OEMs and oil industries are facing new challenges. Emissions controls require a systematic approach on both fuels and vehicles. Chinese production vehicle particulate emissions for a range of PEI fuels are also presented.
Technical Paper

Particulate Characteristics for Varying Engine Operation in a Gasoline Spark Ignited, Direct Injection Engine

2011-04-12
2011-01-1220
The objective of this research is a detailed investigation of particulate sizing and number count from a spark-ignited, direct-injection (SIDI) engine at different operating conditions. The engine is a 549 [cc] single-cylinder, four-valve engine with a flat-top piston, fueled by Tier II EEE. A baseline engine operating condition, with a low number of particulates, was established and repeatability at this condition was ascertained. This baseline condition is specified as 2000 rpm, 320 kPa IMEP, 280 [°bTDC] end of injection (EOI), and 25 [°bTDC] ignition timing. The particle size distributions were recorded for particle sizes between 7 and 289 [nm]. The baseline particle size distribution was relatively flat, around 1E6 [dN/dlogDp], for particle diameters between 7 and 100 [nm], before dropping off to decreasing numbers at larger diameters. Distributions resulting from a matrix of different engine conditions were recorded.
Technical Paper

Correlation of Chemical Compositions and Fuel Properties with Fuel Octane Rating of Gasoline Containing Ethanol

2011-08-30
2011-01-1986
With increasing use of ethanol in automotive fuel in recent years, which can be made from renewable feedstocks, the chemical composition of gasoline is changed. The compositional change results in many changes in fuel properties. One key property is the octane rating of gasoline. Market data has shown the shifts of octane rating (antiknock index or AKI) upward due to more penetration of E10 gasoline in the US market. However, the increase in research octane is more pronounced as compared to motor octane, therefore the increase in octane sensitivity in gasoline. Refineries have used the change in octane due to ethanol contribution by sending so called sub-grade gasoline to terminals expecting the final blend after mixing with ethanol to meet the market requirement in octane. Thus the octane rating of the final blend will largely depend on the sub-grade gasoline composition and ethanol.
Technical Paper

Learning Gasoline Direct Injector Dynamics Using Artificial Neural Networks

2018-04-03
2018-01-0863
In today’s race for improved fuel economy and lower emissions from gasoline engines, precise metering of delivered fuel is essential. Gasoline Direct Injection fuel systems provide the means for improved combustion efficiency through mixture preparation and better atomization. These improvements can be achieved from both increasing fuel pressure and using multiple injection events, which significantly reduce the required energizing time per injection, and in a number of cases, force the injector to operate at less than full stroke. When the injector operates in this condition, the influence of variation in injector dynamics account for a large percentage of the delivered fuel and require compensation to ensure accurate fuel delivery. Injector dynamics such as opening delay and closing time are influenced by operating conditions such as fuel pressure, energizing time, and temperature.
Technical Paper

Update on Gasoline Fuel Property and Gasoline Additives Impacts on Stochastic Preignition with Review of Global Market Gasoline Quality

2022-08-30
2022-01-1071
Stochastic Preignition (SPI) is an abnormal combustion phenomenon for internal combustion engines (ICE), which has been a significant impact to automotive companies developing high efficiency, turbocharged, direct fuel injection, spark ignited engines. It is becoming clearer what fuel properties are related to the cause of SPI, whether directly with fuel preparation in the cylinder, or mechanisms related to the deposit build-up which contributes to initial and follow-on SPI events. The purpose of this paper is to provide a summary of global market gasoline fuel properties with special attention given to properties and specific compounds from the fuel and fuel additives that can contribute to SPI and the deposit build-up in engines. Based on a review of the global fuel quality, it appears that the fuel quality has not caught up to meet the technology requirements for fuel economy from modern technology engines.
Technical Paper

Model Predictive Control of Turbocharged Gasoline Engines for Mass Production

2018-04-03
2018-01-0875
This paper describes the design of a multivariable, constrained Model Predictive Control (MPC) system for torque tracking in turbocharged gasoline engines scheduled for production by General Motors starting in calendar year 2018. The control system has been conceived and co-developed by General Motors and ODYS. The control approach consists of a set of linear MPC controllers scheduled in real time based on engine operating conditions. For each MPC controller, a linear model is obtained by system identification with data collected from engines. The control system coordinates throttle, wastegate, intake and exhaust cams in real time to track a desired engine torque profile, based on measurements and estimates of engine torque and intake manifold pressure.
Technical Paper

Investigation of the Impact of Fuel Properties on Particulate Number Emission of a Modern Gasoline Direct Injection Engine

2018-04-03
2018-01-0358
Gasoline Direct Injection (GDI) has become the preferred technology for spark-ignition engines resulting in greater specific power output and lower fuel consumption, and consequently reduction in CO2 emission. However, GDI engines face a substantial challenge in meeting new and future emission limits, especially the stringent particle number (PN) emissions recently introduced in Europe and China. Studies have shown that the fuel used by a vehicle has a significant impact on engine out emissions. In this study, nine fuels with varying chemical composition and physical properties were tested on a modern turbo-charged side-mounted GDI engine with design changes to reduce particulate emissions. The fuels tested included four fuels meeting US certification requirements; two fuels meeting European certification requirements; and one fuel meeting China 6 certification requirements being proposed at the time of this work.
Technical Paper

Impact of Fuel Detergent Type and Concentration on the Rate and Severity of Stochastic Preignition in a Turbocharged Spark Ignition Direct Injection Gasoline Engine

2021-04-06
2021-01-0490
Stochastic Preignition (SPI) is an abnormal combustion event that occurs in a turbocharged engine and can lead to the loss in fuel economy and engine hardware damage, and in turn result in customer dissatisfaction. It is a significant limiting factor on the use and continued downsizing of turbocharged spark ignited direct injection (SIDI) gasoline engines. Understanding and mitigating all the factors that cause and influence the rate and severity of SPI occurrence are of critical importance to the engine’s continued use and fuel economy improvements for future designs. Previous studies have shown that the heavy molecular weight components of the fuel formulations are one factor that influences the rate of SPI from a turbocharged SIDI gasoline engine. All the previous studies have involved analyzing the fuel’s petroleum hydrocarbon chemistry, but not specifically the additives that are put in the fuel to protect and clean the internal components over the life of the engine.
Technical Paper

A New Predictive Vehicle Particulate Emissions Index Based on Gasoline Simulated Distillation

2022-03-29
2022-01-0489
Fuel chemistry plays a crucial role in the continued reduction of particulate emissions (PE) and cleaner air quality from vehicles and equipment powered by internal combustion engines (ICE). Over the past ten years, there have been great improvements in predictive particulate emissions indices (correlative mathematical models) based on the fuel’s composition. Examples of these particulate indices (PI) are the Honda Particulate Matter Index (PMI) and the General Motors Particulate Evaluation Index (PEI). However, the analytical chemistry lab methods used to generate data for these two PI indices are very time-consuming. Because gasoline can be mixtures of hundreds of hydrocarbon compounds, these lab methods typically include the use of the high resolution chromatographic separation techniques such as detailed hydrocarbon analysis (DHA), with 100m chromatography columns and long (3 - 4 hours) analysis times per sample.
Technical Paper

Potential towards CI Engines with Lower NOx Emissions through Calibration Optimization and Low-Carbon Fuels

2022-03-29
2022-01-0511
The continuous improvement of internal combustion engines (ICEs) with strategies that can be applied to existing vehicle platforms, either directly or with minor modifications, can improve efficiency and reduce GHG emissions to help achieve Paris climate targets. Low carbon fuels (LCF) as diesel substitutes for light and heavy-duty vehicles are currently being considered as a promising alternative to reduce well-to-wheel (WTW) CO2 emissions by taking advantage of the carbon offset their synthesis pathway can promote, which could capture more CO2 than it releases into the atmosphere. Additionally, some low carbon fuels, like OMEx blends, have non-sooting properties that can significantly improve the NOx-soot tradeoff. The current work studies the calibration optimization of a EU6D-TEMP light-duty engine using various LCFs with different renewable contents with the goal of reduced NOx emissions.
Technical Paper

Spark Assist for CA50 Control and Improved Robustness in a Premixed LTGC Engine – Effects of Equivalence Ratio and Intake Boost

2018-04-03
2018-01-1252
Low-temperature gasoline combustion (LTGC) engines can deliver high efficiencies, with ultra-low emissions of nitrogen oxides (NOx) and particulate matter (PM). However, controlling the combustion timing and maintaining robust operation remains a challenge for LTGC engines. One promising technique to overcoming these challenges is spark assist (SA). In this work, well-controlled, fully premixed experiments are performed in a single-cylinder LTGC research engine at 1200 rpm using a cylinder head modified to accommodate a spark plug. Compression ratios (CR) of 16:1 and 14:1 were used during the experiments. Two different fuels were also tested, with properties representative of premium- and regular-grade market gasolines. SA was found to work well for both CRs and fuels. The equivalence ratio (ϕ) limits and the effect of intake-pressure boost on the ability of SA to compensate for a reduced Tin were studied. For the conditions studied, ϕ=0.42 was found to be most effective for SA.
Technical Paper

Development of an Alternative Predictive Model for Gasoline Vehicle Particulate Matter and Particulate Number

2019-04-02
2019-01-1184
The Particulate Matter Index (PMI) is a helpful tool which provides an indication of a fuel’s sooting tendency. Currently, the index is being used by various laboratories and OEMs as a metric to understand the gasoline fuels impact on both sooting found on engine hardware and vehicle out emissions. This paper will explore a new method that could be used to give indication of the sooting tendency of the gasoline range fuels, called the Particulate Evaluation Index (PEI), and provide the detailed equation in its initial form. In addition, the PEI will be shown to have a good correlation agreement to PMI. The paper will then give a detailed explanation of the data used to develop it. Initial vehicle PM/PN data will also be presented that shows correlations of the indices to the vehicle response.
Technical Paper

Influence of Ethanol and MTBE Proportion in China VIB Gasoline on Vehicle Particulate Emissions

2021-04-06
2021-01-0540
With the implementation of the China VI gasoline standards, the use of ethanol is expanding and is intended to further reduce vehicle criteria gaseous and particulate emissions. However, due to the constraints of biomass ethanol production, petroleum derived Methyl tert-Butyl Ether (MTBE) is being used in addition to ethanol to improve fuel octane and maintain oxygen content. The impact of these mixed oxygenates on vehicle emissions are studied in this paper. The correlation of fuel characteristics to vehicle particulate emissions and their predictive indices has been investigated. The results from this study suggest some alternatives to existing fuel indices due to oxygenate contribution. Additionally, this paper studies, the emissions of three direct-injection turbocharged vehicle models focusing on particulate emissions from the Worldwide Harmonized Light Vehicles Test Cycle (WLTC). The test fuels were China VIb gasoline, blended with different ratios of ethanol and MTBE.
Technical Paper

Combustion-Timing Control of Low-Temperature Gasoline Combustion (LTGC) Engines by Using Double Direct-Injections to Control Kinetic Rates

2019-04-02
2019-01-1156
Low-temperature gasoline combustion (LTGC) engines can provide high efficiencies and extremely low NOx and particulate emissions, but controlling the combustion timing remains a challenge. This paper explores the potential of Partial Fuel Stratification (PFS) to provide fast control of CA50 in an LTGC engine. Two different compression ratios are used (CR=16:1 and 14:1) that provide high efficiencies and are compatible with mixed-mode SI-LTGC engines. The fuel used is a research grade E10 gasoline (RON 92, MON 85) representative of a regular-grade market gasoline found in the United States. The fuel was supplied with a gasoline-type direct injector (GDI) mounted centrally in the cylinder. To create the PFS, the GDI injector was pulsed twice each engine cycle. First, an injection early in the intake stroke delivered the majority of the fuel (70 - 80%), establishing the minimum equivalence ratio in the charge.
Technical Paper

Model Based Calibration Generation for Gasoline Particulate Filter Regeneration

2021-04-06
2021-01-0600
Gasoline Particulate Filters (GPF) are widely employed in exhaust aftertreatment systems of gasoline engines to meet the stringent particulate emissions requirements of Euro 6 and China 6 standard. Optimization of GPF performance requires a delicate trade-off between fuel economy, engine performance and drivability. This results in a complex lengthy and iterative calibration development process which uses a lot of hardware resources. To improve the calibration process and reduce hardware testing, physics-based modeling of the GPF system is used. A 1-D chemical model supplemented with 3D CFD solver is utilized to evaluate pressure drop and soot burning performance characteristics of the GPF under engine dynamometer test conditions. The chemical kinetics of soot burning for the 1D model is developed using test data obtained from well controlled laboratory environment.
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